Vlasovite (original) (raw)

A valid IMA mineral species

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About VlasoviteHide

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Colour:

Colorless, honey-brown

Lustre:

Vitreous, Greasy, Pearly

Specific Gravity:

2.92 - 2.97

Crystal System:

Monoclinic

Name:

Named in honor of Kuzma Alekseevich Vlasov (Кузьма Алексеевич Власов) (1 (14) November 1905, Nikolaevka, Tambov Province, Russian Empire - 29 September 1964, Moscow, USSR), mineralogist and geochemist, founder of the Institute of Mineralogy (Moscow).

Seems to be related to khurayyimite; the two are suggested to belong to the same group.

The two minerals can be described using geometrical repeat unit of cTr = 2T4 3T4 and topological repeat unit of cVr = 2V2 3V2.

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:4196:2

e7e0931d-1f7b-4e4b-b725-f19b5b7d1e0e

IMA Classification of VlasoviteHide

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Type description reference:

Classification of VlasoviteHide

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9.DM.25

9 : SILICATES (Germanates)
D : Inosilicates
M : Inosilicates with 6-periodic single chains

66.2.2.1

66 : INOSILICATES Double-Width,Unbranched Chains,(W=2)
2 : Amphiboles - Ca subgroup

14.10.5

14 : Silicates not Containing Aluminum
10 : Silicates of Zr or Hf

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol Source Reference
Vsv IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of VlasoviteHide

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Comment:

highly vitreous to pearly on cleavage surfaces.

Colour:

Colorless, honey-brown

Hardness:

VHN100=770 - Vickers

Cleavage:

Distinct/Good
{010}, good; {h0l}, poor.

Fracture:

Irregular/Uneven, Conchoidal

Density:

2.92 - 2.97 g/cm3 (Measured) 3.07 g/cm3 (Calculated)

Optical Data of VlasoviteHide

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RI values:

_n_α = 1.607(3) _n_β = 1.623(3) _n_γ = 1.628(3)

δ = 0.021

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.

Chemistry of VlasoviteHide

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Mindat Formula:

Na2ZrSi4O11

Crystallography of VlasoviteHide

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Crystal System:

Monoclinic

Class (H-M):

2/m - Prismatic

Cell Parameters:

a = 11.0390(5) Å, b = 10.0980(4) Å, c = 8.5677(4) Å
β = 100.313(1)°

Ratio:

a:b:c = 1.093 : 1 : 0.848

Twinning:

Twin plane {010}, uncommon.

Crystal StructureHide

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ID Species Reference Link Year Locality Pressure (GPa) Temp (K)
0006128 Vlasovite Sokolova E, Hawthorne F C, Ball N A, Mitchell R H, Della Ventura G (2006) Vlasovite, Na2Zr(Si4O11), from the Kipawa alkaline complex, Quebec, Canada: Crystal-structure refinement and infrared spectroscopy The Canadian Mineralogist 44 1349-1356 2006 Kipawa alkaline complex, Quebec, Canada 0 293
0014182 Vlasovite Voronkov A A, Zhdanova T A, Pyatenko Y A (1974) Refinement of the structure of vlasovite Na2ZrSi4O11 and some characteristics of the composition and structure of the zirconosilicates Kristallografiya 19 252-259 1974 0 293
0014445 Vlasovite Fleet S G, Cann J R (1967) Vlasovite: a second occurrence and a triclinic to monoclinic inversion Mineralogical Magazine 36 233-241 1967 0 293

CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

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Powder Diffraction Data:

d-spacing Intensity
5.053 Å (100)
3.669 Å (75)
3.882 Å (45)
3.237 Å (40)
3.363 Å (35)
3.548 Å (25)
1.945 Å (20)

Geological EnvironmentHide

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Type Occurrence of VlasoviteHide

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General Appearance of Type Material:

Place of Conservation of Type Material:

Mining Institute, St. Petersburg, 1037/1; A.E. Fersman Mineralogical Museum, Academy of Sciences, Moscow, Russia, 83207, vis5052; National School of Mines, Paris, France.

Reference:

Tikhonenkova, R.P., Kazakova, M.E. (1961) Vlasovite - a new zirconium silicate from the Lovozero Massif. Doklady Akademii Nauk SSSR: 137: 944-946.

Other Language Names for VlasoviteHide

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Common AssociatesHide

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Associated Minerals Based on Photo Data:

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Fluorescence of VlasoviteHide

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Altered portions fluoresce brownish yellow under SW UV

Other InformationHide

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Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

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References for VlasoviteHide

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Reference List:

Gobechiya, E. R., Pekov, I. V., Pushcharovskii, D. Yu., Ferraris, G., Gula, A., Zubkova, N. V., Chukanov, N. V. (2003) New data on vlasovite: Refinement of the crystal structure and the radiation damage of the crystal during the x-ray diffraction experiment. Crystallography Reports, 48 (5) 750-754 doi:10.1134/1.1612595

Sokolova, E., Hawthorne, F. C., Ball, N. A., Mitchell, R. H., Della Ventura, G. (2006) Vlasovite, Na2Zr(Si4O11), from the Kipawa alkaline complex, Quebec, Canada: crystal-structure refinement and infrared spectroscopy. The Canadian Mineralogist, 44 (6) 1349-1356 doi:10.2113/gscanmin.44.6.1349

Krüger, Biljana, Galuskina, Irina O., Galuskin, Evgeny V., Vapnik, Yevgeny, Murashko, Mikhail N. (2023) Khurayyimite Ca7Zn4(Si2O7)2(OH)10·4H2O: a mineral with unusual loop-branched sechser single chains. Mineralogy and Petrology, 117 (2) 191-200 doi:10.1007/s00710-022-00804-z

Localities for VlasoviteHide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

Antarctica
Eastern Antarctica Queen Maud Land Straumsvola complex Harris et al. (1993)
Australia
New South Wales Gordon Co. Toongi deposit Anenburg et al. (2022)
Canada
Northwest Territories North Slave Region Blachford Lake alkaline complex Thor Lake syenite complex Nechalacho deposit MÖLLER (2016)
Québec Abitibi-Témiscamingue Témiscamingue RCM Les Lacs-du-Témiscamingue Kipawa alkaline complex Currie et al. (1996)
Strange Lake complex (Lac Brisson complex) Miller (1990) +5 other references
Czech Republic
Liberec Region Česká Lípa District Mařenice Luž phonolite Krmíčková et al. (2022)
India
Rajasthan Jodhpur Division Barmer District Malani Igneous Province Siwana granite Mondal et al. (2021)
Portugal
Azores São Miguel Água de Pau Volcano Samples collected by Luigi Chiappino ... +1 other reference
Russia
Buryatia Mama River Basin Maigunda River Burpala alkaline massif A.M. Portnov data +1 other reference
Murmansk Oblast Khibiny Massif Kukisvumchorr Mt
Lovozersky District Vavnbed Mountain (TL) Pekov (1998)
Saint Helena, Ascension and Tristan da Cunha
Ascension Island Bell +20 other references
Green Mountain rruff.geo.arizona.edu (n.d.)