Latiumite (original) (raw)
A valid IMA mineral species - grandfathered
About LatiumiteHide
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Formula:
(Ca,K)4(Si,Al)5O11(SO4,CO3)
Colour:
White, may be zoned or mottled.
Crystal System:
Monoclinic
Name:
Named in 1953 by C.E. Tilley and N.F.M. Henry for Latium, the region of central western Italy that includes the type locality; this is the Latin form of the name, the modern name is Lazio.
A 2D-zeolite that - alongside with the related tuscanite - may be considered a prototype of advanced ion-exchange & ion/proton conductivity materials.
Unique IdentifiersHide
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Long-form identifier:
mindat:1:1:2336:4
cb05a668-5834-4c81-bd62-3e847ed012b1
IMA Classification of LatiumiteHide
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Approved, 'Grandfathered' (first described prior to 1959)
Type description reference:
Classification of LatiumiteHide
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9.EG.45
9 : SILICATES (Germanates)
E : Phyllosilicates
G : Double nets with 6-membered and larger rings
73.1.2.1
73 : PHYLLOSILICATES Condensed Tetrahedral Sheets
1 : Condensed Tetrahedral Sheets with double layers
17.10.6
17 : Silicates Containing other Anions
10 : Silicates with sulphate, molybdate or tungstate
Mineral SymbolsHide
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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Symbol | Source | Reference |
---|---|---|
Lat | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of LatiumiteHide
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Transparency:
Transparent, Translucent
Colour:
White, may be zoned or mottled.
Density:
2.93 g/cm3 (Measured) 2.92 g/cm3 (Calculated)
Optical Data of LatiumiteHide
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RI values:
_n_α = 1.600 - 1.603 _n_β = 1.606 - 1.609 _n_γ = 1.614 - 1.615
2V:
Measured: 83° to 90°, Calculated: 84° to 88°
δ = 0.014
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Chemistry of LatiumiteHide
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Mindat Formula:
(Ca,K)4(Si,Al)5O11(SO4,CO3)
Common Impurities:
Mn,Na,Cl,H20,C
Crystallography of LatiumiteHide
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Crystal System:
Monoclinic
Class (H-M):
2 - Sphenoidal
Cell Parameters:
a = 12.06(1) Å, b = 5.08(2) Å, c = 10.81(1) Å
β = 106.0°
Ratio:
a:b:c = 2.374 : 1 : 2.128
Unit Cell V:
636.62 ų (Calculated from Unit Cell)
Twinning:
On {100} common, simple or multiple.
Crystal StructureHide
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ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
---|---|---|---|---|---|---|---|
0000319 | Latiumite | Cannillo E, Dal Negro A, Rossi G (1973) The crystal structure of latiumite, a new type of sheet silicate American Mineralogist 58 466-470 | ![]() |
1973 | 0 | 293 |
CIF Raw Data - click here to close
X-Ray Powder DiffractionHide
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Powder Diffraction Data:
d-spacing | Intensity |
---|---|
2.86 Å | (s1) |
3.06 Å | (s2) |
2.96 Å | (s3) |
2.54 Å | (s) |
4.6 Å | (m) |
4.5 Å | (m) |
3.83 Å | (m) |
Geological EnvironmentHide
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Type Occurrence of LatiumiteHide
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Place of Conservation of Type Material:
Cambridge University, Cambridge, England, 45482, 29799
Geological Setting of Type Material:
metamorphosed limestone ejected by volcanism.
Associated Minerals at Type Locality:
Other Language Names for LatiumiteHide
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Relationship of Latiumite to other SpeciesHide
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Other Members of Latiumite Group:
Levantite | KCa3Al2(SiO4)(Si2O7)(PO4) | Mon. 2 : _P_21 |
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Common AssociatesHide
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Associated Minerals Based on Photo Data:
Related Minerals - Strunz-mindat GroupingHide
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9.EG.05 | Cymrite | BaAl2Si2(O,OH)8 · H2O | Mon. 2 : _P_21 |
---|---|---|---|
9.EG.10 | Naujakasite | (Na,K)6(Fe2+,Mn2+,Ca)(Al,Fe)4Si8O26 | Mon. |
9.EG.10 | Manganonaujakasite | Na6(Mn2+,Fe2+)Al4Si8O26 | Mon. 2/m : _B_2/m |
9.EG.15 | Dmisteinbergite | Ca(Al2Si2O8) | Trig. 32 : _P_312 |
9.EG.20 | Kampfite | Ba12(Si11Al5)O31(CO3)8Cl5 | Mon. m |
9.EG.25 | Vertumnite | Ca4Al4Si4O6(OH)24 · 3H2O | Mon. 2/m : _P_21/m |
9.EG.25 | Strätlingite | Ca2Al2SiO7 · 8H2O | Trig. 3_m_ : R_3_m |
9.EG.30 | Eggletonite | (Na,K,Ca)2(Mn,Fe)8(Si,Al)12O29(OH)7 · 11H2O | Mon. |
9.EG.30 | Ganophyllite | (K,Na,Ca)2Mn8(Si,Al)12(O,OH)32 · 8H2O | Mon. 2/m |
9.EG.30 | Tamaite | (Ca,K,Ba,Na)3-4Mn24(Si,Al)40(O,OH)112 · 21H2O | Mon. 2/m : _P_21/b |
9.EG.35 | Zussmanite | K(Fe,Mg,Mn)13(Si,Al)18O42(OH)14 | Trig. 3 : _R_3 |
9.EG.35 | Coombsite | KMn2+13(Si,Al)18O42(OH)14 | Trig. |
9.EG.40 | Chalcodite | K(Fe3+,Mg,Fe2+)8(Si,Al)12(O,OH)27 | Tric. 1 : _P_1 |
9.EG.40 | Parsettensite | (K,Na,Ca)7.5(Mn,Mg)49Si72O168(OH)50 · nH2O | Mon. 2/m : _B_2/m |
9.EG.40 | Franklinphilite | (K,Na)4(Mn2+,Mg,Zn)48(Si,Al)72(O,OH)216 · 6H2O | Tric. |
9.EG.40 | Lennilenapeite | K6-7(Mg,Mn,Fe,Zn)48(Si,Al)72(O,OH)216 · 16H2O | Tric. |
9.EG.40 | Stilpnomelane | (K,Ca,Na)(Fe,Mg,Al)8(Si,Al)12(O,OH)36 · nH2O | Tric. 1 : _P_1 |
9.EG.45 | Levantite | KCa3Al2(SiO4)(Si2O7)(PO4) | Mon. 2 : _P_21 |
9.EG.45 | Tuscanite | KCa6(Si,Al)10O22(SO4,CO3)2(OH) · H2O | Mon. 2/m : _P_21/b |
9.EG.50 | Jagoite | Pb18Fe3+4[Si4(Si,Fe3+)6][Pb4Si16(Si,Fe)4]O82Cl6 | Hex. 6_m_2 : _P_6_c_2 |
9.EG.50 | Friisite | Pb8Al3Si8O27Cl3 | Hex. 6_m_2 : P_62_c |
9.EG.55 | Wickenburgite | CaPb3Al2Si10O24(OH)6 | Trig. 3_m_ : P_31_c |
9.EG.60 | Hyttsjöite | Pb18Ba2Ca5Mn2+2Fe3+2Si30O90Cl · 6H2O | Trig. 3 : _R_3 |
9.EG.65 | Armbrusterite | K5Na7Mn15[(Si9O22)4](OH)10 · 4H2O | Mon. 2/m : _B_2/m |
9.EG.70 | Roymillerite | Pb24Mg9(Si10O28)(CO3)10(BO3)(SiO4)(OH)13O5 | Tric. 1 : _P_1 |
9.EG.70 | Britvinite | [Pb7(OH)3F(BO3)2(CO3)][Mg4.5(OH)3(Si5O14)] | Tric. 1 : _P_1 |
9.EG.75 | Kayupovaite | Na2Mn10[(Si14Al2)O38(OH)8] · 7H2O | Mon. 2/m : _B_2/b |
9.EG.75 | UM1989-30-SiO:AlBaCaFeHKMgMn | (Ba,Ca)(Mn,Fe,Mg)22(Si,Al)32O76(OH)16 · 12H2O | |
9.EG.75 | Bannisterite | (Ca,K,Na)(Mn2+,Fe2+)10(Si,Al)16O38(OH)8 · nH2O | Mon. 2/m : _B_2/b |
Other InformationHide
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Thermal Behaviour:
Fuses before the blowpipe. The resulting glass partly devitrifies at a low read heat to a fine grained product.
Notes:
Soluble in weak acids, leaving a silica residue.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for LatiumiteHide
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References for LatiumiteHide
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Reference List:
Zubkova, Natalia V., Chukanov, Nikita V., Varlamov, Dmitry A., Vigasina, Marina F., Pekov, Igor V., Ksenofontov, Dmitry A., Pushcharovsky, Dmitry Yu. (2023) New data on the crystal chemistry of the natural two-layer aluminosilicates latiumite and tuscanite. Acta Crystallographica Section B Structural Science, Crystal Engineering and Materials, 79 (4) 296-304 doi:10.1107/s2052520623004638
Localities for LatiumiteHide
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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The
symbol next to localities in the list can be used to jump to that position on the map.
Locality ListHide
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- This locality has map coordinates listed.
- This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties).
Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).
All localities listed without proper references should be considered as questionable.
France | |
---|---|
Occitanie Aveyron Rodez Sévérac-d'Aveyron ⓘ Lapanouse-de-Sévérac slag locality ? | publication date: November 2018 +1 other reference |
Italy (TL) | |
Lazio Metropolitan City of Rome Capital Albano Laziale ⓘ I Cappuccini (Cappuccini Quarry) (TL) | Tilley et al. (1953) +2 other references |
ⓘ Ariccia | De Michele (1974) +1 other reference |
ⓘ Parco Chigi | Rossano Carlini collection |
Campagnano di Roma ⓘ Cassia State Road | |
ⓘ Cava di Campagnano | |
Rocca di Papa ⓘ |
Tilley et al. (1953) |
ⓘ Sacrofano | Dan Behnke Collection |
Viterbo Province Gradoli ⓘ Poggio Pinzo (Gradoli pozzolana quarry) | Signoretti et al. (2001) |
Onano ⓘ Montenero Quarry | Cresta et al. (2002) |
Tuscany Grosseto Province Pitigliano ⓘ Case Collina | Liotti L. (Grosseto) |