| dbo:abstract |
Dimethyldioxiran ist eine chemische Verbindung aus der Gruppe der Dioxirane, die nur in verdünnter Lösung bekannt ist. (de) Dimethyldioxirane (DMDO), also referred to as Murray's reagent in reference to Robert W. Murray, is a dioxirane derived from acetone and can be considered as a monomer of acetone peroxide. It is a powerful yet selective oxidizing agent which finds use in organic synthesis. It is known only in the form of a dilute solution, usually in acetone, and hence the properties of the pure material are largely unknown. (en) Le diméthyldioxirane (DMDO) est un dioxirane dérivé de l'acétone. C'est le seul dioxirane d'usage courant, c'est un réactif utilisé en synthèse organique. (fr) ジメチルジオキシラン (dimethyldioxirane) とは、有機化合物の一種で、有機合成において用いられる酸化剤。アセトン分子のC=O二重結合に酸素が付加して −C−O−O− 3員環（ジオキシラン環）となった構造を持つ化合物。DDOの略称で呼ばれる。他にDMD, DMDOなど。 酸素−酸素結合と3員環が不安定である点と、酸素を失った後に生成するアセトンが安定な分子である点から、ジメチルジオキシランはさまざまな化合物に速やかに酸素原子を与える酸化剤として優れる。ジメチルジオキシランを用いた酸化反応の基質選択性は比較的高い場合が多い。 (ja) Il dimetildiossirano (DMDO-DiMethylDiOxirane), anche detto reagente di Murray in riferimento al chimico Robert W. Murray, è un composto chimico derivato dal diossirano con acetone e può considerarsi come un monomero del perossido di acetone. È un potente agente ossidante selettivo che trova impiego in sintesi organica. È conosciuto solo nella forma di una soluzione diluita, solitamente in acetone, e quindi le proprietà del materiale puro sono in gran parte sconosciute. (it) 二甲基过氧化酮（DMDO），也称二甲基双环氧乙烷，是由丙酮衍生出的过氧化酮类化合物，分子中含有由过氧链组成的三元环系。它是唯一常用的过氧化酮类化合物，在有机合成中主要用作氧化剂。 (zh) |
| dbo:alternativeName |
DMDO (en) |
| dbo:iupacName |
3,3-Dimethyldioxirane (en) |
| dbo:thumbnail |
wiki-commons:Special:FilePath/Dimethyldioxirane_Structural_Formula_V.2.svg?width=300 |
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| dbp:imagefile |
DMDO3D.png (en) |
| dbp:imagefilel |
Dimethyldioxirane Structural Formula V.2.svg (en) |
| dbp:imagefiler |
DMDO-stick.png (en) |
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DMDO (en) |
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| dcterms:subject |
dbc:Organic_peroxides dbc:Oxidizing_agents dbc:Reagents_for_organic_chemistry dbc:Dioxiranes |
| gold:hypernym |
dbr:Dioxirane |
| rdf:type |
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| rdfs:comment |
Dimethyldioxiran ist eine chemische Verbindung aus der Gruppe der Dioxirane, die nur in verdünnter Lösung bekannt ist. (de) Dimethyldioxirane (DMDO), also referred to as Murray's reagent in reference to Robert W. Murray, is a dioxirane derived from acetone and can be considered as a monomer of acetone peroxide. It is a powerful yet selective oxidizing agent which finds use in organic synthesis. It is known only in the form of a dilute solution, usually in acetone, and hence the properties of the pure material are largely unknown. (en) Le diméthyldioxirane (DMDO) est un dioxirane dérivé de l'acétone. C'est le seul dioxirane d'usage courant, c'est un réactif utilisé en synthèse organique. (fr) ジメチルジオキシラン (dimethyldioxirane) とは、有機化合物の一種で、有機合成において用いられる酸化剤。アセトン分子のC=O二重結合に酸素が付加して −C−O−O− 3員環（ジオキシラン環）となった構造を持つ化合物。DDOの略称で呼ばれる。他にDMD, DMDOなど。 酸素−酸素結合と3員環が不安定である点と、酸素を失った後に生成するアセトンが安定な分子である点から、ジメチルジオキシランはさまざまな化合物に速やかに酸素原子を与える酸化剤として優れる。ジメチルジオキシランを用いた酸化反応の基質選択性は比較的高い場合が多い。 (ja) Il dimetildiossirano (DMDO-DiMethylDiOxirane), anche detto reagente di Murray in riferimento al chimico Robert W. Murray, è un composto chimico derivato dal diossirano con acetone e può considerarsi come un monomero del perossido di acetone. È un potente agente ossidante selettivo che trova impiego in sintesi organica. È conosciuto solo nella forma di una soluzione diluita, solitamente in acetone, e quindi le proprietà del materiale puro sono in gran parte sconosciute. (it) 二甲基过氧化酮（DMDO），也称二甲基双环氧乙烷，是由丙酮衍生出的过氧化酮类化合物，分子中含有由过氧链组成的三元环系。它是唯一常用的过氧化酮类化合物，在有机合成中主要用作氧化剂。 (zh) |
| rdfs:label |
Dimethyldioxiran (de) Dimethyldioxirane (en) Diméthyldioxirane (fr) Dimetildiossirano (it) ジメチルジオキシラン (ja) 二甲基过氧化酮 (zh) |
| owl:sameAs |
freebase:Dimethyldioxirane yago-res:Dimethyldioxirane wikidata:Dimethyldioxirane dbpedia-de:Dimethyldioxirane dbpedia-fa:Dimethyldioxirane dbpedia-fr:Dimethyldioxirane dbpedia-hu:Dimethyldioxirane dbpedia-it:Dimethyldioxirane dbpedia-ja:Dimethyldioxirane dbpedia-sh:Dimethyldioxirane dbpedia-sr:Dimethyldioxirane dbpedia-zh:Dimethyldioxirane https://global.dbpedia.org/id/4vCHz |
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wikipedia-en:Dimethyldioxirane?oldid=1051901365&ns=0 |
| foaf:depiction |
wiki-commons:Special:FilePath/DMDO-stick.png wiki-commons:Special:FilePath/DMDO3D.png wiki-commons:Special:FilePath/Dimethyldioxirane_Structural_Formula_V.2.svg wiki-commons:Special:FilePath/Dimethyldioxirane_Synthesis_V.2.svg wiki-commons:Special:FilePath/Dioxirane_oxidations.png wiki-commons:Special:FilePath/Nef_DMDO.png |
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wikipedia-en:Dimethyldioxirane |
| is dbo:wikiPageDisambiguates of |
dbr:DMD |
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dbr:DMDO |
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dbr:Potassium_peroxymonosulfate dbr:Rubottom_oxidation dbr:Epoxide dbr:Dewar_benzene dbr:C3H6O2 dbr:Thioanisole dbr:DMD dbr:Acetone_peroxide dbr:Cyclooctatetraene dbr:Danishefsky_Taxol_total_synthesis dbr:Bleaching_of_wood_pulp dbr:Coarctate_reaction dbr:Diisobutylamine dbr:Dioxirane dbr:DMDO dbr:Methaneseleninic_acid dbr:Methyldioxirane dbr:Oxidation_with_dioxiranes |
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wikipedia-en:Dimethyldioxirane |
