Monocyclic monoterpene ketone monooxygenase (original) (raw)

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Monocyclic monoterpene ketone monooxygenase (EC 1.14.13.105, 1-hydroxy-2-oxolimonene 1,2-monooxygenase, dihydrocarvone 1,2-monooxygenase, MMKMO) is an enzyme with systematic name (-)-menthone,NADPH:oxygen oxidoreductase. This enzyme catalyses the following chemical reaction Monocyclic monoterpene ketone monooxygenase is a flavoprotein (FAD).

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dbo:abstract Monocyclic monoterpene ketone monooxygenase (EC 1.14.13.105, 1-hydroxy-2-oxolimonene 1,2-monooxygenase, dihydrocarvone 1,2-monooxygenase, MMKMO) is an enzyme with systematic name (-)-menthone,NADPH:oxygen oxidoreductase. This enzyme catalyses the following chemical reaction (1) (-)-menthone + NADPH + H+ + O2 (4R,7S)-7-isopropyl-4-methyloxepan-2-one + NADP+ + H2O(2) dihydrocarvone + NADPH + H+ + O2 4-isopropenyl-7-methyloxepan-2-one + NADP+ + H2O(3) (iso)-dihydrocarvone + NADPH + H+ + O2 6-isopropenyl-3-methyloxepan-2-one + NADP+ + H2O(4a) 1-hydroxymenth-8-en-2-one + NADPH + H+ + O2 7-hydroxy-4-isopropenyl-7-methyloxepan-2-one + NADP+ + H2O(4b) 7-hydroxy-4-isopropenyl-7-methyloxepan-2-one 3-isopropenyl-6-oxoheptanoate (spontaneous) Monocyclic monoterpene ketone monooxygenase is a flavoprotein (FAD). (en) 単環式モノテルペンケトンモノオキシゲナーゼ(monocyclic monoterpene ketone monooxygenase)は、次の化学反応を触媒する酸化還元酵素である。 * (1) (–)-メントン + NADPH + H+ + O2 (4R,7S)-7-イソプロピル-4-メチルオキセパン-2-オン + NADP+ + H2O * (2) ジヒドロカルボン + NADPH + H+ + O2 4-イソプロピル-7-メチルオキセパン-2-オン + NADP+ + H2O * (3) (iso)-ジヒドロカルボン + NADPH + H+ + O2 6-イソプロペニル-3-メチルオキセパン-2-オン + NADP+ + H2O * (4a) 1-ヒドロキシメント-8-エン-2-オン + NADPH + H+ + O2 7-ヒドロキシ-4-イソプロペニル-7-メチルオキセパン-2-オン + NADP+ + H2O * (4b) 7-ヒドロキシ-4-イソプロペニル-7-メチルオキセパン-2-オン 3-イソプロペニル-6-オキソヘプタン酸 (自発的) 組織名は(–)-menthone,NADPH:oxygen oxidoreductaseで、別名に1-hydroxy-2-oxolimonene 1,2-monooxygenase、dihydrocarvone 1,2-monooxygenase、MMKMOがある。 (ja)
dbo:ecNumber 1.14.13.105
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dbp:name Monocyclic monoterpene ketone monooxygenase (en)
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rdfs:comment Monocyclic monoterpene ketone monooxygenase (EC 1.14.13.105, 1-hydroxy-2-oxolimonene 1,2-monooxygenase, dihydrocarvone 1,2-monooxygenase, MMKMO) is an enzyme with systematic name (-)-menthone,NADPH:oxygen oxidoreductase. This enzyme catalyses the following chemical reaction Monocyclic monoterpene ketone monooxygenase is a flavoprotein (FAD). (en) 単環式モノテルペンケトンモノオキシゲナーゼ(monocyclic monoterpene ketone monooxygenase)は、次の化学反応を触媒する酸化還元酵素である。 * (1) (–)-メントン + NADPH + H+ + O2 (4R,7S)-7-イソプロピル-4-メチルオキセパン-2-オン + NADP+ + H2O * (2) ジヒドロカルボン + NADPH + H+ + O2 4-イソプロピル-7-メチルオキセパン-2-オン + NADP+ + H2O * (3) (iso)-ジヒドロカルボン + NADPH + H+ + O2 6-イソプロペニル-3-メチルオキセパン-2-オン + NADP+ + H2O * (4a) 1-ヒドロキシメント-8-エン-2-オン + NADPH + H+ + O2 7-ヒドロキシ-4-イソプロペニル-7-メチルオキセパン-2-オン + NADP+ + H2O * (4b) 7-ヒドロキシ-4-イソプロペニル-7-メチルオキセパン-2-オン 3-イソプロペニル-6-オキソヘプタン酸 (自発的) (ja)
rdfs:label Monocyclic monoterpene ketone monooxygenase (en) 単環式モノテルペンケトンモノオキシゲナーゼ (ja)
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