Ruthenium pentafluoride (original) (raw)
Fluorid rutheničný je chemická sloučenina se vzorcem RuF5. Je to tmavě zelená látka s teplotou tání 86,5 °C. Je citlivý na hydrolýzu vzdušnou vlhkostí. Krystalická struktura sestává z tetramerů Ru4F20, v nichž mají všechny atomy ruthenia oktaedrickou konfiguraci a jsou propojeny dvěma sdílenými můstkovými fluoridy (vrcholy oktaedru).
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| dbo:abstract | Fluorid rutheničný je chemická sloučenina se vzorcem RuF5. Je to tmavě zelená látka s teplotou tání 86,5 °C. Je citlivý na hydrolýzu vzdušnou vlhkostí. Krystalická struktura sestává z tetramerů Ru4F20, v nichž mají všechny atomy ruthenia oktaedrickou konfiguraci a jsou propojeny dvěma sdílenými můstkovými fluoridy (vrcholy oktaedru). (cs) Ruthenium(V)-fluorid ist eine chemische Verbindung des Rutheniums und zählt zu den Fluoriden. Es handelt sich um einen smaragdgrünen Feststoff. (de) Ruthenium pentafluoride is the inorganic compound with the empirical formula RuF5. This green volatile solid has rarely been studied but is of interest as a binary fluoride of ruthenium, i.e. a compound containing only Ru and F. It is sensitive toward hydrolysis. Its structure consists of Ru4F20 tetramers, as seen in the isostructural platinum pentafluoride. Within the tetramers, each Ru adopts octahedral molecular geometry, with two bridging fluoride ligands. Ruthenium pentafluoride reacts with iodine to give ruthenium(III) fluoride. (en) Il pentafluoruro di rutenio è il composto inorganico con formula RuF5. In questo fluoruro il rutenio è nello stato di ossidazione +5. In condizioni normali è un solido volatile di colore verde scuro; allo stato vapore è incolore. È un composto estremamente reattivo, senza usi pratici, pericoloso da utilizzare dato che reagisce formando fluoro e acido fluoridrico. (it) 五フッ化ルテニウム（ごフッかルテニウム、Ruthenium pentafluoride）は、実験式RuF5で表される無機化合物。フッ化ルテニウム(V)(Ruthenium(V) fluoride)とも。緑色で揮発性の固体である。ほとんど研究されることはないが、ルテニウムの二元フッ化物、つまりRuとFのみを含む化合物として興味深いものである。加水分解に対して敏感である。同じ構造の五フッ化白金に見られるようにその構造はRu4F20四量体で作られる。四量体内では各Ruは八面体形分子構造をとり、2つの架橋フッ化物配位子を持つ。 (ja) Фторид рутения(V) — неорганическое соединение, соль металла рутения и плавиковой кислоты с формулой RuF5,тёмно-зелёные кристаллы,реагирует с водой,разъедает стекло. (ru) 五氟化钌是一种无机化合物，最简式为RuF5。人们很少研究这种绿色的挥发性固体，但是作为钌的二元氟化物，即仅包含钌和氟的化合物而受到关注。它很容易水解。如同五氟化铂的结构，其结构是Ru4F20，为四聚体。在四聚体中，每个钌原子都采用，并带有两个桥接氟原子配体。 (zh) |
| dbo:alternativeName | Ruthenium(V) fluoride, Ruthenium(5+) pentafluoride (en) |
| dbo:iupacName | ruthenium(V) fluoride (en) |
| dbo:thumbnail | wiki-commons:Special:FilePath/Unit_cell_of_OsF5.png?width=300 |
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| dbo:wikiPageLength | 2196 (xsd:nonNegativeInteger) |
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| dbp:imagefile | PtF5solid.tif (en) Unit_cell__of_OsF5.png (en) |
| dbp:imagesize | 264 (xsd:integer) |
| dbp:iupacname | ruthenium fluoride (en) |
| dbp:othernames | Ruthenium fluoride, Ruthenium pentafluoride (en) |
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| dcterms:subject | dbc:Fluorides dbc:Ruthenium_compounds dbc:Platinum_group_halides |
| gold:hypernym | dbr:Compound |
| rdf:type | owl:Thing dul:ChemicalObject dbo:ChemicalSubstance wikidata:Q11173 dbo:ChemicalCompound |
| rdfs:comment | Fluorid rutheničný je chemická sloučenina se vzorcem RuF5. Je to tmavě zelená látka s teplotou tání 86,5 °C. Je citlivý na hydrolýzu vzdušnou vlhkostí. Krystalická struktura sestává z tetramerů Ru4F20, v nichž mají všechny atomy ruthenia oktaedrickou konfiguraci a jsou propojeny dvěma sdílenými můstkovými fluoridy (vrcholy oktaedru). (cs) Ruthenium(V)-fluorid ist eine chemische Verbindung des Rutheniums und zählt zu den Fluoriden. Es handelt sich um einen smaragdgrünen Feststoff. (de) Ruthenium pentafluoride is the inorganic compound with the empirical formula RuF5. This green volatile solid has rarely been studied but is of interest as a binary fluoride of ruthenium, i.e. a compound containing only Ru and F. It is sensitive toward hydrolysis. Its structure consists of Ru4F20 tetramers, as seen in the isostructural platinum pentafluoride. Within the tetramers, each Ru adopts octahedral molecular geometry, with two bridging fluoride ligands. Ruthenium pentafluoride reacts with iodine to give ruthenium(III) fluoride. (en) Il pentafluoruro di rutenio è il composto inorganico con formula RuF5. In questo fluoruro il rutenio è nello stato di ossidazione +5. In condizioni normali è un solido volatile di colore verde scuro; allo stato vapore è incolore. È un composto estremamente reattivo, senza usi pratici, pericoloso da utilizzare dato che reagisce formando fluoro e acido fluoridrico. (it) 五フッ化ルテニウム（ごフッかルテニウム、Ruthenium pentafluoride）は、実験式RuF5で表される無機化合物。フッ化ルテニウム(V)(Ruthenium(V) fluoride)とも。緑色で揮発性の固体である。ほとんど研究されることはないが、ルテニウムの二元フッ化物、つまりRuとFのみを含む化合物として興味深いものである。加水分解に対して敏感である。同じ構造の五フッ化白金に見られるようにその構造はRu4F20四量体で作られる。四量体内では各Ruは八面体形分子構造をとり、2つの架橋フッ化物配位子を持つ。 (ja) Фторид рутения(V) — неорганическое соединение, соль металла рутения и плавиковой кислоты с формулой RuF5,тёмно-зелёные кристаллы,реагирует с водой,разъедает стекло. (ru) 五氟化钌是一种无机化合物，最简式为RuF5。人们很少研究这种绿色的挥发性固体，但是作为钌的二元氟化物，即仅包含钌和氟的化合物而受到关注。它很容易水解。如同五氟化铂的结构，其结构是Ru4F20，为四聚体。在四聚体中，每个钌原子都采用，并带有两个桥接氟原子配体。 (zh) |
| rdfs:label | Fluorid rutheničný (cs) Ruthenium(V)-fluorid (de) Pentafluoruro di rutenio (it) 五フッ化ルテニウム (ja) Ruthenium pentafluoride (en) Фторид рутения(V) (ru) 五氟化钌 (zh) |
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| foaf:depiction | wiki-commons:Special:FilePath/Unit_cell_of_OsF5.png |
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