Triphosphane (original) (raw)
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Triphosphane
 Structural formula of triphosphane  Ball-and-stick model |
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|---|---|
| Names | |
| Systematic IUPAC name Triphosphane[2] | |
| Other namesTriphosphine[1] | |
| Identifiers | |
| CAS Number | 13597-70-1  Y |
| 3D model (JSmol) | Interactive image |
| ChEBI | CHEBI:35893  N |
| ChemSpider | 123032 N |
| PubChem CID | 139510 |
| CompTox Dashboard (EPA) | DTXSID80159606  |
| InChI InChI=1S/H5P3/c1-3-2/h3H,1-2H2 NKey: ITHPEWAHFNDNIO-UHFFFAOYSA-N N |
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| SMILES PPP | |
| Properties | |
| Chemical formula | P3H5 |
| Molar mass | 97.96099 g·mol−1 |
| Appearance | Colourless gas |
| Related compounds | |
| Other anions | triazane |
| Related Binary phosphanes | phosphanediphosphane |
| Related compounds | triazene |
| Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). N verify (what is YN ?) Infobox references |
Chemical compound
Triphosphane (IUPAC systematic name) or triphosphine is an inorganic compound having the chemical formula HP(PH2)2. It can be generated from diphosphine but is highly unstable at room temperature:[3]
2 P2H4 → P3H5 + PH3
Samples have been isolated by gas chromatography. The compound rapidly converts to PH3 and the cyclophosphine _cyclo_-P5H5.[4]
- ^ "Triphosphine". NIST Chemistry WebBook. USA: National Institute of Standards and Technology. Retrieved 27 September 2011.
- ^ "triphosphane (CHEBI:35893)". Chemical Entities of Biological Interest (ChEBI). UK: European Bioinformatics Institute. 7 June 2006. Main. Retrieved 27 September 2011.
- ^ Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. ISBN 978-0-08-037941-8.
- ^ Marianne Baudler, Klaus Glinka (1993). "Monocyclic and Polycyclic Phosphines". Chem. Rev. 93: 1623–1667. doi:10.1021/cr00020a010.