Atacamite (original) (raw)

From Wikipedia, the free encyclopedia

Halide evaporite mineral

Atacamite
Atacamite from Mt. Gunson mines, South Australia
General
Category Halide mineral
Formula(repeating unit) Cu2Cl(OH)3
IMA symbol Ata[1]
Strunz classification 3.DA.10a
Crystal system Orthorhombic
Crystal class Dipyramidal (mmm) H-M symbol: (2/m 2/m 2/m)
Space group Pnma
Unit cell a = 6.03, b = 9.12 c = 6.865 [Å]; Z = 4
Identification
Color Bright green, dark emerald-green to blackish green
Crystal habit Slender prismatic crystals, fibrous, granular to compact, massive
Twinning Contact and penetration with complex twinned groupings
Cleavage Perfect on {010}, fair on {101}
Fracture Conchoidal
Tenacity Brittle
Mohs scale hardness 3–3.5
Luster Adamantine to vitreous
Streak Apple green
Diaphaneity Transparent to translucent
Specific gravity 3.745–3.776
Optical properties Biaxial (−)
Refractive index nα = 1.831 nβ = 1.861 nγ = 1.880
Birefringence δ = 0.049
Pleochroism X = pale green; Y = yellow-green; Z = grass-green
2V angle Calculated: 74°
Dispersion r < v, strong
References [2][3][4][5]

Atacamite is a copper halide mineral: a copper(II) chloride hydroxide with formula Cu2Cl(OH)3. It was first described for deposits in the Atacama Desert of Chile in 1802 by Dmitri de Gallitzin.[2] The Atacama Desert is also the namesake of the mineral.

Atacamite is polymorphous with botallackite, clinoatacamite, and paratacamite.[2] Atacamite is a comparatively rare mineral, formed from primary copper minerals in the oxidation or weathering zone of arid climates. It has also been reported as a volcanic sublimate from fumarole deposits, as sulfide alteration products in black smokers.[3] The mineral has also been found naturally on oxidized copper deposits in Chile, China, Russia, Czech Republic, Arizona, and Australia.[6] It occurs in association with cuprite, brochantite, linarite, caledonite, malachite, chrysocolla and its polymorphs.[3]

Synthetic Occurrence

[edit]

Atacamite has been discovered in the patina of the Statue of Liberty, and as alteration of ancient bronze and copper artifacts. The mineral has been found as a pigment in sculpture, manuscripts, maps, and frescoes discovered in Eurasia, Russia, and Persia.[6]

Atacamite occurs as a biomineral in the jaws of bloodworms.[7][8]

Wikimedia Commons has media related to Atacamite.

  1. ^ Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi:10.1180/mgm.2021.43. S2CID 235729616.
  2. ^ a b c Atacamite on Mindat.org
  3. ^ a b c Handbook of Mineralogy
  4. ^ Atacamite on Webmineral
  5. ^ Mineralienatlas
  6. ^ a b "Atacamite – CAMEO". cameo.mfa.org. Retrieved 2017-10-15.
  7. ^ Lichtenegger HC, Schöberl T, Bartl MH, Waite H, Stucky GD (October 2002). "High abrasion resistance with sparse mineralization: copper biomineral in worm jaws". Science. 298 (5592): 389–92. Bibcode:2002Sci...298..389L. doi:10.1126/science.1075433. PMID 12376695. S2CID 14001250.
  8. ^ Lichtenegger HC, Schöberl T, Ruokolainen JT, et al. (August 2003). "Zinc and mechanical prowess in the jaws of Nereis, a marine worm". Proc. Natl. Acad. Sci. U.S.A. 100 (16): 9144–9. Bibcode:2003PNAS..100.9144L. doi:10.1073/pnas.1632658100. PMC 170886. PMID 12886017.