Guilleminite (original) (raw)

A valid IMA mineral species

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About GuilleminiteHide

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Formula:

Ba(UO2)3(SeO3)2O2 · 3H2O

Lustre:

Waxy, Greasy, Dull, Earthy

Crystal System:

Orthorhombic

Name:

Named by R. Pierrot, J. Toussaint, and T. Verbeek in 1965 in honor of Jean Claude Guillemin [September 13, 1923 France - April 6, 1994 France], chemist and mineralogist, 1957-1969 he was professor at the Ecole des Mines in Paris and curator of the mineral collection of the Ecole des Mines. Guillemin was director general of the Union Miniere du Haut-Katanga and co-founder of the International Mineralogical Association.

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:1771:4

723358e5-c1e7-4eb1-94cd-de5f69b34860

IMA Classification of GuilleminiteHide

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IMA Formula:

Ba(UO2)3(Se4+O3)2O2 · 3H2O

Type description reference:

Classification of GuilleminiteHide

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4.JJ.10

4 : OXIDES (Hydroxides, V[5,6] vanadates, arsenites, antimonites, bismuthites, sulfites, selenites, tellurites, iodates)
J : Arsenites, antimonites, bismuthites, sulfites, selenites, tellurites; iodates
J : Selenites with additional anions, with H2O

34.7.3.1

34 : SELENITES, TELLURITES AND SULFITES
7 : Hydrated Selenites, Tellurites and Sulfites containing Hydroxyl or Halogen

28.1.9

28 : Selenites, Selenates, Tellurites, and Tellurates
1 : Selenites

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol Source Reference
Gul IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of GuilleminiteHide

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Waxy, Greasy, Dull, Earthy

Cleavage:

Perfect
{100} perfect, {010} good.

Density:

4.88(2) g/cm3 (Measured) 5.08 g/cm3 (Calculated)

Optical Data of GuilleminiteHide

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RI values:

_n_α = 1.720 _n_β = 1.798 _n_γ = 1.805

2V:

Measured: 35° , Calculated: 32°

δ = 0.085

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.

Optical Extinction:

Parallel. X = c; Y = b; Z = a.

Comments:

X = bright yellow; Y = yellow; Z = colorless.

Chemistry of GuilleminiteHide

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Mindat Formula:

Ba(UO2)3(SeO3)2O2 · 3H2O

Crystallography of GuilleminiteHide

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Crystal System:

Orthorhombic

Class (H-M):

m _m_2 - Pyramidal

Cell Parameters:

a = 7.29 Å, b = 16.87 Å, c = 7.07 Å

Ratio:

a:b:c = 0.432 : 1 : 0.419

Unit Cell V:

869.48 ų (Calculated from Unit Cell)

Morphology:

As rectangular crystals, tabular on {010}. Forms include {001}, {010}, {001}, and minor {101}.

Comment:

Space group is P21nm

Crystal StructureHide

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ID Species Reference Link Year Locality Pressure (GPa) Temp (K)
0005466 Guilleminite Cooper M A, Hawthorne F C (1995) The crystal structure of guilleminite, a hydrated Ba-U-Se sheet structure The Canadian Mineralogist 33 1103-1109 1995 0 293

CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

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Powder Diffraction Data:

d-spacing Intensity
8.39 Å (100)
7.29 Å (100)
6.68 Å (60)
6.51 Å (20)
3.55 Å (80)
3.17 Å (40)
3.04 Å (60)
2.80 Å (60)

Geological EnvironmentHide

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Type Occurrence of GuilleminiteHide

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General Appearance of Type Material:

Canary-yellow coatings and silky masses up to 1 cm2. In geodes, it forms tablets up to 0.4 x 0.2 mm.

Place of Conservation of Type Material:

National School of Mines, Paris, France.
National Museum of Natural History, Washington, D.C., USA, 119360.

Geological Setting of Type Material:

Oxidized zone of a uranium-selenium-copper deposit.

Associated Minerals at Type Locality:

Reference:

Pierrot, R., Toussaint, J., Verbeek, T. (1965) La guilleminite, une nouvelle espèce minérale. Bulletin de la Société Française de Minéralogie et de Cristallographie, 88, 132-135.

Synonyms of GuilleminiteHide

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Other Language Names for GuilleminiteHide

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Common AssociatesHide

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Associated Minerals Based on Photo Data:

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4.JJ. Petermegawite Al6(Se4+O3)3[SiO3(OH)](OH)9 · 10H2O Orth. m _m_2 : C m _c_21
4.JJ. Borzęckiite Pb(UO2)3(SeO3)2O2 · 3H2O Orth. m _m_2
4.JJ.05 Marthozite Cu2+(UO2)3(SeO3)2O2 · 8H2O Orth. m _m_2
4.JJ.15 Piretite Ca(UO2)3(SeO3)2(OH)4 · 4H2O Orth.
4.JJ.20 Demesmaekerite Pb2Cu5(UO2)2(SeO3)6(OH)6 · 2H2O Tric. 1 : _P_1
4.JJ.25 Haynesite (UO2)3(OH)2(SeO3)2 · 5H2O Orth.
4.JJ.30 Favreauite PbBiCu6O4(SeO3)4(OH) · H2O Tet. 4/m : _P_4/n

Fluorescence of GuilleminiteHide

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Other InformationHide

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Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

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References for GuilleminiteHide

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Localities for GuilleminiteHide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

DR Congo
Haut-Katanga Kambove Territory Shinkolobwe Shinkolobwe Mine KMMA +1 other reference
Lualaba Mutshatsha Kolwezi Musonoi Mine (TL) Pierrot et al. (1965) +2 other references
France
Auvergne-Rhône-Alpes Puy-de-Dôme Clermont-Ferrand Olloix Liauzun - (1998)
Spain
Catalonia Lleida Pallars Jussà La Vall Fosca La Torre de Cabdella Castell-estaó Eureka mine Castillo-Oliver et al. (2019)