Grumantite (original) (raw)

A valid IMA mineral species

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About GrumantiteHide

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Lustre:

Vitreous, Silky, Dull

Crystal System:

Orthorhombic

Name:

From an old Russian name for the Spitzbergen Archipelago.

This page provides mineralogical data about Grumantite.

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:1757:8

99acf463-107c-4784-9a02-c80f17d41bdc

IMA Classification of GrumantiteHide

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IMA Formula:

NaSi2O4(OH) · H2O

Type description reference:

Classification of GrumantiteHide

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9.EH.10

9 : SILICATES (Germanates)
E : Phyllosilicates
H : Transitional structures between phyllosilicate and other silicate units

78.4.5.1

78 : Unclassified Silicates
4 :

14.1.7

14 : Silicates not Containing Aluminum
1 : Silicates of the alkali metals

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol Source Reference
Gmt IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of GrumantiteHide

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Comment:

Aggregates dull to silky, single crystals vitreous

Density:

2.21 g/cm3 (Measured) 2.26 g/cm3 (Calculated)

Optical Data of GrumantiteHide

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RI values:

_n_α = 1.494(2) _n_β = 1.507(2) _n_γ = 1.523(2)

2V:

Measured: 83° to 87°, Calculated: 84.9°

δ = 0.029

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.

Optical Extinction:

X = a, Y = c, Z = b

Chemistry of GrumantiteHide

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Mindat Formula:

Na(HSi2O5) · H2O

Crystallography of GrumantiteHide

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Crystal System:

Orthorhombic

Class (H-M):

m _m_2 - Pyramidal

Cell Parameters:

a = 15.979 Å, b = 18.25 Å, c = 7.169 Å

Ratio:

a:b:c = 0.876 : 1 : 0.393

Unit Cell V:

2,090.60 ų (Calculated from Unit Cell)

X-Ray Powder DiffractionHide

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Powder Diffraction Data:

d-spacing Intensity
3.505 Å (100)
3.006 Å (100)
6.20 Å (50)
6.05 Å (50)
4.46 Å (50)
3.087 Å (50)
3.346 Å (25)

Geological EnvironmentHide

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Type Occurrence of GrumantiteHide

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General Appearance of Type Material:

irregular crystals, compact massive

Place of Conservation of Type Material:

Geology Museum, Kola Branch, Academy of Sciences, Apatity, Russia.
Mineralogical Museum, St. Petersberg, Russia.
A.E.Fersman Mineralogical Museum, Moscow, Russia.

Geological Setting of Type Material:

in veins cutting alkalic feldspathoid-bearing pegmatites in a differentiated alkalic massif

Associated Minerals at Type Locality:

Reference:

Khomyakov, A.P., Korobitsyn, M.F., Kurova, T.A., Cherepivskaya, G.E. (1987) Grumantite NaHSi2O5·H2O—a new mineral. Zapiski Vsesoyuznogo Mineralogicheskogo Obshchestva: 116(2): 244-248.

Synonyms of GrumantiteHide

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Other Language Names for GrumantiteHide

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Common AssociatesHide

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Associated Minerals Based on Photo Data:

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9.EH.05 Manganoneptunite KNa2Li(Mn2+)2Ti2[Si4O12]2 Mon. m : B b
9.EH.05 Neptunite KNa2Li(Fe2+)2Ti2[Si4O12]2 Mon. m : B b
9.EH.05 Watatsumiite KNa2Li(Mn2+)2V4+2[Si4O12]2 Mon. m : B b
9.EH.05 Magnesioneptunite KNa2Li(Mg)2Ti2[Si4O12]2 Mon. 2/m : _B_2/b
9.EH.05 Rotherkopfite KNa2Fe2+(Fe2+)2(Ti1.5Fe2+0.5)[Si4O12]2 Mon. 2/m : _B_2/b
9.EH.15 Sarcolite Na4Ca12Al8Si12O46(SiO4,PO4)(OH,H2O)4(CO3,Cl) Tet. 4/m : _I_4/m
9.EH.20 Ussingite Na2AlSi3O8OH Tric. 1 : _P_1
9.EH.25 Leifite (Na,H2O)Na6[Be2Al2(Al,Si)Si15O39]F2 Trig. 3_m_ : _P_3_m_1
9.EH.25 Telyushenkoite (Cs,Na,K)Na6[Be2Al3Si15O39]F2 Trig. 3_m_ _(_32/m ) : P_31_m
9.EH.25 Eirikite KNa6Be2(Si15Al3)O39F2 Trig. 3_m_ _(_32/m ) : _P_3_m_1
9.EH.30 Nafertisite Na3Fe2+10Ti2(Si6O17)2O2(OH)6F(H2O)2 Mon. 2/m
9.EH.35 Veblenite KNa(Fe2+5Fe3+4Mn7)Nb4(Si2O7)2(Si8O22)2O6(OH)10(H2O)3 Tric. 1 : _P_1

Fluorescence of GrumantiteHide

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Other InformationHide

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Thermal Behaviour:

The DTA curve exhibits marked endothermal effects at 280°C (dehydration), 700°C (phase transition), and 760°C (melting).

Notes:

Insoluble in cold water and cold 10% HCl, readily
soluble in hot 10% HCl giving a silicic residue.

Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

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References for GrumantiteHide

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Reference List:

Yamnova, N.Y., Pushcharovskii, D.Y., Andrianov, V.I., Rastsvetaeva, R.K., Khomyakov, A.P., Mikheeva, M.G. (1989) A new type of silicon-oxygen group in the structure of grumantite Na[Si2O4(OH)]·H2O. Soviet Physics - Doklady: 34: 284-286.

Yamnova, N.Y., Pushcharovskii, D.Y., Andrianov, V.I., Rastsvetaeva, R.K., Khomyakov, A.P., Mikheeva, M.G. (1989) A new type of silicate radical in the structure of grumantite, Na[Si2O4(OH)].H2O. Doklady Akademii Nauk SSSR: 305(4): 868-871.

Localities for GrumantiteHide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

Russia
Murmansk Oblast Khibiny Massif Rasvumchorr Mt Rasvumchorr Mine Tsentral'nyi Mine Pekov I.V. et al. (2010)
Lovozersky District Alluaiv Mountain ZVMO (1987)
Umbozero North quarry (TL) Pekov (1998)