Tschermigite (original) (raw)

A valid IMA mineral species - grandfathered

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About TschermigiteHide

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Formula:

(NH4)Al(SO4)2 · 12H2O

Colour:

Colourless, white; colourless in transmitted light

Name:

Named after its discovery locality, Tschermig (now Cermniky), near Kadan, Czech Republic.

Note: Specimens frequently offered for sale of 'tschermigite' as large, good quality purple crystals on matrix are artificially created specimens made by growing crystals of this ammonium alum in a laboratory. Godovikovite is a dehydration product of tschermigite sometimes occurring on burning coal dumps.

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:4036:1

9d64c18f-6a7d-4f1e-a831-9d3406238942

IMA Classification of TschermigiteHide

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Approved, 'Grandfathered' (first described prior to 1959)

Type description reference:

Classification of TschermigiteHide

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7.CC.20

7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
C : Sulfates (selenates, etc.) without additional anions, with H2O
C : With medium-sized and large cations

29.5.5.3

29 : HYDRATED ACID AND NORMAL SULFATES
5 : AB(XO4)2·xH2O

25.6.20

25 : Sulphates
6 : Sulphates of Al and Tl

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol Source Reference
Tmi IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of TschermigiteHide

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Comment:

Crystals vitreous; fibrous masses silky

Colour:

Colourless, white; colourless in transmitted light

Density:

1.645 g/cm3 (Measured) 1.641 g/cm3 (Calculated)

Optical Data of TschermigiteHide

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Birefringence:

Anomalous - due to strain arising in mechanical deformation or compositional variation.

Chemistry of TschermigiteHide

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Mindat Formula:

(NH4)Al(SO4)2 · 12H2O

Crystallography of TschermigiteHide

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Class (H-M):

m_3(2/m_3) - Diploidal

Cell Parameters:

a = 12.242``(1) Å

Unit Cell V:

1,834.67 ų (Calculated from Unit Cell)

Morphology:

Octahedral (artificial crystals from pure water solutions); fibrous, columnar massive; as efflorescences.

Crystal StructureHide

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ID Species Reference Link Year Locality Pressure (GPa) Temp (K)
0019048 Tschermigite Larson A C, Cromer D T (1967) Refinement of the alum structures. III. X-ray study of the a alums, K, Rb and NH4Al(SO4)2*12H2O Acta Crystallographica 22 793-800 1967 Synthetic 0 293
0010843 Tschermigite Abdeen A M, Will G, Schaefer W, Kirfel A, Bargouth M O, Recker K, Weiss A (1981) X-ray and neutron diffraction study of alums II. The crystal structure of methylammonium aluminium alum III. The crystal structure of ammonium aluminium alum Zeitschrift fur Kristallographie 157 147-166 1981 synthetic 0 293
0010844 Tschermigite Abdeen A M, Will G, Schafer W, Kirfel A, Bargouth M O, Recker K, Weiss A (1981) X-ray and neutron diffraction study of alums: II. The crystal structure of methylammonium aluminium alum III. The crystal structure of ammonium aluminium alum Zeitschrift fur Kristallographie 157 147-166 1981 0 293

CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

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Radiation - Copper Kα

Data Set:

Data courtesy of RRUFF project at University of Arizona, used with permission.

Powder Diffraction Data:

d-spacing Intensity
4.327 Å (100)
4.079 Å (80)
3.273 Å (75)
7.07 Å (55)
5.48 Å (55)
4.998 Å (35)
3.691 Å (35)

Geological EnvironmentHide

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Geological Setting:

In lignite (brown-coal) beds and bituminous shales; in fumaroles; in burning coal seams and coal mine waste heaps.

Type Occurrence of TschermigiteHide

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Reference:

von Kobel F (1858) Es sind in Salzsäure, einige auch in Wasser, ohne merklichen Rückstand auflöslich. Die Aufl. bildet keine Gallerte. in Tafeln zur Bestimmung der Mineralien mittelst einfacher chemischer Versuche auf trockenem und nassem Wege., Joseph Lindauer'sche Buchhandlung (München) 47-47

Synonyms of TschermigiteHide

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Other Language Names for TschermigiteHide

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Relationship of Tschermigite to other SpeciesHide

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Other Members of this group:

Common AssociatesHide

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Associated Minerals Based on Photo Data:

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Other InformationHide

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Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

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References for TschermigiteHide

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Reference List:

**Palache, Charles, Berman, Harry, Frondel, Clifford (1951) The System of Mineralogy (7th ed.) Vol. 2 - Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, Ect. John Wiley and Sons, New York.**pp.475-476

Localities for TschermigiteHide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

Austria
Styria Deutschlandsberg District Bad Schwanberg Glashütten Forestry road cut Postl et al. (2020)
Leoben District Leoben Seegraben mine Meixner (1954)
Belgium
Wallonia Namur Houyet Chaleux cave Leduc et al. (2012)
Brazil
Minas Gerais Caldas Osamu Utsumi mine Waber et al. (1992) +2 other references
Bulgaria
Blagoevgrad Province Simitli Municipality Brezhani Pirin mine Elena Shcherbakova (2010)
China
Inner Mongolia Wuhai (Wuhai Prefecture) Wuda District Wuda Coal mining area Huangbaici coal field Stracher et al. (2005)
Czech Republic
Central Bohemian Region Kladno District Zacek et al. (1995)
Libušin Kladno mine Palache et al. (1951) +2 other references
Mladá Boleslav District Branžež Zakopaná Breiter K. (1976)
Kněžmost Breiter K. (1976)
Hradec Králové Region Jičín District Prachovské skály Breiter K. (1976)
Trutnov District Lampertice Jan Šverma Mine Harapát
Radvanice Kateřina Coal Mine Jirásek (2001)
Liberec Region Česká Lípa District Dubá Bukovec Breiter K. (1976)
Jablonec nad Nisou District Malá Skála Breiter K. (1976)
North Bohemian Uranium District Scharm +7 other references
Moravian-Silesian Region Ostrava-City District Ostrava Heřmanice Dalibor Matýsek
Heřmanice dump Dalibor Matýsek +1 other reference
Plzeň Region Klatovy District Sušice Hamr quarry Hofmanovi P. a R.: Příspěvek k ...
South Moravian Region Brno-Country District Oslavany Rosice-Oslavany coalfield Hršelová et al. (2013)
Zastávka Zastávka coal dumps www.handbookofmineralogy.org (n.d.)
Hodonín District Žeravice Sekanina (1948) +1 other reference
Ústí nad Labem Region Chomutov District Březno Cermniky (TL) Duda +1 other reference
Děčín District Pravčice rock arch Varilová et al. (2011)
DR Congo
North Kivu Masisi Territory Bahunde Nyamuragira volcano Palache et al. (1951)
France
Auvergne-Rhône-Alpes Savoie Chambéry Aix-les-Bains Serpents cave Audra et al. (2007)
Hauts-de-France Pas-de-Calais Lens Avion Naze-Nancy Masalehdani et al. (2009)
Occitanie Aveyron Villefranche-de-Rouergue Decazeville www.geoforum.fr (2018)
Germany
Baden-Württemberg Freiburg Region Ortenaukreis Oberwolfach Clara Mine Walenta (1992)
North Rhine-Westphalia Cologne Aachen Alsdorf Anna mine Dr.Thomas Witzke on www.strahlen.org +3 other references
Anna I dump Košek (2018)
Saxony Sächsische Schweiz-Osterzgebirge Freital Döhlen Carola Mine Thalheim +1 other reference
Thuringia Greiz District Kauern Lichtenberg Absetzer dump T. Witzke & F. Rüger: Lapis 1998 (7/8)
Hungary
Baranya County Komló District Komló Shaft No. III Sándor et al. (2005)
Pécs District Pécs-Vasas Szakáll et al. (2008)
Komárom-Esztergom County Mogyorósbánya Szakáll et al. (1996)
Tokodaltáró Palache et al. (1951) +1 other reference
Italy
Calabria Cosenza Province Cerchiara di Calabria Cerchiara di Calabria caves D’Angeli et al. (2017) +1 other reference
Campania Metropolitan City of Naples Pozzuoli Pisciarelli di Agnano Russo et al. (2017)
Solfatara di Pozzuoli Palache et al. (1951)
"Bocca Grande" fumarole Russo et al. (2017)
Piedmont Cuneo Province Entracque Punta Chistafort Ciriotti et al. (2020) +1 other reference
Sicily Caltanissetta Province Butera Acqua Mintina Cave (Grotta dell'Acqua Mintina) D'Angeli et al. (2018)
Metropolitan City of Catania Etna Volcanic Complex Mount Etna Palache et al. (1951)
Metropolitan City of Messina Eolie Islands (Aeolian Islands) Lipari Vulcano Island La Fossa crater Campostrini et al. (2011)
Tuscany Livorno Province Rio Rio Marina Rio Mine Antenna stope Rögner et al. (2007)
Pisa Province Pomarance Larderello Coradossi (1973)
Siena Province Chiusdino Le Cetine di Cotorniano Mine Brizzi G. et al. (1986) +1 other reference
Japan
Hokkaidō Prefecture Sorachi Subprefecture Mikasa City Ikushunbetsu Shimobayashi et al. (2011)
Kenya
Trans-Nzoia County Mount Elgon Kitum Cave Bowell et al. (1996)
New Zealand
Bay of Plenty Region Rotorua District Te Kopia geothermal area Martin et al. (1999)
Manawatu-Whanganui Region Ruapehu District Tongariro National Park Tongariro Alpine Crossing Northern Circuit Johnstone (1979)
Waikato Region Taupo District Orakeikorako Thermal Area (Orakei Korako; The Hidden Valley) Ruatapu Cave (Alum Cave) Rod Martin et al. (NZ)
Peru
Arequipa Caylloma Province Chivay District Pinchollo geyser Ciesielczuk et al. (2013)
Poland
Lower Silesian Voivodeship Kłodzko County Nowa Ruda Słupiec Mine Słupiec heap Ciesielczuk et al. (2014)
Silesian Voivodeship Katowice Wełnowiec-Józefowiec "Alpy" dump Fabiańska et al. (Poland)
Mikołów County Łaziska Górne Skalny dump Lukasz Kruszewski Minerals arising in cause of underground fires of "Skalny" coal mine dump in Laziska (unpublished) +1 other reference
Rybnik County Gmina Czerwionka-Leszczyny Dębieńsko Mine heap Parafiniuk et al. (2009)
Wodzisław County Radlin Marcel mine heap Łukasz Kruszewski (2012)
Rydułtowy ROW Ruch Rydułtowy Mine Rydułtowy heap (Szarlota heap) Kruszewski et al. (1 November 2018) +1 other reference
Wodzisław Śląski Pszów ? Kruszewski +1 other reference
Portugal
Aveiro Albergaria-a-Velha Branca Palhal Mine Marques de Sá et al. (2010)
Russia
Chelyabinsk Oblast Chelyabinsk coal basin Cesnokov et al. (1998)
Kamchatka Krai Ust-Bolsheretsky District Kambalny volcanic ridge Severo-Kambalny geothermal field Zhitova et al. (2018)
Yelizovsky District Kronotsky Reserve Uzon Caldera Active Volcanoes of Kamchatka
Mutnovskoe Okrugin (2004)
Mutnovsky volcano Dachnoe thermal field Zhitova et al. (2022)
Slovakia
Prešov Region Prešov District Červenica Dubník Libanka Koděra (1986)
South Africa
Mpumalanga Ehlanzeni District Municipality Thaba Chweu Local Municipality Sabie Lone Creek Falls Lone Creek Falls cave Cairncross et al. (1995)
Spain
Aragon Teruel Libros Libros sulphur mines Calvo (2008)
Extremadura Cáceres Tajo-Salor Aliseda Pastora Mine Crespo et al. (2017)
Switzerland
Ticino Locarno Brissago Ponte Valley Stalder et al. (1998)
Valais Saint-Maurice Collonges Pyrite occurrence Stalder et al. (1998)
Tajikistan
Sughd Gissar Range Jijikrut (Dzhidzhikrut) Lukasz Kruszewski (PXRD)
Zeravshan Range Yagnob River Ravat village Kukhi-Malik area (Kuhi-malik) D.I.Belakovskiy data
USA
California Imperial County Salton Sea Mullet Island F1 fumarole field Adams et al. (2014)
F2 fumarole field Adams et al. (2014)
Lake County Sulphur Creek Mining District (Sulfur Creek Mining District; Wilbur Springs Mining District) Clear Lake Oaks Sulphur Bank Mine (Sulfur Bank Mine; Sulphur Bank deposits) Becker (1888b) +2 other references
Sonoma County West Mayacmas Mining District The Geysers Palache et al. (1951)
Geyser Canyon (Geyser Creek Canyon) Upper Geyser Creek Canyon Van Nostrand Reinholt Press: 265 +4 other references
Colorado Garfield County Glenwood Springs South Canyon No. 1 Mine GSA Field Guide 10 (2007)
Kentucky Floyd County Truman Shepherd coal mine Hower et al. (2013)
New Mexico Quay County Tucumcari area Palache et al. (1951) +1 other reference
Ohio Huron County Huron River Huron Shale burn site Richards et al. (2017)
Pennsylvania Carbon County Lansford Lapham (Oct, 1972) +2 other references
Columbia County Centralia Matt Livingood
Dauphin County Williamstown Montgomery (Sep, 1972) +1 other reference
Luzerne County Glen Lyon Finkelman et al. (1974) +1 other reference
Schuylkill County Saint Clair Lapham (Oct, 1972) +2 other references
Tennessee Sevier County Alum Cave Bluff Coskren et al. (2000)
Utah Kane County Kaibab fault Palache et al. (1951)
San Juan County Blanding White Mesa Uranium Mill Wendlandt et al. (2006)
Wyoming Sweetwater County Wamsutter Palache et al. (1951)