Dysprosium(III) nitrate (original) (raw)

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Dysprosium(III) nitrate

Names
Other namesDysprosium nitrate, Dysprosium trinitrate
Identifiers
CAS Number	10143-38-1 Nmonhydrate: 100641-13-2pentahydrate: 10031-49-9hexahydrate: 35725-30-5
3D model (JSmol)	Interactive imagemonhydrate: Interactive imagepentahydrate: Interactive imagehexahydrate: Interactive image
ChemSpider	23375monhydrate: 26666880pentahydrate: 21241308hexahydrate: 186810
ECHA InfoCard	100.030.360
EC Number	233-410-5pentahydrate: 629-564-1
PubChem CID	25007monhydrate: 57346095pentahydrate: 91886635hexahydrate: 215463
CompTox Dashboard (EPA)	DTXSID60890646 monhydrate: DTXSID80721100hexahydrate: DTXSID50189253
InChI InChI=1S/Dy.3NO3/c;3*2-1(3)4/q+3;3*-1Key: DVENVBCPDCQQGD-UHFFFAOYSA-Nmonhydrate: InChI=1S/Dy.3NO3.H2O/c;3*2-1(3)4;/h;;;;1H2/q+3;3*-1;Key: DSEBQRTVZFLVND-UHFFFAOYSA-Npentahydrate: InChI=1S/Dy.3NO3.5H2O/c;3*2-1(3)4;;;;;/h;;;;5*1H2/q+3;3*-1;;;;;Key: NOTQUFQJAWMLCE-UHFFFAOYSA-Nhexahydrate: InChI=1S/Dy.3NO3.6H2O/c;3*2-1(3)4;;;;;;/h;;;;6*1H2/q+3;3*-1;;;;;;Key: DCKWZDOAGNMKMX-UHFFFAOYSA-N
SMILES O.[Dy+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=Omonhydrate: [N+](=O)([O-])[O-].[N+](=O)([O-])[O-].[N+](=O)([O-])[O-].O.[Dy+3]pentahydrate: [N+](=O)([O-])[O-].[N+](=O)([O-])[O-].[N+](=O)([O-])[O-].O.O.O.O.O.[Dy+3]hexahydrate: [N+](=O)([O-])[O-].[N+](=O)([O-])[O-].[N+](=O)([O-])[O-].O.O.O.O.O.O.[Dy+3]
Properties
Chemical formula	Dy(NO3)3
Molar mass	348.51
Appearance	Yellowish crystals
Melting point	88.6[1] °C (191.5 °F; 361.8 K)
Solubility in water	Soluble
Hazards
GHS labelling:
Pictograms
Signal word	Warning
Hazard statements	H272, H315, H319, H335
Precautionary statements	P210, P220, P221, P261, P264, P271, P280, P302+P352, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P370+P378, P403+P233, P405, P501
Related compounds
Related compounds	Terbium(III) nitrate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

Chemical compound

Dysprosium(III) nitrate is an inorganic compound, a salt of dysprosium and nitric acid with the chemical formula Dy(NO3)3. The compound forms yellowish crystals, dissolves in water, forms a crystalline hydrate.[2]

Anhydrous salt is obtained by the action of nitrogen dioxide on dysprosium(III) oxide:[3]

2 D y 2 O 3 + 9 N 2 O 4 → 150 o C 4 D y ( N O 3 ) 3 + 6 N O {\displaystyle {\mathsf {2Dy_{2}O_{3}+9N_{2}O_{4}\ {\xrightarrow {150^{o}C}}\ 4Dy(NO_{3})_{3}+6NO}}}

The action of nitrogen dioxide on metallic dysprosium:

D y + 3 N 2 O 4 → 200 o C D y ( N O 3 ) 3 + 3 N O {\displaystyle {\mathsf {Dy+3N_{2}O_{4}\ {\xrightarrow {200^{o}C}}\ Dy(NO_{3})_{3}+3NO}}}

Physical properties

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Dysprosium(III) nitrate forms yellowish crystals.[4]

The anhydrous nitrate forms a crystalline hydrate in wet air with the ideal composition of Dy(NO3)3·5H2O, which melts in its own crystallization water at 88.6 °C.[5][6]

All hydrates (anhydrous, pentahydrate, and hexahydrate) are soluble in water and ethanol, hygroscopic.

Chemical properties

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Hydrated dysprosium nitrate thermally decomposes to form DyONO3,[_citation needed_] and further heating produces dysprosium oxide.

Dysprosium(III) nitrate is used as a catalyst.

1. ^ "Dysprosium(III) nitrate | CAS 10031-49-9". scbt.com. Retrieved 18 August 2021.
2. ^ Macintyre, Jane E. (23 July 1992). Dictionary of Inorganic Compounds. CRC Press. p. 3117. ISBN 978-0-412-30120-9. Retrieved 18 August 2021.
3. ^ Edelmann, Frank T.; Herrmann, Wolfgang A. (14 May 2014). Synthetic Methods of Organometallic and Inorganic Chemistry, Volume 6, 1997: Volume 6: Lanthanides and Actinides. Georg Thieme Verlag. p. 23. ISBN 978-3-13-179221-1. Retrieved 18 August 2021.
4. ^ "Dysprosium(III) nitrate - Hazardous Agents | Haz-Map". haz-map.com. Retrieved 18 August 2021.
5. ^ "Dysprosium(III) nitrate hydrate". Sigma Aldrich. Retrieved 18 August 2021.
6. ^ "10031-49-9 - Dysprosium(III) nitrate pentahydrate, 99.9% (REO) - 12922 - Alfa Aesar". Alfa Aesar. Retrieved 18 August 2021.