Shibkovite (original) (raw)

A valid IMA mineral species

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About ShibkoviteHide

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Formula:

K(◻K)Ca2Zn3[Si12O30]

Previously given as K(□,K,Na)2Zn3Ca2[Si12O30].

Name:

Named after two prominent Russian geologists, Viktor Sergeevitch Shibkov (Виктор Сергеевич Шибков) (1926-1992) and Nikolai Viktorovitch Shibkov (Николай Викторович Шибков) (1951-1991), who both spent their professional lives working on the geology of Soviet Asia.

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:7290:4

b3a6f10d-d3aa-4662-970b-344b6aa444b6

IMA Classification of ShibkoviteHide

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IMA Formula:

K2Ca2(Zn3Si12)O30

Type description reference:

Classification of ShibkoviteHide

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9.CM.05

9 : SILICATES (Germanates)
C : Cyclosilicates
M : [Si6O18]12- 6-membered double rings (sechser-Doppelringe)

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol Source Reference
Sko IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of ShibkoviteHide

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Hardness:

VHN50=609 kg/mm2 - Vickers

Density:

2.89(2) g/cm3 (Measured) 2.90(5) g/cm3 (Calculated)

Optical Data of ShibkoviteHide

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RI values:

_n_ω = 1.561 _n_ε = 1.563

δ = 0.002

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.

Chemistry of ShibkoviteHide

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Mindat Formula:

K(◻K)Ca2Zn3[Si12O30]

Previously given as K(□,K,Na)2Zn3Ca2[Si12O30].

Crystallography of ShibkoviteHide

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Class (H-M):

6/m m m _(_6/_m_2/_m_2/m ) - Dihexagonal Dipyramidal

Cell Parameters:

a = 10.505 Å, c = 14.185 Å

Unit Cell V:

1,355.66 ų (Calculated from Unit Cell)

Crystal StructureHide

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ID Species Reference Link Year Locality Pressure (GPa) Temp (K)
0012494 Shibkovite Sokolova E V, Rybakov V B, Pautov L A (1999) Crystal structure of shibkovite Doklady Akademii Nauk SSSR 369 378-380 1999 0 293

CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

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Powder Diffraction Data:

d-spacing Intensity
7.11 Å (35)
3.830 Å (100)
3.345 Å (60)
3.304 Å (40)
2.940 Å (50)
2.795 Å (85)
2.627 Å (35)

Geological EnvironmentHide

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Type Occurrence of ShibkoviteHide

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General Appearance of Type Material:

Occurs as white to colorless equant grains, to 0.5 mm, resembling quartz.

Place of Conservation of Type Material:

Museum of the Ilmensky National Park at Miass, Russia, and in the A. E. Fersman Mineralogical Museum, Moscow, Russia.

Associated Minerals at Type Locality:

Reference:

Pautov, L.A., Agakhanov, A.A., Sokolova, E.V. (1998) Shibkovite K(Ca,Mn,Na)2(K2-x□x)2Zn3Si12O30 — the new mineral from the milarite group. Zapiski Vserossijskogo Mineralogicheskogo Obshchestva: 127(4): 89-94.

Synonyms of ShibkoviteHide

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Other Language Names for ShibkoviteHide

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Relationship of Shibkovite to other SpeciesHide

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Other Members of this group:

Agakhanovite-(Y) K◻2(YCa)Be3[Si12O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m c c
Almarudite K◻2Mn2+2(Be2Al)[Si12O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m m m
Aluminosugilite KNa2Al2Li3[Si12O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m c c
Armenite Ba(H2O)2Ca2Al3[Al3Si9O30] Orth. m m m _(_2/_m_2/_m_2/m ) : P n n a
Berezanskite K◻2Ti2Li3[Si12O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m c c
Brannockite K◻2Sn2Li3[Si12O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m c c
Chayesite K◻2Mg2(Mg2Fe3+)[Si12O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m c c
Darapiosite KNa2Mn2(Zn2Li)[Si12O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m c c
Dusmatovite K(K◻)Mn2+2Zn3[Si12O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m c c
Eifelite KNa2(MgNa)Mg3[Si12O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m c c
Friedrichbeckeite K(◻Na)Mg2(Be2Mg)[Si12O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m c c
Klöchite K◻2(Fe2+Fe3+)Zn3[Si12O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_63/m m c
Laurentthomasite K◻2Mg2(Be2Al)[Si12O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m c c
Merrihueite K(◻Na)Fe2+2Fe2+3[Si12O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m c c
Milarite K(◻H2O)Ca2(Be2Al)[Si12O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m c c
Oftedalite K◻2(ScCa)Be3[Si12O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m c c
Osumilite K◻2Fe2+2Al3[Al2Si10O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m c c
Osumilite-(Mg) K◻2Mg2Al3[Al2Si10O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m c c
Poudretteite K◻2Na2B3[Si12O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m c c
Roedderite K(◻Na)Mg2Mg3[Si12O30] Hex. 6_m_2 : P_62_c
Sogdianite K◻2Zr2Li3[Si12O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m c c
Sugilite KNa2Fe3+2Li3[Si12O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m c c
Trattnerite ◻(◻)2Fe3+2Mg3[Si12O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m c c
UM1990-73-SiO:KMnNaZn K(KNa0.5◻0.5)(Mn1.5Na0.5)Zn3[Si12O30] Hex.
Unnamed (Mn3+-dominant analog of Sugilite) KNa2Mn3+2Li3[Si12O30]
Yagiite Na◻2Mg2Al3[Al2Si10O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m c c

Common AssociatesHide

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Associated Minerals Based on Photo Data:

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9.CM. Agakhanovite-(Y) K◻2(YCa)Be3[Si12O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m c c
9.CM.05 Armenite Ba(H2O)2Ca2Al3[Al3Si9O30] Orth. m m m _(_2/_m_2/_m_2/m ) : P n n a
9.CM.05 Brannockite K◻2Sn2Li3[Si12O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m c c
9.CM.05 Chayesite K◻2Mg2(Mg2Fe3+)[Si12O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m c c
9.CM.05 Darapiosite KNa2Mn2(Zn2Li)[Si12O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m c c
9.CM.05 Eifelite KNa2(MgNa)Mg3[Si12O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m c c
9.CM.05 Merrihueite K(◻Na)Fe2+2Fe2+3[Si12O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m c c
9.CM.05 Milarite K(◻H2O)Ca2(Be2Al)[Si12O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m c c
9.CM.05 Osumilite-(Mg) K◻2Mg2Al3[Al2Si10O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m c c
9.CM.05 Osumilite K◻2Fe2+2Al3[Al2Si10O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m c c
9.CM.05 Poudretteite K◻2Na2B3[Si12O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m c c
9.CM.05 Roedderite K(◻Na)Mg2Mg3[Si12O30] Hex. 6_m_2 : P_62_c
9.CM.05 Sogdianite K◻2Zr2Li3[Si12O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m c c
9.CM.05 Sugilite KNa2Fe3+2Li3[Si12O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m c c
9.CM.05 Yagiite Na◻2Mg2Al3[Al2Si10O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m c c
9.CM.05 Berezanskite K◻2Ti2Li3[Si12O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m c c
9.CM.05 Dusmatovite K(K◻)Mn2+2Zn3[Si12O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m c c
9.CM.05 Almarudite K◻2Mn2+2(Be2Al)[Si12O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m m m
9.CM.05 Trattnerite ◻(◻)2Fe3+2Mg3[Si12O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m c c
9.CM.05 Oftedalite K◻2(ScCa)Be3[Si12O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m c c
9.CM.05 Klöchite K◻2(Fe2+Fe3+)Zn3[Si12O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_63/m m c
9.CM.05 Friedrichbeckeite K(◻Na)Mg2(Be2Mg)[Si12O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m c c
9.CM.05 UM1990-73-SiO:KMnNaZn K(KNa0.5◻0.5)(Mn1.5Na0.5)Zn3[Si12O30] Hex.
9.CM.05 Laurentthomasite K◻2Mg2(Be2Al)[Si12O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m c c
9.CM.9.CM. Aluminosugilite KNa2Al2Li3[Si12O30] Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_6/m c c
9.CM.10 Faizievite K2Na(Ca6Na)Ti4Li6[Si6O18]2[Si12O30]F2 Tric. 1 : _P_1

Fluorescence of ShibkoviteHide

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Bright red fluorescence in short-wave ultraviolet light

Other InformationHide

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IR Spectrum:

Bands at 495, 530, 575, 700, 790, 920, 940, 1000, 1048, and 1105 cm–1.

Notes:

Insoluble in water and 1:1 HCl

Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

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References for ShibkoviteHide

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Localities for ShibkoviteHide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.