Cuprobismutite (original) (raw)

A valid IMA mineral species - grandfathered

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About CuprobismutiteHide

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Crystal System:

Monoclinic

Name:

In allusion to its content of copper and bismuth.

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:1177:4

8962d367-0e25-42d8-9225-3a6491a49bce

IMA Classification of CuprobismutiteHide

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Approved, 'Grandfathered' (first described prior to 1959)

Classification of CuprobismutiteHide

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2.JA.10a

2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
J : Sulfosalts of PbS archetype
A : Galena derivatives with little or no Pb

3.8.2.1

3 : SULFOSALTS
8 : 1 < ø < 2

5.1.8

5 : Sulphosalts - Sulpharsenites and Sulphobismuthites (those containing Sn, Ge,or V are in Section 6)
1 : Sulpharsenites etc. of Cu

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.

Symbol Source Reference
Cbit IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43
Cbs The Canadian Mineralogist (2019) The Canadian Mineralogist (2019) The Canadian Mineralogist list of symbols for rock- and ore-forming minerals (December 30, 2019). download

Physical Properties of CuprobismutiteHide

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Density:

6.36 g/cm3 (Measured) 6.24 g/cm3 (Calculated)

Optical Data of CuprobismutiteHide

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Reflectivity:

Wavelength R1 R2
400nm 31.8% 35.2%
440nm 33.1% 36.4%
480nm 34.9% 37.6%
520nm 35.4% 38.4%
560nm 36.2% 39.4%
600nm 36.8% 40.1%
640nm 37.2% 40.4%
680nm 37.2% 40.5%
700nm 37.2% 40.5%

Reflectance graph
Graph shows reflectance levels at different wavelengths (in nm). Top of box is 100%. Peak reflectance is 40.5%.
R1 shown in black, R2 shown in red

Chemistry of CuprobismutiteHide

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Mindat Formula:

Cu8AgBi13S24

Crystallography of CuprobismutiteHide

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Crystal System:

Monoclinic

Class (H-M):

2/m - Prismatic

Cell Parameters:

a = 17.520(1) Å, b = 3.926(3) Å, c = 15.261(1) Å
β = 100.18(1)°

Ratio:

a:b:c = 4.463 : 1 : 3.887

Unit Cell V:

1,033.18 ų (Calculated from Unit Cell)

Morphology:

Massive, prismatic crystals, thin blades

Crystal StructureHide

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ID Species Reference Link Year Locality Pressure (GPa) Temp (K)
0005923 Cuprobismutite Topa D, Makovicky E, Balic-Zunic T (2003) Crystal structures and crystal chemistry of members of the cuprobismutite homologous series of sulfosalts The Canadian Mineralogist 41 1481-1501 2003 Felbertal Austria 0 293

CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

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Powder Diffraction Data:

d-spacing Intensity
3.10 Å (100)
2.73 Å (60)
3.65 Å (40b)
4.31 Å (30)
1.961 Å (30)
1.719 Å (30)
6.24 Å (20)

Comments:

Hall’s Valley, Colorado, USA. An analysis is also given in Nuffield (1952).

Geological EnvironmentHide

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Geological Setting:

Quartz veins

Type Occurrence of CuprobismutiteHide

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General Appearance of Type Material:

Small slender crystals, generally bronzed by oxidation and deeply striated. Occasionally they are joined together laterally, forming thin corrugated plates.

Place of Conservation of Type Material:

Harvard University, Cambridge, Massachusetts, USA, number 94989.
National Museum of Natural History (Smithsonian), Washington, D.C., USA, number 92902.

Associated Minerals at Type Locality:

Other Language Names for CuprobismutiteHide

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Simplified Chinese:辉铜铋矿

Traditional Chinese:輝鉍銅礦

Relationship of Cuprobismutite to other SpeciesHide

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Other Members of this group:

Common AssociatesHide

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Associated Minerals Based on Photo Data:

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Other InformationHide

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Notes:

Soluble in HNO3. Also soluble in HCl, with precipitation of silver chloride.
Heating in closed tube gives a sublimate of sulfur. On charcoal it gives a strong bismuth reaction.

Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

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References for CuprobismutiteHide

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Reference List:

Pršek, J., Mikuš, T., Makovicky, E., Chovan, M. (2005) Cuprobismutite, kupcikite, hodrushite and associated sulfosalts from the black shale hosted Ni-Bi-As mineralization at Cierna Lehota, Slovakia. European Journal of Mineralogy: 155-162.

Izumino, Y., Nakashima, K., Nagashima, M. (2014) Cuprobismutite group minerals (cuprobismutite, hodrušhite, kupčíkite and padĕrite), other Bi-sulfosalts and Bi-tellurides from the Obari mine, Yamagata Prefecture, Japan. Journal of Mineralogical and Petrological Sciences: 109: 177-190.

Localities for CuprobismutiteHide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

Argentina
Catamarca Province Andalgalá Department Capillitas mining district Putz et al. (2009)
Chubut Province Futaleufú department Trevelin Los Cipreses Cordón de los Galeses Brodtkorb (2002)
San Juan Province Calingasta Department Calingasta San Francisco de los Andes mine Testa et al. (2018)
Australia
Northern Territory Barkly Region Tennant Creek Eldorado Gold Mine Skirrow (1993)
Austria
Salzburg Zell am See District Mittersill Mittersill Scheelite deposit Western ore field Lapis 29 (5)
Bolivia
La Paz Royal Ontario Museum specimen # M13339
Larecaja Province Sorata Marcamarcani Mine (San Baldomero Mine) ? Royal Ontario Museum specimen # M13339
Bulgaria
Burgas Province Malko Tarnovo Municipality Malko Târnovo ore field Cook et al. (2002)
Sozopol Municipality Zidarovo Zidarovo complex Cook et al. (2002)
Canada
British Columbia Omineca Mining Division Owen Lake Silver Queen Mine (Nadina Mine) Hood et al. (1991)
China
Yunnan Chuxiong Yao'an County Yao'an Au-Ag deposit Zhou et al. (2018)
Czech Republic
Karlovy Vary Region Karlovy Vary District Abertamy Hřebečná Maurizi Mine (St. Maurizius shaft; Mauritius Mine; Beer Mine) Sejkora et al. (2021)
Ústí nad Labem Region Teplice District Krupka ? Anthony et al. (1990)
France
Corsica Corse-du-Sud Sartène Figari Testa Bradesi Lheur et al. (2011)
Grand Est Haut-Rhin Colmar-Ribeauvillé Sainte-Marie-aux-Mines Wittern et al. (Cologne)
Neuenberg P&T N°23-24 et al. (Haut-Rhin)
Sankt Johann vein Sankt Johann mine (Engelsbourg mine) Ruhlmann (1978)
Provence-Alpes-Côte d'Azur Alpes-Maritimes Nice Saint-Etienne-de-Tinée Claï R. Pierrot
Germany
Baden-Württemberg Freiburg Region Ortenaukreis Oberkirch Lapis 1984 (1)
Oberwolfach Clara Mine Walenta (1992)
Karlsruhe Region Freudenstadt Bad Rippoldsau-Schapbach Wildschapbach valley Friedrich-Christian Mine Walenta (1989) +1 other reference
Bavaria Lower Franconia Aschaffenburg District Waldaschaff Pauline Mine Lorenz et al. (2007)
Upper Palatinate Neustadt an der Waldnaab District Waidhaus Hagendorf Hagendorf South Pegmatite www.berthold-weber.de (2001)
Rhineland-Palatinate Altenkirchen Daaden-Herdorf Schutzbach Grüneau Mine (Grüne Au Mine; Grünau Mine) Weiß (1990)
Greece
Eastern Macedonia and Thrace Evros Alexandroupoli Kirki Mines Agios Philippos Mine Triantafyllidis (2019)
Indonesia
South Sulawesi Province Gowa Regency Baturappe prospect Nur et al. (2012)
Iran
Zanjan Province Tarom County Chodarchay deposit Mousavi Motlagh et al. (2024)
Japan
Yamagata Prefecture Ohari mine (Obari mine) Izumino et al. (2014)
Yamaguchi Prefecture Mine City Naganobori mine Eboshi Deposit Nagashima et al. (2021)
Morocco
Drâa-Tafilalet Region Bou Azzer mining district S. Weiß: Lapis 31 (7/8)
Peru
Pasco Pasco Province Simón Bolívar District Cerro de Pasco mine (Paragsha mine) Baumgartner (2008)
Poland
Lower Silesian Voivodeship Karkonosze County Szklarska Poręba Szklarska Poręba Huta granite quarry Pieczka et al. (2012) +3 other references
Silesian Voivodeship Myszków County Kraków-Lubliniec tectonic zone Żarki-Kotowice area 144-Ż borehole ? Karwowski et al. (2012)
Portugal
Évora Vila Viçosa Nossa Senhora da Conceição e São Bartolomeu Miguel Vacas Mine Gustavo Pereira Fernandes
Romania
Bihor County Nucet Băiţa mining district Cook et al. (2002) +1 other reference
Antoniu ore pipe Shimizu et al. (1998)
Blidar deposit Shimizu et al. (1998)
Secundar Contact deposit Shimizu et al. (1998)
Caraş-Severin County Ocna de Fier-Dognecea District Cook et al. (2002)
Ocna de Fier Paulus Mine Ciobanu +3 other references
Russia
Altai Republic Kosh-Agachsky District Kalgutinskoye W-Mo deposit (Kalguty) Potseluev et al. (2006)
Sakha Aldansky District Spokoininsky ore cluster Kondratieva et al. (2023)
Slovakia
Banská Bystrica Region Žarnovica District Hodruša-Hámre Hodruša-Hámre mines Rozália Mine Jeleň et al. (2012)
Košice Region Rožňava District Gemerská Poloma Koděra (1986)
Trenčín Region Bánovce nad Bebravou District Čierna Lehota Ni-Bi-As occurrence Mikuš T. (dipl.práca) +2 other references
Switzerland
Valais Saint-Maurice Evionnaz Salanfe Robert Mine (Arsenic mine) ? Meisser (2012)
Sierre Anniviers Ayer Lapine Rousse Mine Ansermet (2012)
Grimentz Baicolliou Mine Picot et al. (1977)
USA
California Mono County Bodie Hills Masonic Mining District New York Hill Pittsburg-Liberty Mine (Pittsburg claim; Pittsburg No. 2 claim; Liberty claim; Liberty No. 2 claim) MarekC pers. coll. 2017-2018
Colorado Custer County Rosita Mining District Twenty-Six Shafts Eckel et al. (1997)
Park County Montezuma Mining District Hall Valley (Hall's Valley) Missouri Mine (TL) Amer.J.Sci. (1884) +1 other reference
Summit County Montezuma Mining District (Snake River Mining District) USGS PP 223 (Lovering,1950)
Connecticut Middlesex County Portland Case Quarries Vajdak (1997)
Utah Piute County Mount Baldy-Ohio Mining District Deer Trail Mine Econ Geol (1986)
Tunnel Extension No. 2 Mine Bullock (1981) +1 other reference
Utah County East Tintic Mining District Bullock (1981)
Virginia Fairfax County Culpeper Basin Centreville Fairfax Quarry Dietrich (1990)