Pennantite (original) (raw)

08668880014947046865413.jpg

Formula:

Mn2+5Al(AlSi3O10)(OH)8

Colour:

Orange-red, red-brown, brown, dark red, dark green, black

Specific Gravity:

2.89 - 3.07

Name:

Named in 1946 by Walter Campbell Smith, Frederick Allen Bannister, and Max Hutchinson Hey in honor of Thomas Pennant [14 June {Old Style}, 1726 Whitford, Flintshire, Wales, United Kingdom - 16 December 1798 Whitford, Flintshire, Wales], author, naturalist, and antiquary.

Forms solid solution series with clinochlore and chamosite.
However, Abrecht (1989) gave evidence for a miscibility gap between pennantite and clinochlore.

Compare also gonyerite, a chemically similar, but Al-free Mn-member of the chlorite group.

RI values:

_n_α = 1.615 - 1.664 _n_β = 1.661 _n_γ = 1.622 - 1.673

δ = 0.007 - 0.009

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.

Comments:

X = pinkish orange, orange-buff, reddish brown
Y = Z = orange, yellowish orange, very dark brown

Comments:

Absorption: Y = Z > X.

Cell Parameters:

a = 5.45 Å, b = 9.50 Å, c = 14.40 Å
α = 90°, β = 97.3°, γ = 90°

Ratio:

a:b:c = 0.574 : 1 : 1.516

Unit Cell V:

739.52 ų (Calculated from Unit Cell)

Morphology:

Lamellar crystals and flakes.

Comment:

Point Group: 1 or 1; Space Group: P1 or P1.

General Appearance of Type Material:

Very poorly crystallized as patches and small specks in the matrix. Less commonly it occurs as minute flakes in the ore and sometimes as a constituent of very thin veins which traverse the ore. In some specimens the mineral is better developed forming orange-brown micaceous flakes to 0.5 mm. Patches of the mineral in the matrix frequently enclose very small garnets.

Place of Conservation of Type Material:

The Natural History Museum, London, England, 1947,295-296.
Harvard University, Cambridge, Massachusetts, USA, 104705.
National Museum of Natural History, Washington, D.C., USA, 105855.

Geological Setting of Type Material:

Hydrothermal alteration of manganese deposits.

Associated Minerals at Type Locality:

Reference:

Smith W C, Bannister F A, Hey M H (1946) Pennantite, a new manganese-rich chlorite from Benallt mine, Rhiw, Carnarvonshire. Mineralogical Magazine 27, 217-220

9.EC. Balestraite KLi2V5+Si4O12 Mon. 2 : _B_2
9.EC. Meifuite KFe6(Si7Al)O19(OH)4Cl2 Tric. 1 : _P_1
9.EC.05 Minnesotaite Fe2+3Si4O10(OH)2 Tric. 1 : _P_1
9.EC.05 Talc Mg3Si4O10(OH)2 Tric. 1 : _P_1
9.EC.05 Willemseite Ni3Si4O10(OH)2 Mon.
9.EC.9.EC. Voloshinite Rb(LiAl1.5◻0.5)(Al0.5Si3.5)O10F2 Mon. 2/m : _B_2/b
9.EC.10 Ferripyrophyllite Fe3+Si2O5(OH) Mon. 2/m
9.EC.10 Pyrophyllite Al2Si4O10(OH)2 Tric. 1
9.EC.10 Luanshiweiite KLiAl1.5(Si3.5Al0.5)O10(OH)2 Mon. 2/m : _B_2/b
9.EC.10 Fluorluanshiweiite KLiAl1.5(Si3.5Al0.5)O10F2 Mon. 2/m : _B_2/m
9.EC.10 Manganiceladonite K(MgMn3+◻)(Si4O10)(OH)2 Mon.
9.EC.10 Garmite CsLiMg2(Si4O10)F2 Mon.
9.EC.10 Gorbunovite CsLi2(Ti,Fe)Si4O10(F,OH,O)2 Mon.
9.EC.15 Boromuscovite KAl2(BSi3O10)(OH)2 Mon. 2/m
9.EC.15 Celadonite K(MgFe3+◻)(Si4O10)(OH)2 Mon. 2/m : _B_2/m
9.EC.15 Chernykhite (Ba,Na)(V3+,Al,Mg)2((Si,Al)4O10)(OH)2 Mon.
9.EC.15 Montdorite (K,Na)2(Fe2+,Mn2+,Mg)5(Si4O10)2(OH,F)4 Mon. 2/m : _B_2/m
9.EC.15 Muscovite KAl2(AlSi3O10)(OH)2 Mon. 2/m : _B_2/b
9.EC.15 Nanpingite CsAl2(AlSi3O10)(OH,F)2 Mon. 2/m : _B_2/b
9.EC.15 Paragonite NaAl2(AlSi3O10)(OH)2 Mon.
9.EC.15 Roscoelite K(V3+,Al)2(AlSi3O10)(OH)2 Mon. 2/m : _B_2/b
9.EC.15 Tobelite (NH4,K)Al2(AlSi3O10)(OH)2 Mon. 2/m : _B_2/m
9.EC.15 Aluminoceladonite K(MgAl◻)(Si4O10)(OH)2 Mon. 2/m : _B_2/m
9.EC.15 Chromphyllite K(Cr,Al)2(AlSi3O10)(OH,F)2 Mon. 2/m : _B_2/b
9.EC.15 Ferroaluminoceladonite K(Fe2+Al◻)(Si4O10)(OH)2 Mon. 2/m : _B_2/m
9.EC.15 Ferroceladonite K(Fe2+Fe3+◻)(Si4O10)(OH)2 Mon. 2/m : _B_2/m
9.EC.15 Chromceladonite K(MgCr◻)(Si4O10)(OH)2 Mon. 2 : _B_2
9.EC.15 Tainiolite KLiMg2(Si4O10)F2 Mon. 2/m : _B_2/m
9.EC.15 Ganterite (Ba,Na,K)(Al,Mg)2(AlSi3O10)(OH)2 Mon. 2/m : _B_2/b
9.EC.15 UM1988-22-SiO:AlCaFFeHKLiMg KLiMgAl2Si3O10F2 Mon.
9.EC.15 Kreiterite CsLi2Fe3+(Si4O10)F2 Mon.
9.EC.20 Annite KFe2+3(AlSi3O10)(OH)2 Mon. 2/m : _B_2/m
9.EC.20 Ephesite NaLiAl2(Al2Si2O10)(OH)2 Tric. 1 : _P_1
9.EC.20 Hendricksite KZn3(Si3Al)O10(OH)2 Mon. 2/m : _B_2/m
9.EC.20 Masutomilite (K,Rb)(Li,Mn3+,Al)3(AlSi3O10)(F,OH)2 Mon. 2 : _B_2
9.EC.20 Norrishite KLiMn3+2(Si4O10)O2 Mon. 2/m : _B_2/m
9.EC.20 Phlogopite KMg3(AlSi3O10)(OH)2 Mon. 2/m : _B_2/m
9.EC.20 Polylithionite KLi2Al(Si4O10)(F,OH)2 Mon. 2/m : _B_2/b
9.EC.20 Preiswerkite NaMg2Al(Al2Si2O10)(OH)2 Mon. 2/m : _B_2/b
9.EC.20 Siderophyllite KFe2+2Al(Al2Si2O10)(OH)2 Mon.
9.EC.20 Tetraferriphlogopite KMg3(Fe3+Si3O10)(OH,F)2 Mon. 2/m : _B_2/m
9.EC.20 Fluorotetraferriphlogopite KMg3(Fe3+Si3O10)F2 Mon. 2/m : _B_2/m
9.EC.20 Wonesite (Na,K)(Mg,Fe,Al)6((Al,Si)4O10)2(OH,F)4 Mon. 2/m : _B_2/m
9.EC.20 Eastonite KMg2Al(Al2Si2O10)(OH)2 Mon.
9.EC.20 Tetraferriannite KFe2+3(Si3Fe3+)O10(OH)2 Mon. 2/m : _B_2/m
9.EC.20 Trilithionite K(Li1.5Al1.5)(AlSi3O10)(F,OH)2 Mon. 2/m : _B_2/b
9.EC.20 Fluorannite KFe2+3(Si3Al)O10F2 Mon. 2/m : _B_2/m
9.EC.20 Shirokshinite K(NaMg2)(Si4O10)F2 Mon. 2/m : _B_2/m
9.EC.20 Shirozulite KMn2+3(Si3Al)O10(OH)2 Mon. 2/m : _B_2/m
9.EC.20 Sokolovaite CsLi2Al(Si4O10)F2 Mon.
9.EC.20 Aspidolite NaMg3(AlSi3O10)(OH)2 Mon. 2/m : _B_2/m
9.EC.20 Fluorophlogopite KMg3(Si3Al)O10F2 Mon. 2/m : _B_2/m
9.EC.20 UM2004-49-SiO:AlCsFHKLi (Cs,K)(Al,Li)2.6((Si,Al)4O10)(F,OH)2
9.EC.20 Suhailite (NH4)Fe2+3(AlSi3O10)(OH)2 Mon. 2/m : _B_2/m
9.EC.20 Yangzhumingite KMg2.5(Si4O10)F2 Mon. 2/m : _B_2/m
9.EC.20 Orlovite KLi2Ti(Si4O10)OF Mon. 2 : _B_2
9.EC.20 Oxyphlogopite K(Mg,Ti,Fe)3[(Si,Al)4O10](O,F)2 Mon. 2/m : _B_2/m
9.EC.20 Chloroferrokinoshitalite (Ba,K)(Fe2+,Mg)3(Al2Si2O10)(Cl,OH,F)2
9.EC.22 Pimelite Ni3Si4O10(OH)2 · 4H2O Hex.
9.EC.30 Chlorophaeite (Ca,Mg,Fe)2Fe2Si4O13 · 10H2O
9.EC.30 Margarite CaAl2(Al2Si2O10)(OH)2 Mon. 2/m : _B_2/b
9.EC.35 Anandite (Ba,K)(Fe2+,Mg)3((Si,Al,Fe)4O10)(S,OH)2 Mon. 2/m : _B_2/b
9.EC.35 Bityite CaLiAl2(AlBeSi2O10)(OH)2 Mon. 2/m : _B_2/b
9.EC.35 Clintonite CaAlMg2(SiAl3O10)(OH)2 Mon. 2/m : _B_2/m
9.EC.35 Kinoshitalite (Ba,K)(Mg,Mn2+,Al)3(Al2Si2O10)(OH)2 Mon. 2/m : _B_2/m
9.EC.35 Ferrokinoshitalite (Ba,K)(Fe2+,Mg)3(Al2Si2O10)(OH,F)2 Mon. 2/m : _B_2/m
9.EC.35 Oxykinoshitalite (Ba,K)(Mg,Ti,Fe3+,Fe2+)3((Si,Al)4O10)(O,OH,F)2 Mon. 2/m : _B_2/m
9.EC.35 Fluorokinoshitalite BaMg3(Al2Si2O10)F2 Mon. 2/m : _B_2/m
9.EC.40 Beidellite (Na,Ca0.5)0.3Al2((Si,Al)4O10)(OH)2 · nH2O Mon. 2/m : _B_2/m
9.EC.40 Kurumsakite (Zn,Ni,Cu)8Al8V5+2Si5O35 · 27H2O (?) Orth.
9.EC.40 Montmorillonite (Na,Ca)0.33(Al,Mg)2(Si4O10)(OH)2 · nH2O Mon. 2/m : _B_2/m
9.EC.40 Nontronite Na0.3Fe2((Si,Al)4O10)(OH)2 · nH2O Mon. 2/m : _B_2/m
9.EC.40 Volkonskoite Ca0.3(Cr,Mg,Fe)2((Si,Al)4O10)(OH)2 · 4H2O Mon.
9.EC.40 Yakhontovite (Ca,Na)0.5(Cu,Fe,Mg)2(Si4O10)(OH)2 · 3H2O Mon.
9.EC.45 Hectorite Na0.3(Mg,Li)3(Si4O10)(F,OH)2 Mon. 2/m : _B_2/m
9.EC.45 Saponite Ca0.25(Mg,Fe)3((Si,Al)4O10)(OH)2 · nH2O Mon.
9.EC.45 Sauconite Na0.3Zn3((Si,Al)4O10)(OH)2 · 4H2O Mon.
9.EC.45 Spadaite MgSiO2(OH)2 · H2O (?)
9.EC.45 Stevensite (Ca,Na)xMg3-x(Si4O10)(OH)2 Mon.
9.EC.45 Swinefordite Li(Al,Li,Mg)3((Si,Al)4O10)2(OH,F)4 · nH2O Mon. 2/m : _B_2/m
9.EC.45 Zincsilite Zn3Si4O10(OH)2 · 4H2O (?) Mon.
9.EC.45 Ferrosaponite Ca0.3(Fe2+,Mg,Fe3+)3((Si,Al)4O10)(OH)2 · 4H2O Mon.
9.EC.45 Hanjiangite Ba2CaV3+Al(H2AlSi3O12)(CO3)2F Mon. 2 : _B_2
9.EC.50 Vermiculite Mg0.7(Mg,Fe,Al)6(Si,Al)8O20(OH)4 · 8H2O Mon. 2/m
9.EC.52 Tarasovite near NaKAl11Si13O40(OH)9 · 3H2O
9.EC.55 Baileychlore (Zn,Fe2+,Al,Mg)6(Si,Al)4O10(OH)8 Tric. 1
9.EC.55 Chamosite (Fe2+)5Al(Si,Al)4O10(OH,O)8 Mon. 2/m : _B_2/m
9.EC.55 Clinochlore Mg5Al(AlSi3O10)(OH)8 Mon. 2/m : _B_2/m
9.EC.55 Cookeite (LiAl4◻)[AlSi3O10](OH)8 Mon. 2/m
9.EC.55 Franklinfurnaceite Ca2Fe3+Mn2+3Mn3+(Zn2Si2O10)(OH)8 Mon. 2 : _B_2
9.EC.55 Gonyerite (Mn2+,Mg)5Fe3+(Fe3+Si3O10)(OH)8 Orth.
9.EC.55 Nimite (Ni,Mg,Al)6((Si,Al)4O10)(OH)8 Mon. 2/m : _B_2/m
9.EC.55 Orthochamosite (Fe2+,Mg,Fe3+)5Al(AlSi3O10)(OH,O)8
9.EC.55 Sudoite Mg2Al3(Si3Al)O10)(OH)8 Mon. 2/m : _B_2/m
9.EC.55 Donbassite Al4.33(Si3Al)O10(OH)8 Mon. 2 : _B_2
9.EC.55 Glagolevite Na(Mg,Al)6(AlSi3O10)(OH,O)8 Tric. 1 : _P_1
9.EC.55 Borocookeite (LiAl4◻)[BSi3O10](OH)8 Mon. m : B b
9.EC.60 Aliettite Ca0.2Mg6((Si,Al)8O20)(OH)4 · 4H2O Mon.
9.EC.60 Corrensite (Mg,Fe)9((Si,Al)8O20)(OH)10 · nH2O Orth.
9.EC.60 Dozyite Mg7Al2(Al2Si4O15)(OH)12 Mon.
9.EC.60 Hydrobiotite K(Mg,Fe2+)6((Si,Al)8O20)(OH)4 · nH2O Mon. 2/m : _B_2/m
9.EC.60 Karpinskite (Ni,Mg)2Si2O5(OH)2 (?) Mon.
9.EC.60 Kulkeite Mg8Al(AlSi7O20)(OH)10 Mon.
9.EC.60 Lunijianlaite Li0.7Al6.2(AlSi7O20)(OH,O)10 Mon.
9.EC.60 Rectorite (Na,Ca)Al4((Si,Al)8O20)(OH)4 · 2H2O Mon.
9.EC.60 Saliotite (Li,Na)Al3(AlSi3O10)(OH)5 Mon. 2/m : _B_2/m
9.EC.60 Tosudite Na0.5(Al,Mg)6((Si,Al)8O18)(OH)12 · 5H2O Mon. 2 : _B_2
9.EC.60 Brinrobertsite Na0.3Al4(Si4O10)2(OH)4 · 3.5 H2O Mon.
9.EC.65 Macaulayite (Fe,Al)24Si4O43(OH)2 Mon.
9.EC.70 Burckhardtite Pb2(Fe3+Te6+)[AlSi3O8]O6 Trig. 3_m_ _(_32/m ) : P_31_m
9.EC.75 Ferrisurite (Pb,Ca)2.4Fe3+2(Si4O10)(CO3)1.7(OH)3 · nH2O Mon.
9.EC.75 Surite (Pb,Ca)3(Al,Fe2+,Mg)2((Si,Al)4O10)(CO3)2(OH)2 Mon. 2 : _P_21
9.EC.75 Niksergievite (Ba,Ca)2Al3(AlSi3O10)(CO3)(OH)6 · nH2O Mon.
9.EC.80 Kegelite Pb8Al4(Si8O20)(SO4)2(CO3)4(OH)8 Mon.

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

Australia
South Australia Pastoral Unincorporated Area Iron Knob Iron Monarch Main Pit Sorrell (n.d.)
Austria
Styria Bruck-Mürzzuschlag District Sankt Barbara im Mürztal Veitsch Kleinveitsch Kaiblinggraben Friedlkogel (Friedelkogel; Heinzlkogel) Francis (2004)
Tyrol Innsbruck-Land District Navis Navis stream (Navis creek) Kolitsch et al. (2019)
Trins Kirchdachspitze Kolitsch et al. (2021)
Greece
Attica East Attica Marathon Varnavas Stouraiti et al. (2022)
Italy
Liguria Genoa Ne Molinello Mine Matteo Chinellato specimen
Reppia Gambatesa Mine Palenzona (1990)
Statale Scrava Mine (Statale Mine) //doi.org/10.57635/MICRO.2023.21.7
Piedmont Metropolitan City of Turin Salbertrand Case Berge Ambrino et al. (2022)
Japan
Tochigi Prefecture Kanuma City Kaso Mine Akira Kato (undated manuscript)
Kazakhstan
Ulytau Region Karazhal Ushkatyn deposits (Ushkatan) Frank Dzubeck +1 other reference
Ushkatyn No. 1 deposit Hey et al. (1974)
Zhayrem (Zhairem) Ushkatyn No. 3 deposit (Ushkatyn-III deposit) Frank Dzubeck +3 other references
Romania
Bistriţa Mn belt Hirtopanu (2006)
Maramureș County Târgu Lăpuș Răzoare Udubasa et al. (1996) +2 other references
Russia
Khakassia (Republic of Khakassia) Askizsky Rayon Askiz ore district Chapsordag deposit Kassandrov et al. (2009)
Malosyrsky deposit Kassandrov et al. (2009)
South Africa
Limpopo Vhembe District Municipality Musina Local Municipality Musina
Messina Mine Cairncross et al. (1995)
Sweden
Värmland County Filipstad Långban Ore District Långban Mine Bjelke's shaft dump Grensman (2003)
Persberg ore district Pajsberg Harstigen Mine Nysten (1984)
Switzerland
Valais Leuk Turtmann-Unterems Turtmann Valley Pipjitälli Pipji glacier The Canadian Mineralogist Vol. 44 (2006) +1 other reference
UK (TL)
Wales Gwynedd Aberdaron Rhiw Benallt Mine (TL) Campbell Smith et al. (1946) +6 other references
USA
New Jersey Sussex County Franklin Franklin Mine Dunn et al. (1983) +2 other references
New Mexico Hidalgo County Pyramid Mountains Lordsburg Mining District Lordsburg Virginia District Jerry Cone Collection
North Carolina Alleghany County Sparta Bald Knob Bald Knob deposit Rocks & Min.: 60:130-135. +1 other reference
South Dakota Pennington County Keystone Mining District Keystone Roberts et al. (1965)
Washington Chelan County Chiwawa Mining District Phelps Ridge (Red Mountain) Trinity Mine Cannon (1975) +1 other reference
Leavenworth Mining District Icicle Creek Roadcuts Cannon (1975)
King County Snoqualmie Mining District Middle Fork of the Snoqualmie River Rainy Mine Cannon (1975)
Source Lake Breccia Cannon (1975)
Snohomish County Index Mining District Lake Serene Mine Cannon (1975)
Monte Cristo Mining District Silvertip Peak Cannon (1975)
Stevens County Deer Trail Mining District Read Mine Cannon (1975)