�� . (original) (raw)

��  � � " Études de dynamique chimi que" (127 [1884]; ��. Van't Hoff-Cohen, "Studien zur Chemischen Dynamik", 126�130 � 152 [1896]) ��'�-�� :

(d ln k1)/(dT) � (d ln k2)/(dT) = q/(RT2),

�� k1 � k2 �� [� �� R �� (� �� ) �� 2 (��./��).] �� , a q �� , �� , �� '�-�� . �� , �� , �

k1/k2 = �,

�

(d ln K)/(dT) = q/(RT2),

�� (��. �� ). "�� , � �� '�-��, � �� , �� :

(d ln �)/dT = �/T 2 + B...",

�� . �� '�-�� , �� , �� , � �� '�-�� . �� , ��

q = f(T).

�� , � �� :

f(T) = A + BT + CT2 + DT3...,

�� A, B, C, D... � �� , �� , ��

(d ln �)/dT = (A + BT + CT 2 + DT3...)/(RT2)

��

ln � = a/T + b ln T + �� +... + const,

�� �, b, �... �� . �� , ��

A + BT + CT2...

��, �� . ��. �� (Kooij, 1893) �� 3 � AsH 3

�� :

(d ln K)/dT = (A + BT)/(RT2)

��

ln k = a/T + b lnT + const;

Ap�� (1889) � �� , ��, ��, �� :

(d ln K)/dT = A/(RT2)

��

ln k1 � ln k2 = a(1/T1 � 1/T0),

�. �.

k = k0e � [(T0 � T1)/(T0T1)];

�� (1867) ��

(d ln K)/dT = B/RT,

��

k/k0 = (T/T0)B;

�� . ��' �-��, ��, �� = 0, ��, �� = �� , ��

(d ln K)/dT = C,

� ��

ln k = �� + const,

�� , ��., �� (Tammann, 1897, Arrhenius, 1899) � �. �.

�� . Mellor, "Chemical Statics and Dynamics", 387�93 [1904].

�. �� 

������� �������. (original) (raw)