Laurionite (original) (raw)

A valid IMA mineral species - grandfathered

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About LaurioniteHide

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Lustre:

Adamantine, Pearly

Crystal System:

Orthorhombic

Name:

Named in 1887 by Rudolf Ignatz Koechlin after the type locality at Laurion, Greece. (Note that the type material consists of a piece of oxidised galena ore, not a slag.)

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:2343:2

0da45688-3470-4506-b859-7fe594ee640e

IMA Classification of LaurioniteHide

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Approved, 'Grandfathered' (first described prior to 1959)

Type description reference:

Classification of LaurioniteHide

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3.DC.05

3 : HALIDES
D : Oxyhalides, hydroxyhalides and related double halides
C : With Pb (As,Sb,Bi), without Cu

10.2.2.1

10 : OXYHALIDES AND HYDROXYHALIDES
2 : A(O,OH)Xq

8.8.7

8 : Halides - Fluorides, Chlorides, Bromides and Iodides; also Fluoborates and Fluosilicates
8 : Halides of Pb

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol Source Reference
Lri IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Pronunciation of LaurioniteHide

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Pronunciation:

Play Recorded by Country
Sorry, your browser doesn't support HTML5 audio. Jolyon Ralph United Kingdom

Physical Properties of LaurioniteHide

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Cleavage:

Distinct/Good
distinct on {101}.

Density:

6.241 g/cm3 (Measured) 6.212 g/cm3 (Calculated)

Optical Data of LaurioniteHide

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RI values:

_n_α = 2.077 _n_β = 2.116 _n_γ = 2.158

2V:

Measured: 70° , Calculated: 90°

δ = 0.081

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.

Chemistry of LaurioniteHide

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Crystallography of LaurioniteHide

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Crystal System:

Orthorhombic

Class (H-M):

m m m _(_2/_m_2/_m_2/m ) - Dipyramidal

Cell Parameters:

a = 7.1110 Å, b = 9.6987 Å, c = 4.0203 Å

Ratio:

a:b:c = 0.733 : 1 : 0.415

Unit Cell V:

277.27 ų (Calculated from Unit Cell)

Morphology:

Crystals elongated [010] thick to thin tabular {100}. Often sword-shaped morphology. {100} striated [021] at times. Significant form {812} is generally replaced, or accompanied, by vicinal faces. Also lenticular.

Comment:

Non-standard space-group setting Pcmn.

Crystallographic forms of LaurioniteHide

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Crystal Atlas:

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Crystal StructureHide

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ID Species Reference Link Year Locality Pressure (GPa) Temp (K)
0010776 Laurionite Venetopoulos C C, Rentzeperis P J (1975) The crystal structure of laurionite, Pb(OH)Cl Zeitschrift fur Kristallographie 141 246-259 1975 0 293
0011877 Laurionite Wyckoff R W G (1963) Second edition. Interscience Publishers, New York, New York Crystal Structures 1 298-306 1963 0 293
0017980 Laurionite Brasseur H (1940) Etude roentgenographique de la laurionite Pb Cl (O H) _cod_database_code 1011083 Bulletin de la Societe Royal des Sciences de Liege 9 166-169 1940 0 293
0017924 Laurionite Goldsztaub S (1937) Structure cristalline de la laurionite _cod_database_code 1011017 Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences 204 702-703 1937 0 293

CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

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Powder Diffraction Data:

d-spacing Intensity
4.01 Å (100)
3.30 Å (55)
2.30 Å (50)
3.56 Å (40)
3.33 Å (30)
5.7 Å (25)
2.87 Å (25)

Geological EnvironmentHide

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Geological Setting:

Saline water acting on lead slags. Oxidation zone in lead deposits.

Type Occurrence of LaurioniteHide

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General Appearance of Type Material:

Lath shaped crystals to 5 mm in length

Associated Minerals at Type Locality:

Reference:

Köchlin, R. (1887) Ueber Phosgenit und ein muthmasslich neues Mineral vom Laurion. Annalen des K.K. Naturhistorischen Hofmuseums: 2: 185-190.

Synonyms of LaurioniteHide

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Other Language Names for LaurioniteHide

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Relationship of Laurionite to other SpeciesHide

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Other Members of this group:

Common AssociatesHide

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Associated Minerals Based on Photo Data:

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Other InformationHide

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Notes:

Slightly soluble in cold water, more soluble in warm water. Soluble in nitric acid.

Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

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References for LaurioniteHide

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Reference List:

**Palache, Charles, Berman, Harry, Frondel, Clifford (1951) The System of Mineralogy (7th ed.) Vol. 2 - Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, Ect. John Wiley and Sons, New York.**pp.62-64

Lutz, H.D., Beckenkamp, K., Kellersohn, T., Möller, H., Peter, S. (1996) Neutron and X-ray structure determination of laurionite-type Pb{O(H,D)}X, with X=Cl, Br, and I, Hydrogen Bonds to Lead (II) Ions as a Hydrogen-Bond Acceptor. Journal of Solid State Chemistry: 124: 156-161.

**Anthony, John Williams, Bideaux, Richard A., Bladh, Kenneth W., Nichols, Monte C. - Ed. (1997) Handbook of Mineralogy Vol. 3 - Halides, Hydroxides, Oxides. Mineral Data Publishing, Tucson, Arizona. p.1-682.**pp.307-307

Localities for LaurioniteHide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

Australia
New South Wales Robinson Co. Cobar Endeavor Mine (Elura Mine) Chapman et al. (2005) +1 other reference
South Australia Pastoral Unincorporated Area Mount Lyndhurst Avondale Mine Toma (2017)
Paris silver deposit Paul et al. (2015)
Tasmania Central Coast municipality Penguin www.crocoite.com (2003)
Penguin Mine (Penguin silver mine) Bottrill et al. (2008)
Western Australia Ashburton Shire Ashburton Downs Station Nickel et al. (1993)
Mineral Claim 84 Cu deposit (Anticline prospect) Nickel et al. (1993)
Exmouth Shire Rapid shipwreck MacLeod (1991)
Austria
Carinthia Sankt Veit an der Glan District Guttaring Waitschach Slag localities Kolitsch et al. (2009) +2 other references
Canada
Québec Estrie Les Sources RCM Val-des-Sources Jeffrey Mine Horváth et al. (2013)
Chile
Antofagasta Antofagasta Province Sierra Gorda Caracoles mining district Caracoles Unión Minera mine Georges Favreau collection
Czech Republic
Central Bohemian Region Příbram District Lhota u Příbramě Lhota Smelter (Lotha Smelter) slag locality RÜSENBERG et al. (1996)
Moravian-Silesian Region Karviná District Doubrava Doubrava Mine ? Jirásek J. et al. (Czech part of the Upper Silesian Basin)
France
Auvergne-Rhône-Alpes Loire Roanne Le Crozet Les Rats Mine slag dumps Vernay (1997)
Brittany Côtes-d'Armor Guingamp Carnoët Menez-Plom Slag dumps P. Le Roch collection
Finistère Châteaulin Poullaouen La Fonderie slag locality Germain C. et al. (1990)
Provence-Alpes-Côte d'Azur Var Toulon Le Pradet Cap Garonne Mine Favreau et al. (2024)
North mine Georges FAVREAU collection & EDX ... +1 other reference
Germany
Hesse Kassel Region Hersfeld-Rotenburg Nentershausen Süß Richelsdorf Smelter Slag dumps Weiß (1990)
Lower Saxony Goslar District Langelsheim Astfeld Herzog Julius smelter slag locality van den Berg et al. (1990)
Lautenthal Drachenhöhlental slag locality Luetcke (n.d.)
North Rhine-Westphalia Cologne Euskirchen Kall Copper smelter slag locality Blaß et al. (1995)
Düsseldorf Essen Dellwig Christian Levin coal mine Weiß (1990)
Münster Recklinghausen Marl Hüls Auguste Victoria coal mine Weiß (1990)
Rhineland-Palatinate Rhein-Lahn-Kreis Loreley Braubach Lead and silver smelter slag locality Schnorrer (1993)
Greece (TL)
Attica East Attica Lavreotiki Lavrion Mining District (TL) Köchlin (1887)
Lavrion slag localities Herbert Smith et al. (1899) +4 other references
Agios Nikolaos Cove slag locality Fritz Schreiber collection (SXRD-analysed by Uwe Kolitsch)
Harakas Cove slag locality Fritz Schreiber collection +1 other reference
Lavrion Port slag locality
Legrena Cove slag locality (Legraina Cove) van Kalmthout (2012)
Oxygono Cove slag locality (Oxygono Bay slag locality)
Panormos Cove slag locality
Passa Limani Cove slag locality Gelaude et al. (1996)
Sounion Cove slag locality Gelaude et al. (1996)
Thorikos Bay slag locality Gelaude et al. (1996)
Tourkolimanon Cove slag locality
Vrysaki Point slag locality Lacroix et al. (1908) +1 other reference
Israel
Southern District (HaDarom District) Ramat Negev Regional Council Makhtesh Ramon (Ramon crater) Shen Ramon syenite Itamar (1993)
Italy
Lazio Metropolitan City of Rome Capital Anzio Tor Caldara slag locality Marco Bonifazi collection
Liguria Genoa Genoa Varenna Valley Carpenara slag locality Rivista Mineralogica Italiana (Avril/Juin)
Lombardy Lecco Province Primaluna Cortabbio Sassi Rossi mine Luigi Possenti Collection
Tuscany Livorno Province Campiglia Marittima Madonna di Fucinaia (Madonna della Fucinaia) slag heaps Capattoli Valley slag locality www.comune.pisa.it (2000)
Piombino Baratti slag locality Franzini et al. (1992) +2 other references
Sassetta Canina Valley Podere del Cancellino (Podere dei Cancellini) slag locality Jansen et al. (1998)
Mozambique
Nampula Province Monapo District Evate carbonatite Hurai (2015)
Norway
Nordland Narvik Hundholmen Husdal (2019)
South Africa
Mpumalanga Nkangala District Municipality Victor Khanye Local Municipality Delmas Argent Dwarsfontein Farm Transvaal Mine East Trench Cairncross et al. (1995)
Spain
Andalusia Almería Cuevas del Almanzora Sierra Almagrera Villaricos Slag locality Georges FAVREAU collection + EDS
Canary Islands Santa Cruz de Tenerife Province Tenerife Candelaria Barranco Hondo Lava flow Dill et al. (2023)
Poris de Abona Dill et al. (2023)
Murcia Mazarrón Santa Elisa smelter slag locality Van den Berg et al. (2020)
Tunisia
Mahdia Mahdia Late-Hellenistic shipwreck Kutzke et al. (1997)
Turkmenistan
Balkan Province Cheleken Peninsula Türkmenbaşy Lebedev et al. (1983)
UK
England Bristol Westbury on Trym Wesley Mine Day (1999)
Cornwall Crantock The Gannel Smelter slag locality BMS Newsletter 79 (http://britishmicromountsociety.homestead.com/Gannell-Smelter.html)
Feock Penpol Penpol smelter slag locality Chollet Pascal Collection
Porthleven Wheal Rose (Wheal Lomax) Russell et al. (1927) +1 other reference
St Hilary Penberthy Croft Mine Betterton (2000)
County Durham Healeyfield Castleside Smelting Mill slag locality Norman Wilson collection
Stanhope Bollihope Smelt Mill slag locality Norman Wilson collection
Somerset Mendip Cranmore Torr Works Quarry Turner et al. (2010)
Wales Ceredigion Ceulanymaesmawr Tal-y-bont Eaglebrook Mine Rust (1995)
USA
California San Bernardino County Silver Lake Mining District Soda Mountains Baker Otto Mountain Bird Nest drift Collected by Chuck Adan. EDS confirmed ...
Minnesota St. Louis County Ely-Hoyt Lakes Area Mesaba deposit (Minnamax deposit; Babbitt deposit; Babbitt Lake deposit; Amax Underground Mine) McSwiggen (1999)
New Mexico Eddy County Gnome event (Project Gnome test site) Northrop et al. (1996)
Vietnam