Haematopodin (original) (raw)
Haematopodin is the more stable breakdown product of Haematopodin B. Both compounds are found in the mushroom Mycena haematopus, although haematopodin only occurs in trace amounts in fresh fruit bodies. Similar pigments (with the 1,3,4,5-tetrahydropyrrolo[4,3,2-de]quinoline structure), known as and , have been found in sea sponges. A chemical synthesis for haematopodin was reported in 1996. Key steps in the synthesis involved the addition of 3-[(2,4-dimethoxybenzyl)amino]-1-propanol to the indolo-6,7-quinone and cyclization of the resulting adduct with trifluoroacetic acid.
| Property | Value |
|---|---|
| dbo:abstract | Haematopodin is the more stable breakdown product of Haematopodin B. Both compounds are found in the mushroom Mycena haematopus, although haematopodin only occurs in trace amounts in fresh fruit bodies. Similar pigments (with the 1,3,4,5-tetrahydropyrrolo[4,3,2-de]quinoline structure), known as and , have been found in sea sponges. A chemical synthesis for haematopodin was reported in 1996. Key steps in the synthesis involved the addition of 3-[(2,4-dimethoxybenzyl)amino]-1-propanol to the indolo-6,7-quinone and cyclization of the resulting adduct with trifluoroacetic acid. (en) ヘマトポジン(Haematopodin)は、ヘマトポジンBよりも安定なヘマトポジンBの分解生成物である。両方の化合物が(Mycena haematopus)で見られるが、ヘマトポジンだけは担子器果でも痕跡量が見られる。batzellinやdamironeとして知られる、1,3,4,5-テトラヒドロピロール[4,3,2-デ]キノリン構造を持つ類似の色素は、海綿動物で見られる。ヘマトポジンの化学合成は1996年に報告されている。合成の重要な段階は、3-[(2,4-ジメトキシベンジル)アミノ]-1-プロパノールのインドール-6,7-キノンへの付加と、トリフルオロ酢酸中でのこのの環化である。 (ja) |
| dbo:iupacName | (6aR)-6,6a,9,10-Tetrahydro-2H,8H-[1,3]oxazolo[3,2-a]pyrrolo[4,3,2-de]quinoline-2,3(4H)-dione (en) |
| dbo:thumbnail | wiki-commons:Special:FilePath/Haematopodin.png?width=300 |
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| dbo:wikiPageLength | 3012 (xsd:nonNegativeInteger) |
| dbo:wikiPageRevisionID | 1105093268 (xsd:integer) |
| dbo:wikiPageWikiLink | dbc:Biological_pigments dbr:Cyclic_compound dbc:Enones dbc:Heterocyclic_compounds_with_4_rings dbc:Nitrogen_heterocycles dbc:Oxygen_heterocycles dbc:Tetracyclic_compounds dbr:Pigment dbr:Organic_synthesis dbc:Quinoline_alkaloids dbr:Addition_reaction dbr:Adduct dbr:Trifluoroacetic_acid dbr:Basidiocarp dbc:Quinones dbr:Haematopodin_B dbc:Alkaloids_found_in_fungi dbr:Mycena_haematopus dbr:Sea_sponge dbr:Batzellin dbr:Damirone |
| dbp:imagefile | Haematopodin.png (en) |
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| dbp:watchedfields | changed (en) |
| dbp:wikiPageUsesTemplate | dbt:Chembox dbt:Chembox_Hazards dbt:Chembox_Identifiers dbt:Chembox_Properties dbt:Heterocyclic-stub dbt:Reflist dbt:Chemspidercite dbt:Fdacite dbt:Stdinchicite |
| dcterms:subject | dbc:Biological_pigments dbc:Enones dbc:Heterocyclic_compounds_with_4_rings dbc:Nitrogen_heterocycles dbc:Oxygen_heterocycles dbc:Tetracyclic_compounds dbc:Quinoline_alkaloids dbc:Quinones dbc:Alkaloids_found_in_fungi |
| rdf:type | owl:Thing dul:ChemicalObject dbo:ChemicalSubstance wikidata:Q11173 yago:WikicatBiologicalPigments yago:WikicatNitrogenHeterocycles yago:WikicatOxygenHeterocycles yago:Abstraction100002137 yago:Alkaloid114712692 yago:Chemical114806838 yago:ColoringMaterial114984973 yago:Compound114818238 yago:HeterocyclicCompound115025397 yago:Material114580897 yago:Matter100020827 yago:OrganicCompound114727670 yago:Part113809207 yago:PhysicalEntity100001930 yago:Pigment114989820 yago:Quinone115000973 yago:Relation100031921 dbo:ChemicalCompound yago:Substance100019613 yago:WikicatAlkaloids yago:WikicatQuinones |
| rdfs:comment | Haematopodin is the more stable breakdown product of Haematopodin B. Both compounds are found in the mushroom Mycena haematopus, although haematopodin only occurs in trace amounts in fresh fruit bodies. Similar pigments (with the 1,3,4,5-tetrahydropyrrolo[4,3,2-de]quinoline structure), known as and , have been found in sea sponges. A chemical synthesis for haematopodin was reported in 1996. Key steps in the synthesis involved the addition of 3-[(2,4-dimethoxybenzyl)amino]-1-propanol to the indolo-6,7-quinone and cyclization of the resulting adduct with trifluoroacetic acid. (en) ヘマトポジン(Haematopodin)は、ヘマトポジンBよりも安定なヘマトポジンBの分解生成物である。両方の化合物が(Mycena haematopus)で見られるが、ヘマトポジンだけは担子器果でも痕跡量が見られる。batzellinやdamironeとして知られる、1,3,4,5-テトラヒドロピロール[4,3,2-デ]キノリン構造を持つ類似の色素は、海綿動物で見られる。ヘマトポジンの化学合成は1996年に報告されている。合成の重要な段階は、3-[(2,4-ジメトキシベンジル)アミノ]-1-プロパノールのインドール-6,7-キノンへの付加と、トリフルオロ酢酸中でのこのの環化である。 (ja) |
| rdfs:label | Haematopodin (en) ヘマトポジン (ja) |
| owl:sameAs | freebase:Haematopodin yago-res:Haematopodin wikidata:Haematopodin dbpedia-fa:Haematopodin dbpedia-ja:Haematopodin dbpedia-sh:Haematopodin dbpedia-sr:Haematopodin https://global.dbpedia.org/id/4keGu |
| prov:wasDerivedFrom | wikipedia-en:Haematopodin?oldid=1105093268&ns=0 |
| foaf:depiction | wiki-commons:Special:FilePath/Haematopodin.png |
| foaf:isPrimaryTopicOf | wikipedia-en:Haematopodin |
| is dbo:wikiPageWikiLink of | dbr:C13H12N2O3 dbr:Haematopodin_B dbr:Mycena_haematopus |
| is foaf:primaryTopic of | wikipedia-en:Haematopodin |
