4-Dimethylaminophenylpentazole (original) (raw)
4-(二甲基氨基)苯基五唑，是一个不稳定的、有的化合物，它包含了非常罕见的由五个氮原子组成的五唑环。苯环对位上的二甲基氨基的使得此化合物比苯基五唑更稳定。在室温下，其化学半衰期只有几个小时, 然而在超低温下储存是可能的。这个化合物在1956年与其他取代的芳基五唑一起被初次制备出来。对各种其他的衍生物的研究也在进行，但必定由于这些化合物的不稳定性而受到限制。 一些取代基更多的衍生物，如 2,6-二羟基-4-(二甲基氨基)苯基五唑，要稍微更稳定一些，但是反过来，制备这些衍生物的难度更大。目前的研究聚焦于形成这些五唑衍生物的过渡金属配合物，因为五唑环可能由于与金属中心的化学键而稳定下来。
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| dbo:abstract | 4-Dimethylaminophenylpentazole is an unstable, explosive compound that contains the rare pentazole ring, which is composed of five nitrogen atoms. The electron donating effect of the 4-dimethylamino substituent on the phenyl ring makes this compound one of the more stable of the phenylpentazoles. At room temperature, its chemical half-life is only a few hours, although storage is possible at cryogenic temperatures. The compound was first prepared in 1956 along with other substituted phenylpentazoles. Studies have been conducted on various other derivatives, though necessarily limited by the instability of these compounds. Some more highly substituted derivatives, such as 2,6-dihydroxy-4-dimethylaminophenylpentazole, are slightly more stable but conversely, more difficult to make. Current research has focused on forming transition metal complexes of these pentazole derivatives, as the pentazole ring should be stabilised by bonding to the metal centre. (en) O 4-dimetilaminofenilpentazol é um composto instável e explosivo que contém um raro anel pentazol, formado por cinco átomos de nitrogênio. O efeito doador de densidade eletrônica do substituinte 4-dimetilamino no anel fenil confere a esse composto uma das maiores estabilidades dentre os fenilpentazois. À temperatura ambiente, sua meia-vida é de apenas algumas horas, mas é possível estocar a substância a baixas temperaturas. O composto foi sintetizado pela primeira vez em 1956, junto de outros fenilpentazois substituídos. Estudos foram conduzidos com vários outros derivados, apesar de bastante restritos em função da instabilidade desses compostos. Alguns derivados mais substituídos, como o 2,6-di-hidroxi-4-dimetilaminopenilpentazol, são um pouco mais estáveis, mas sua síntese é mais complicada. Pesquisas recentes têm focado esforços na formação de complexos de metais de transição desses derivados do pentazol, já que o anel presente deve ser estabilizado por meio de ligações a um centro de coordenação metálico. (pt) 4-(二甲基氨基)苯基五唑，是一个不稳定的、有的化合物，它包含了非常罕见的由五个氮原子组成的五唑环。苯环对位上的二甲基氨基的使得此化合物比苯基五唑更稳定。在室温下，其化学半衰期只有几个小时, 然而在超低温下储存是可能的。这个化合物在1956年与其他取代的芳基五唑一起被初次制备出来。对各种其他的衍生物的研究也在进行，但必定由于这些化合物的不稳定性而受到限制。 一些取代基更多的衍生物，如 2,6-二羟基-4-(二甲基氨基)苯基五唑，要稍微更稳定一些，但是反过来，制备这些衍生物的难度更大。目前的研究聚焦于形成这些五唑衍生物的过渡金属配合物，因为五唑环可能由于与金属中心的化学键而稳定下来。 (zh) |
| dbo:iupacName | N,N-Dimethyl-4-(1H-pentazol-1-yl)aniline (en) |
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| dbp:pin | N,N-Dimethyl-4-aniline (en) |
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| gold:hypernym | dbr:Compound |
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| rdfs:comment | 4-(二甲基氨基)苯基五唑，是一个不稳定的、有的化合物，它包含了非常罕见的由五个氮原子组成的五唑环。苯环对位上的二甲基氨基的使得此化合物比苯基五唑更稳定。在室温下，其化学半衰期只有几个小时, 然而在超低温下储存是可能的。这个化合物在1956年与其他取代的芳基五唑一起被初次制备出来。对各种其他的衍生物的研究也在进行，但必定由于这些化合物的不稳定性而受到限制。 一些取代基更多的衍生物，如 2,6-二羟基-4-(二甲基氨基)苯基五唑，要稍微更稳定一些，但是反过来，制备这些衍生物的难度更大。目前的研究聚焦于形成这些五唑衍生物的过渡金属配合物，因为五唑环可能由于与金属中心的化学键而稳定下来。 (zh) 4-Dimethylaminophenylpentazole is an unstable, explosive compound that contains the rare pentazole ring, which is composed of five nitrogen atoms. The electron donating effect of the 4-dimethylamino substituent on the phenyl ring makes this compound one of the more stable of the phenylpentazoles. At room temperature, its chemical half-life is only a few hours, although storage is possible at cryogenic temperatures. The compound was first prepared in 1956 along with other substituted phenylpentazoles. Studies have been conducted on various other derivatives, though necessarily limited by the instability of these compounds. Some more highly substituted derivatives, such as 2,6-dihydroxy-4-dimethylaminophenylpentazole, are slightly more stable but conversely, more difficult to make. Current r (en) O 4-dimetilaminofenilpentazol é um composto instável e explosivo que contém um raro anel pentazol, formado por cinco átomos de nitrogênio. O efeito doador de densidade eletrônica do substituinte 4-dimetilamino no anel fenil confere a esse composto uma das maiores estabilidades dentre os fenilpentazois. À temperatura ambiente, sua meia-vida é de apenas algumas horas, mas é possível estocar a substância a baixas temperaturas. (pt) |
| rdfs:label | 4-Dimethylaminophenylpentazole (en) 4-dimetilaminofenilpentazol (pt) 4-(二甲基氨基)苯基五唑 (zh) |
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