Sodium methanethiolate (original) (raw)

From Wikipedia, the free encyclopedia

For sodium 2-mercaptoethanesulfonate, see Mesna.

Sodium methanethiolate

Names
Preferred IUPAC name Sodium methanethiolate
Other namessodium thiomethoxide, sodium methyl mercaptide, sodium thiomethylate, methanethiol sodium salt, methyl mercaptan sodium salt
Identifiers
CAS Number 5188-07-8 checkY
3D model (JSmol) Interactive image
ChemSpider 71198 checkY
ECHA InfoCard 100.023.609 Edit this at Wikidata
EC Number 225-969-9
PubChem CID 4378561
UNII LB29JWW8H7 ☒N
CompTox Dashboard (EPA) DTXSID7027592 Edit this at Wikidata
InChI InChI=1S/CH4S.Na/c1-2;/h2H,1H3;/q;+1/p-1 checkYKey: RMBAVIFYHOYIFM-UHFFFAOYSA-M checkYInChI=1/CH4S.Na/c1-2;/h2H,1H3;/q;+1/p-1
SMILES [Na+].[S-]C
Properties
Chemical formula CH3NaS
Molar mass 70.08 g·mol−1
Appearance yellow-red[1]
Solubility in water soluble[1]
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). ☒N verify (what is checkY☒N ?) Infobox references

Chemical compound

Sodium methanethiolate or sodium thiomethoxide (CH3SNa, MeSNa) is the sodium conjugate base of methanethiol. This compound is commercially available as a white solid. It is a powerful nucleophile that can be used to prepare methylthioether and other organic compounds like ethyl bromide. Its hydrolysis in moist air produces methanethiol, which has a low odor threshold and a noxious fecal smell.

  1. ^ a b "Sodium thiomethoxide | 5188-07-8".