Diphosphene (original) (raw)

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Diphosphene

Ball and stick model of diphosphene moleculeBall and stick model of diphosphene molecule
Identifiers
CAS Number 41916-72-7 checkY
3D model (JSmol) Interactive image
ChemSpider 125761 checkY
PubChem CID 142559
CompTox Dashboard (EPA) DTXSID50194680 Edit this at Wikidata
InChI InChI=1S/H2P2/c1-2/h1-2H checkYKey: SWJAOBXRZSMKNS-UHFFFAOYSA-N checkY
SMILES P=P
Properties
Chemical formula P2H2
Molar mass 63.96340 g·mol−1
Related compounds
Other anions diazene
Other cations diphosphenes
Related Binary azenes triazenetetrazene
Related compounds ammoniadiazanetriazane
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). checkY verify (what is checkY☒N ?) Infobox references

Chemical compound

Diphosphene is a compound having the formula (PH)2. It exists as two geometric isomers, E and Z.[1] Diphosphene is also the parent member of the entire class of diphosphene compounds with the formula (PR)2, where R is an organyl group.[2]

  1. ^ Lu, T.; Simmonett, A. C.; Evangelista, F. A.; Yamaguchi, Y.; Schaefer, H. F. (2009). "Diphosphene and Diphosphinylidene". The Journal of Physical Chemistry A. 113 (47): 13227–13236. Bibcode:2009JPCA..11313227L. doi:10.1021/jp904028a. PMID 19594123.
  2. ^ Yoshifuji, M.; Shibayama, K.; Inamoto, N.; Hirotsu, K.; Higuchi, T. (1983). "Reaction of the diphosphene ArP=PAr (Ar = 2,4,6-But3C6H2) with sulphur: isolation and X-ray structure of the diphosphene monosulphide". Journal of the Chemical Society, Chemical Communications. 1983 (16): 862–863. doi:10.1039/C39830000862.