(Terpyridine)ruthenium trichloride (original) (raw)
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(Terpyridine)ruthenium trichloride
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| Identifiers | |
| CAS Number | 72905-30-7  Y |
| 3D model (JSmol) | Interactive image |
| ChemSpider | 9179899 |
| PubChem CID | 11004708 |
| InChI InChI=1S/C15H11N3.3ClH.Ru/c1-3-10-16-12(6-1)14-8-5-9-15(18-14)13-7-2-4-11-17-13;;;;/h1-11H;3*1H;/q;;;;+3/p-3Key: YDKDTFLOHRMCRP-UHFFFAOYSA-K | |
| SMILES c1ccnc(c1)c2cccc(n2)c3ccccn3.[Ru+3].[Cl-].[Cl-].[Cl-] | |
| Properties | |
| Chemical formula | C15H11Cl3N3Ru |
| Molar mass | 440.69 g·mol−1 |
| Appearance | brown solid |
| Density | 1.451 g/cm3 |
| Solubility in water | insoluble |
| Hazards | |
| GHS labelling: | |
| Signal word | Warning |
| Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references |
Chemical compound
(Terpyridine)ruthenium trichloride is the coordination complex with the formula RuCl3(terpy), where terpy is terpyridine. It is a brown paramagnetic solid that is a precursor to other complexes of ruthenium, mainly by substitution of the chloride ligands. The complex has octahedral geometry.[1] The synthesis of this complex was reported for the first time in 1980, it was prepared by mixing ruthenium trichloride and terpyridine in ethanol, heating the mixture to reflux conditions[2] A later synthetic protocol uses a similar approach by heating ruthenium trichloride with a DMF solution of terpyridine.[3]
- ^ Ziegler, Marco; Monney, Véronique; Stoeckli-Evans, Helen; von Zelewsky, Alex; Sasaki, Isabelle; Dupic, Gilles; Daran, Jean-Claude; Balavoine, Gilbert G. A. (1999). "Complexes of New Chiral Terpyridyl Ligands. Synthesis and Characterization of Their Ruthenium(II) and Rhodium(III) Complexes". Journal of the Chemical Society, Dalton Transactions (5): 667–676. doi:10.1039/a900194h.
- ^ Sullivan, B. Patrick; Calvert, Jeffrey M.; Meyer, Thomas J. (May 1980). "Cis-trans isomerism in (trpy)(PPh3)RuC12. Comparisons between the chemical and physical properties of a cis-trans isomeric pair". Inorganic Chemistry. 19 (5): 1404–1407. doi:10.1021/ic50207a066. ISSN 0020-1669.
- ^ Bessel, Carol A.; Leising, Randolph A.; Szczepura, Lisa F.; Perez, Willie J.; Vo Huyhn, My Hang; Takeuchi, Kenneth J. (1998). "Trichloro[2,2′:6′,2″-Terpyridine]Ruthenium(III) and Phosphine Ligand Derivatives". Inorganic Syntheses. Vol. 32. p. 186-198. doi:10.1002/9780470132630.ch32. ISBN 9780471249214.