Ophirite (original) (raw)

A valid IMA mineral species

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About OphiriteHide

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Formula:

Ca2Mg4[Zn2Mn3+2(H2O)2(Fe3+W9O34)2] · 46H2O

Specific Gravity:

4.060 (Calculated)

Name:

Names for the type locality, Ophir Hill Consolidated mine, Ophir District, Oquirrh Mountains, Tooele County, Utah

Ophirite is the first known mineral to contain a lacunary defect derivative of the Keggin anion, a heteropolyanion that is well known in synthetic phases.

Awarded 'Mineral of the Year' by the IMA-CNMNC in 2014.

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:43845:8

6349bccd-5200-43ea-9916-3ad1f0022390

IMA Classification of OphiriteHide

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IMA Formula:

Ca2Mg4[Zn2Mn3+2(H2O)2(Fe3+W9O34)2] · 46H2O

Classification of OphiriteHide

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7.GB.80

7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
G : Molybdates, Wolframates and Niobates
B : With additional anions and/or H2O

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol Source Reference
Oph IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of OphiriteHide

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Fracture:

Irregular/Uneven

Density:

4.060 g/cm3 (Calculated)

Optical Data of OphiriteHide

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RI values:

_n_α = 1.730(3) _n_β = 1.735(3) _n_γ = 1.770(3)

δ = 0.040

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.

Comments:

X = light orange brown, Y = light orange brown, Z = orange brown; X < Y << Z

Chemistry of OphiriteHide

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Mindat Formula:

Ca2Mg4[Zn2Mn3+2(H2O)2(Fe3+W9O34)2] · 46H2O

heteropolytungstate

Crystallography of OphiriteHide

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Class (H-M):

1 - Pinacoidal

Cell Parameters:

a = 11.9860(2) Å, b = 13.2073(2) Å, c = 17.689(1) Å
α = 69.690(5)°, β = 85.364(6)°, γ = 64.875(5)°

Ratio:

a:b:c = 0.908 : 1 : 1.339

Morphology:

Tablets on {001} with irregular {100} and {110} bounding forms.

Crystal StructureHide

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ID Species Reference Link Year Locality Pressure (GPa) Temp (K)
0020331 Ophirite Kampf A R, Hughes J M, Nash B P, Wright S E, Rossman G R, Marty J (2014) Ophirite, Ca2Mg4[Zn2Mn3+2(H2O)2(Fe3+W9O34)2]*46H2O, a new mineral with a heteropolytungstate tri-lacunary Keggin anion American Mineralogist 99 1045-1051 2014 Ophir Hill Consolidated mine, Tooele County, Utah, USA 0 293

CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

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Powder Diffraction Data:

d-spacing Intensity
16.72 Å (38)
11.33 Å (91)
10.69 Å (100)
8.27 Å (55)
5.44 Å (33)
2.992 Å (75)
2.760 Å (55)
2.594 Å (33)

Geological EnvironmentHide

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Type Occurrence of OphiriteHide

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General Appearance of Type Material:

orange-brown tablets on {001} with irregular {100} and {110} bounding forms. Individual crystals up to about 1mm in maximum dimension.

Place of Conservation of Type Material:

Cotype specimens - Natual History Museum of Los Angeles County, Los Angeles, California, catalog numbers 64029 and 64030

Synonyms of OphiriteHide

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Common AssociatesHide

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Associated Minerals Based on Photo Data:

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7.GB. Wangpuite K3(PO4)(Mo12O36) Iso. m_3_m _(_4/_m_32/m ) : P n_3_m
7.GB. Natromolybdite Na2MoO4 · 2H2O Orth. m m m _(_2/_m_2/_m_2/m ) : P b c a
7.GB. Ootannite Th4+2W6+4O16 · 5H2O Mon. 2/m : _P_21/b
7.GB.05 Lindgrenite Cu3(MoO4)2(OH)2 Mon. 2/m : _P_21/m
7.GB.10 Szenicsite Cu3(MoO4)(OH)4 Orth. m m m _(_2/_m_2/_m_2/m ) : P n n m
7.GB.15 Cuprotungstite Cu2(WO4)(OH)2 Tet. 422 : _P_41212
7.GB.15 UM1999-38-WO:CrV (V, Cr, W, O, H) [V:Cr:W ratio about 2:1:3]
7.GB.15 Huenite Cu4(MoO4)3(OH)2 Trig. 3_m_ : P_31_c
7.GB.20 Phyllotungstite (H2O,M)x(W,Fe)(O,OH)3 · yH2O (M = Ca, Cs, Pb or K) Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_63/m m c
7.GB.25 Rankachite Ca0.5(V4+,V5+)(W6+,Fe3+)2O8(OH) · 2H2O Mon. 2/m : _P_21/m
7.GB.30 Ferrimolybdite Fe2(MoO4)3 · nH2O Orth. m m m _(_2/_m_2/_m_2/m ) : P m m n
7.GB.35 Anthoinite AlWO3(OH)3 Tric. 1
7.GB.35 Mpororoite WAlO3(OH)3 · 2(H2O) Tric.
7.GB.40 Obradovicite-KCu [K2(H2O)17Cu(H2O)6][Mo8As2Fe3+3O34(OH)3] Orth. m m m _(_2/_m_2/_m_2/m ) : P m n a
7.GB.45 Mendozavilite-NaFe [Na2(H2O)15Fe3+(H2O)6][Mo8P2Fe3+3O35(OH)2] Mon. 2/m : _B_2/m
7.GB.45 Paramendozavilite [KAl4(H2O)30][Mo12P6Fe3+6O60(OH)13] Mon.
7.GB.45 Obradovicite-NaCu Na2(H2O)17Cu(H2O)6][Mo8As2Fe3+3O34(OH)3] Orth. m m m _(_2/_m_2/_m_2/m ) : P m n a
7.GB.45 Obradovicite-NaNa [Na2(H2O)16Na(H2O)6][Mo8As2Fe3+3O33(OH)4] Orth.
7.GB.50 Tancaite-(Ce) FeCe(MoO4)3 · 3H2O Trig. 3 : _R_3
7.GB.50 Mendozavilite-NaCu [Na2(H2O)15Cu(H2O)6][Mo8P2Fe3+3O34(OH)3] Mon. 2/m : _B_2/m
7.GB.50 Mendozavilite-KCa [K2(H2O)15Ca(H2O)6][Mo8P2Fe3+3O34(OH)3] Mon. 2/m : _B_2/m
7.GB.60 Peterandresenite Mn4Nb6O19 · 14H2O Mon. 2/m : _B_2/m
7.GB.60 Melcherite Ba2Na2Mg[Nb6O19] · 6H2O Trig. 3 : _R_3
7.GB.60 Hansesmarkite Ca2Mn2Nb6O19 · 20H2O Tric. 1 : _P_1
7.GB.65 Ichnusaite Th(MoO4)2 · 3H2O Mon. 2/m : _P_21/b
7.GB.70 Markascherite Cu3(MoO4)(OH)4 Mon. 2/m : _P_21/m
7.GB.75 Nuragheite Th(MoO4)2 · H2O Mon. 2/m : _P_21/b

Fluorescence of OphiriteHide

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Does not fluoresce in short- or long-wave ultraviolet radiation

Other InformationHide

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Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

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References for OphiriteHide

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Reference List:

Kampf, A. R., Hughes, J. M., Nash, B. P., Wright, S. E., Rossman, G. R., Marty, J. (2014) Ophirite, Ca2Mg4[Zn2Mn3+2(H2O)2(Fe3+W9O34)2]·46H2O, a new mineral with a heteropolytungstate tri-lacunary Keggin anion. American Mineralogist, 99 (5) 1045-1051 doi:10.2138/am.2014.4699

Localities for OphiriteHide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

USA (TL)
Utah Tooele County Ophir Mining District Ophir Ophir Hill Consolidated Mine (TL) Williams et al. (2013)