Cuprokalininite (original) (raw)

Long-form identifier:

mindat:1:1:40142:7

1e51d90c-2dd0-4cbf-95f0-f26ed2acbe81

IMA Formula:

Cu(Cr3+Cr4+)S4

Type description reference:

Reznitsky, L.Z., Sklyarov, E.V., Ushchapovskaya, Z.F., Suvorova, L.F., Polekhovsky, Yu.S., Dzerzanovsky, P., Barash, I.G. (2010) Cuprokalininite CuCr2S4 - the new sulfospinel from metamorphic rocks of Sludyanka Complex (South Baikal Region). [Zapiski Rossiyskogo Mineralogicheskogo Obshchestva], 139 (6) 39-49

2.DA.05

2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
D : Metal Sulfides, M: S = 3 :4 and 2:3
A : M:S = 3:4

2.10.1.20

2 : SULFIDES
10 : AmBnXp, with (m+n):p = 3:4

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol Source Reference
Ckal IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Comment:

Close to metallic

Comment:

with a weak dark bronze tint

Hardness:

VHN20=356 - 458 kg/mm2 - Vickers

Comment:

Mohs hardness was estimated from VHN.

Fracture:

Irregular/Uneven

Density:

4.16 g/cm3 (Calculated)

Reflectivity:

Wavelength R
400nm 34.30%
420nm 34.10%
440nm 33.90%
460nm 33.70%
480nm 33.50%
500nm 33.20%
520nm 33.00%
540nm 32.80%
560nm 32.50%
580nm 32.20%
600nm 31.90%
620nm 31.60%
640nm 31.20%
660nm 30.90%
680nm 30.60%
700nm 30.40%

Reflectance graph
Graph shows reflectance levels at different wavelengths (in nm). Top of box is 100%. Peak reflectance is 34.30%.

Colour in reflected light:

Pale cream

Internal Reflections:

None observed

Common Impurities:

V,Fe,Zn

Class (H-M):

m_3_m _(_4/_m_32/m ) - Hexoctahedral

Cell Parameters:

a = 9.814(2) Å

Morphology:

Dominant forms are {111} and {100} with distinct growth steps.

Twinning:

Polysynthetic twins on {111} are typical. Occasionally, simple twinning by the spinel law is identified.

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ID Species Reference Link Year Locality Pressure (GPa) Temp (K)
0012907 Cuprokalininite Raccah P M, Bouchard R J, Wold A (1966) Crystallographic study of chromium spinels Journal of Applied Physics 37 1436-1437 1966 synthetic 0 293
0013422 Cuprokalininite Riedel E, Karl R, Rackwitz R (1981) Mossbauer studies of thiospinels. V. The systems Cu1-xFexMe2S4 (Me=Cr,Rh) and Cu1-xFexCr2(S.7Se.3)4 Journal of Solid State Chemistry 40 255-265 1981 synthetic 0 293
0013423 Cuprokalininite Riedel E, Karl R, Rackwitz R (1981) Mossbauer studies of thiospinels. V. The systems Cu1-xFexMe2S4 (Me=Cr,Rh) and Cu1-xFexCr2(S.7Se.3)4 Journal of Solid State Chemistry 40 255-265 1981 synthetic 0 293
0013424 Cuprokalininite Riedel E, Karl R, Rackwitz R (1981) Mossbauer studies of thiospinels. V. The systems Cu1-xFexMe2S4 (Me=Cr,Rh) and Cu1-xFexCr2(S.7Se.3)4 Journal of Solid State Chemistry 40 255-265 1981 synthetic 0 293
0013425 Cuprokalininite Riedel E, Karl R, Rackwitz R (1981) Mossbauer studies of thiospinels. V. The systems Cu1-xFexMe2S4 (Me=Cr,Rh) and Cu1-xFexCr2(S.7Se.3)4 Journal of Solid State Chemistry 40 255-265 1981 synthetic 0 293
0013444 Cuprokalininite Riedel E, Karl R, Rackwitz R (1981) Mossbauer studies of thiospinels. V. The systems Cu1-xFexMe2S4 (Me=Cr,Rh) and Cu1-xFexCr2(S.7Se.3)4 Journal of Solid State Chemistry 40 255-265 1981 synthetic 0 293
0013445 Cuprokalininite Riedel E, Karl R, Rackwitz R (1981) Mossbauer studies of thiospinels. V. The systems Cu1-xFexMe2S4 (Me=Cr,Rh) and Cu1-xFexCr2(S.7Se.3)4 Journal of Solid State Chemistry 40 255-265 1981 synthetic 0 293
0013446 Cuprokalininite Riedel E, Karl R, Rackwitz R (1981) Mossbauer studies of thiospinels. V. The systems Cu1-xFexMe2S4 (Me=Cr,Rh) and Cu1-xFexCr2(S.7Se.3)4 Journal of Solid State Chemistry 40 255-265 1981 synthetic 0 293
0013447 Cuprokalininite Riedel E, Karl R, Rackwitz R (1981) Mossbauer studies of thiospinels. V. The systems Cu1-xFexMe2S4 (Me=Cr,Rh) and Cu1-xFexCr2(S.7Se.3)4 Journal of Solid State Chemistry 40 255-265 1981 synthetic 0 293
0013448 Cuprokalininite Riedel E, Karl R, Rackwitz R (1981) Mossbauer studies of thiospinels. V. The systems Cu1-xFexMe2S4 (Me=Cr,Rh) and Cu1-xFexCr2(S.7Se.3)4 Journal of Solid State Chemistry 40 255-265 1981 synthetic 0 293
0013449 Cuprokalininite Riedel E, Karl R, Rackwitz R (1981) Mossbauer studies of thiospinels. V. The systems Cu1-xFexMe2S4 (Me=Cr,Rh) and Cu1-xFexCr2(S.7Se.3)4 Journal of Solid State Chemistry 40 255-265 1981 synthetic 0 293
0013450 Cuprokalininite Riedel E, Karl R, Rackwitz R (1981) Mossbauer studies of thiospinels. V. The systems Cu1-xFexMe2S4 (Me=Cr,Rh) and Cu1-xFexCr2(S.7Se.3)4 Journal of Solid State Chemistry 40 255-265 1981 synthetic 0 293
0018335 Cuprokalininite Riedel E, Horvath E (1973) Spinelle mit substituierten Nichtmetallteilgittern. IV. Roentgenographische Untersuchung der Systeme CuCr2(S11-xSex)4 und CuCr3(Se1-xTex)4 Zeitschrift fur Anorganische und Allgemeine Chemie 399 219-224 1973 0 293

CIF Raw Data - click here to close

General Appearance of Type Material:

Euhedral octahedral or cubo-octahedral microcrystals up to 0.2 mm in size.

Place of Conservation of Type Material:

Fersman Mineralogical Museum, Russian Academy of Sciences, Moscow, catalog no. 3886/1-3

Geological Setting of Type Material:

In a Cr-V-bearing quartz-diopside metamorphic rock.

Associated Minerals at Type Locality:

Reference:

Reznitsky, L.Z., Sklyarov, E.V., Ushchapovskaya, Z.F., Suvorova, L.F., Polekhovsky, Yu.S., Dzerzanovsky, P., Barash, I.G. (2010) Cuprokalininite CuCr2S4 - the new sulfospinel from metamorphic rocks of Sludyanka Complex (South Baikal Region). Zapiski Rossiyskogo Mineralogicheskogo Obshchestva: 139(6): 39-49

Other Members of this group:

Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Reference List:

Reznitsky, L.Z., Sklyarov, E.V., Ushchapovskaya, Z.F., Suvorova, L.F., Polekhovsky, Yu.S., Dzerzanovsky, P., Barash, I.G. (2010) Cuprokalininite CuCr2S4 - the new sulfospinel from metamorphic rocks of Sludyanka Complex (South Baikal Region). [Zapiski Rossiyskogo Mineralogicheskogo Obshchestva], 139 (6) 39-49

Reznitsky, L. Z., Sklyarov, E. V., Ushchapovskaya, Z. F., Suvorova, L. F., Polekhovsky, Yu. S., Dzerzanovsky, P., Barash, I. G. (2011) Cuprokalininite, CuCr2S4, a new sulfospinel from metamorphic rocks of the Sludyanka Complex, South Baikal region. Geology of Ore Deposits, 53 (8) 758-766 doi:10.1134/s1075701511080137

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

Russia (TL)
Lake Baikal area Slyudyanka Pereval marble quarry (TL) Williams et al. (2010) +1 other reference