| dbo:abstract |
Phanephos is an organophosphorus compound with the chemical formula (C2H4)2(C6H3PPh2)2 (Ph = C6H5). It is a white solid that is soluble in organic solvents. It is an example of a chiral C2-symmetric diphosphine ligand used in asymmetric hydrogenation. Many substituents have been introduced in place of the phenyl groups, e.g., i-Pr, C6H11, etc and a variety of chiral diphosphine ligands have been reported in asymmetric catalysis since the 1960s. (en) |
| dbo:alternativeName |
(S)-Phanephos; (R)-Phanephos (en) |
| dbo:iupacName |
(S)-(+)-4,12-Bis(diphenylphosphino)-[2.2]-paracyclophane; (R)-(−)-4,12-Bis(diphenylphosphino)-[2.2]-paracyclophane (en) |
| dbo:thumbnail |
wiki-commons:Special:FilePath/Diphosphino_phanephos.png?width=300 |
| dbo:wikiPageID |
40708524 (xsd:integer) |
| dbo:wikiPageLength |
3280 (xsd:nonNegativeInteger) |
| dbo:wikiPageRevisionID |
1118577879 (xsd:integer) |
| dbo:wikiPageWikiLink |
dbr:Rhodium dbr:Ruthenium dbc:Chelating_agents dbc:Diphosphines dbc:Phenyl_compounds dbr:N-Butyllithium dbc:Cyclophanes dbr:Atropisomer dbr:Hydrogenation dbr:Chlorodiphenylphosphine dbr:C2-Symmetric_ligands dbr:Organophosphorus_compound dbr:Paracyclophane dbr:Phenyl dbr:Diphosphine dbr:File:Phanphos_preparation.png |
| dbp:imagefile |
Diphosphino phanephos.png (en) |
| dbp:imagesize |
150 (xsd:integer) |
| dbp:iupacname |
--4,12-Bis-[2.2]-paracyclophane; --4,12-Bis-[2.2]-paracyclophane (en) |
| dbp:othernames |
-Phanephos; -Phanephos (en) |
| dbp:wikiPageUsesTemplate |
dbt:Chembox dbt:Chembox_Hazards dbt:Chembox_Identifiers dbt:Chembox_Properties dbt:Clear-left dbt:Cascite |
| dct:subject |
dbc:Chelating_agents dbc:Diphosphines dbc:Phenyl_compounds dbc:Cyclophanes |
| gold:hypernym |
dbr:Compound |
| rdf:type |
owl:Thing dul:ChemicalObject dbo:ChemicalSubstance wikidata:Q11173 yago:WikicatChelatingAgents yago:Agent109190918 yago:CausalAgent100007347 yago:PhysicalEntity100001930 dbo:ChemicalCompound |
| rdfs:comment |
Phanephos is an organophosphorus compound with the chemical formula (C2H4)2(C6H3PPh2)2 (Ph = C6H5). It is a white solid that is soluble in organic solvents. It is an example of a chiral C2-symmetric diphosphine ligand used in asymmetric hydrogenation. Many substituents have been introduced in place of the phenyl groups, e.g., i-Pr, C6H11, etc and a variety of chiral diphosphine ligands have been reported in asymmetric catalysis since the 1960s. (en) |
| rdfs:label |
Phanephos (en) |
| owl:sameAs |
freebase:Phanephos yago-res:Phanephos wikidata:Phanephos https://global.dbpedia.org/id/ZFLs |
| prov:wasDerivedFrom |
wikipedia-en:Phanephos?oldid=1118577879&ns=0 |
| foaf:depiction |
wiki-commons:Special:FilePath/Diphosphino_phanephos.png wiki-commons:Special:FilePath/Phanphos_preparation.png |
| foaf:isPrimaryTopicOf |
wikipedia-en:Phanephos |
| is foaf:primaryTopic of |
wikipedia-en:Phanephos |
