Erionite-Ca (original) (raw)

A valid IMA mineral species

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About Erionite-CaHide

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Formula:

(Ca,K2,Na2)2[Al4Si14O36] · 15H2O

Name:

Named in 1898 by Arthur Starr Eakle from the Greek εριον meaning wool in allusion to the "wooly" appearance of the type material. Erionite was first found at the Durkee Fire Opal Mine, Swayze Creek, Durkee, Baker Co., Oregon (Tschernich, 1992). In modern nomenclature, the original erionite was erionite-Na, but potassium was nearly equal to sodium. Levinson Rule suffix added in allusion to Ca dominant exchangeable cations.

A zeolite difficult to distinguish from offretite.

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:6915:7

f86210a4-cfe8-4f64-b504-8bdf29900181

IMA Classification of Erionite-CaHide

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IMA Formula:

Ca5[Si26Al10O72] · 30H2O

Classification of Erionite-CaHide

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9.GD.20

9 : SILICATES (Germanates)
G : Tektosilicates with zeolitic H2O; zeolite family
D : Chains of 6-membered rings – tabular zeolites

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.

Symbol Source Reference
Eri-Ca IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43
Eri Whitney & Evans (2010) Whitney, D.L. and Evans, B.W. (2010) Abbreviations for names of rock-forming minerals. American Mineralogist, 95, 185–187 doi:10.2138/am.2010.3371
Eri Warr (2020) Warr, L.N. (2020) Recommended abbreviations for the names of clay minerals and associated phases. Clay Minerals, 55, 261–264 doi:10.1180/clm.2020.30

Physical Properties of Erionite-CaHide

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Density:

2.08 g/cm3 (Measured) 2.13 g/cm3 (Calculated)

Optical Data of Erionite-CaHide

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RI values:

_n_ω = 1.471 _n_ε = 1.474

δ = 0.003

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.

Optical Extinction:

Parallel extinction, positive elongation.

Chemistry of Erionite-CaHide

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Mindat Formula:

(Ca,K2,Na2)2[Al4Si14O36] · 15H2O

Crystallography of Erionite-CaHide

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Class (H-M):

6/m m m _(_6/_m_2/_m_2/m ) - Dihexagonal Dipyramidal

Cell Parameters:

a = 13.333(1) Å, c = 15.091(2) Å

Unit Cell V:

2,323.30 ų (Calculated from Unit Cell)

Comment:

Cell parameters from Harada et al 1967 (type material).

Crystal StructureHide

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ID Species Reference Link Year Locality Pressure (GPa) Temp (K)
0002001 Erionite-Ca Gualtieri A, Artioli G, Passaglia E, Bigi S, Viani A, Hanson J C (1998) Crystal structure-crystal chemistry relationships in the zeolites erionite and offretite Sample from Lady Hill American Mineralogist 83 590-606 1998 0 293
0002002 Erionite-Ca Gualtieri A, Artioli G, Passaglia E, Bigi S, Viani A, Hanson J C (1998) Crystal structure-crystal chemistry relationships in the zeolites erionite and offretite Sample from Shourdo American Mineralogist 83 590-606 1998 0 293
0002003 Erionite-Ca Gualtieri A, Artioli G, Passaglia E, Bigi S, Viani A, Hanson J C (1998) Crystal structure-crystal chemistry relationships in the zeolites erionite and offretite Sample from Tunguska American Mineralogist 83 590-606 1998 0 293
0002004 Erionite-Ca Gualtieri A, Artioli G, Passaglia E, Bigi S, Viani A, Hanson J C (1998) Crystal structure-crystal chemistry relationships in the zeolites erionite and offretite Sample from Agate Beach American Mineralogist 83 590-606 1998 0 293

CIF Raw Data - click here to close

Geological EnvironmentHide

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Type Occurrence of Erionite-CaHide

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General Appearance of Type Material:

Woolly white radial aggregates of fibers. The fibers reach 2 x 0.05 mm in size.

Place of Conservation of Type Material:

No designated type material.

Geological Setting of Type Material:

In thoroughly weathered and altered olivine basalt and andesite.

Associated Minerals at Type Locality:

Other Language Names for Erionite-CaHide

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Relationship of Erionite-Ca to other SpeciesHide

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Other Members of this group:

Erionite-K (K2,Ca,Na2)2[Al4Si14O36] · 15H2O Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_63/m m c
Erionite-Na (Na2,K2,Ca)2[Al4Si14O36] · 15H2O Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_63/m m c

Common AssociatesHide

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Associated Minerals Based on Photo Data:

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9.GD.05 Gmelinite-Ca Ca2(Si8Al4)O24 · 11H2O Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_63/m m c
9.GD.05 Gmelinite-K K4(Si8Al4O24) · 11H2O Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_63/m m c
9.GD.05 Gmelinite-Na Na4(Si8Al4)O24 · 11H2O Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_63/m m c
9.GD.10 Willhendersonite KCa[Al3Si3O12] · 5H2O Tric. 1 : _P_1
9.GD.10 Chabazite-Ca (Ca,K2,Na2)2[Al2Si4O12]2 · 12H2O Tric. 1 : _P_1
9.GD.10 Chabazite-K (K2,Ca,Na2,Sr,Mg)2[Al2Si4O12]2 · 12H2O Trig. 3_m_ _(_32/m ) : R_3_m
9.GD.10 Chabazite-Na (Na2,K2,Ca,Sr,Mg)2[Al2Si4O12]2 · 12H2O Trig. 3_m_ : R_3_m
9.GD.10 Chabazite-Sr Sr2[Al2Si4O12]2 · 12H2O Trig. 3_m_ _(_32/m ) : R_3_m
9.GD.10 Chabazite-Mg (Mg0.7K0.5Ca0.5Na0.1)[Al3Si9O24] · 10H2O Trig. 3_m_ _(_32/m ) : R_3_m
9.GD.15 Lévyne-Ca (Ca,Na2,K2)[Al2Si4O12] · 6H2O Trig. 3_m_ _(_32/m ) : R_3_m
9.GD.15 Lévyne-Na (Na2,Ca,K2)[Al2Si4O12] · 6H2O Trig. 3_m_ _(_32/m ) : R_3_m
9.GD.20 Bellbergite (K,Ba,Sr)2Sr2Ca2(Ca,Na)4[Al3Si3O12]6 · 30H2O Hex.
9.GD.20 Erionite-K (K2,Ca,Na2)2[Al4Si14O36] · 15H2O Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_63/m m c
9.GD.20 Erionite-Na (Na2,K2,Ca)2[Al4Si14O36] · 15H2O Hex. 6/m m m _(_6/_m_2/_m_2/m ) : _P_63/m m c
9.GD.25 Offretite KCaMg(Si13Al5)O36 · 15H2O Hex. 6_m_2 : _P_6_m_2
9.GD.25 Wenkite (Ba,K)4(Ca,Na)6[(Si,Al)20O39(OH)2](SO4)3 · 0.5H2O Hex. 6_m_2 : P_62_m
9.GD.30 Faujasite-Ca (Ca,Na2,Mg)3.5[Al7Si17O48] · 32H2O Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
9.GD.30 Faujasite-Mg (Mg,Na2,Ca)3.5[Al7Si17O48] · 32H2O Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
9.GD.30 Faujasite-Na (Na2,Ca,Mg)3.5[Al7Si17O48] · 32H2O Iso. m_3_m _(_4/_m_32/m ) : F d_3_m
9.GD.35 Maricopaite Pb7Ca2(Si,Al)48O100 · 32H2O Orth.
9.GD.35 Mordenite (Na2,Ca,K2)4(Al8Si40)O96 · 28H2O Orth.
9.GD.40 Dachiardite-K K4(Si20Al4O48) · 13H2O Mon.
9.GD.40 Dachiardite-Ca (Ca,Na2,K2)5Al10Si38O96 · 25H2O Mon. 2/m : _B_2/m
9.GD.40 Dachiardite-Na (Na2,Ca,K2)5Al10Si38O96 · 25H2O Mon. 2/m : _B_2/m
9.GD.45 Epistilbite CaAl2Si6O16 · 5H2O Mon.
9.GD.50 Ferrierite-K (K,Na)5(Si31Al5)O72 · 18H2O Orth. m m m _(_2/_m_2/_m_2/m ) : I m m m
9.GD.50 Ferrierite-Mg [Mg2(K,Na)2Ca0.5](Si29Al7)O72 · 18H2O Orth. m m m _(_2/_m_2/_m_2/m ) : P n n m
9.GD.50 Ferrierite-Na (Na,K)5(Si31Al5)O72 · 18H2O Mon. 2/m
9.GD.50 Ferrierite-NH4 (NH4,Mg0.5)5(Al5Si31O72) · 22H2O Orth. m m m _(_2/_m_2/_m_2/m ) : I m m m
9.GD.55 Bikitaite LiAlSi2O6 · H2O Tric. 1 : _P_1

Other InformationHide

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Health Risks:

Carcinogenic upon inhalation of its dust, due to its fibrous structure (Ref.: IARC Monography 42:225-239, 1987)

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References for Erionite-CaHide

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Reference List:

Harada, K., Iwamoto, S., Kihara, K. (1967) Erionite, phillipsite and gonnardite in the amygdales of altered basalt from Mazé, Niigata Prefecture, Japan. American Mineralogist, 52, 1785-1794.

Gualtieri, A., Artioli, G., Passaglia, E., Bigi, S., Viani, A., Hanson, J. C. (1998) Crystal structure-crystal chemistry relationships in the zeolites erionite and offretite. American Mineralogist, 83 (5) 590-606 doi:10.2138/am-1998-5-619

Localities for Erionite-CaHide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

Australia
New South Wales Brisbane Co. Merriwa Merriwa zeolite locality Dogan et al. (2008)
Tasmania Central Coast municipality South Nietta Jean Brook (Smith’s Plains) M Latham Collection +1 other reference
Victoria Bass Coast Shire Phillip Island Birch (1989)
Baw Baw Shire Jindivick Dogan et al. (2008)
Canada
British Columbia Dogan et al. (2008)
Czech Republic
Liberec Region Česká Lípa District Provodín Michlův hill quarry Erionite-Ca from the Michlův hill near ...
Žandov Heřmanice Pauliš et al. (2018)
Unnamed hill Pauliš et al. (2018)
Ústí nad Labem Region Děčín District Česká Kamenice Hackenberg P.Pauliš et al. (2014)
Ústí nad Labem District Chuderov Žežice Rychlý
France
Auvergne-Rhône-Alpes Haute-Loire Yssingeaux Araules Le Collet Gualtieri et al. (1998)
Germany
Hesse Giessen Region Lahn-Dill-Kreis Greifenstein Allendorf Alter Stein Quarry SEM-EDS by Joy Desor
Rhineland-Palatinate Mayen-Koblenz Vordereifel Ettringen Caspar quarry Blass et al. (2001)
Italy
Sardinia Oristano Province Montresta Passaglia et al. (1998)
Veneto Padova Province Cinto Euganeo Faedo Monte Fasolo Case Berton Quarry Passaglia et al. (1995) +2 other references
Vicenza Province Montecchio Maggiore San Pietro Monte Nero Passaglia et al. (1998)
Japan (TL)
Niigata Prefecture Niigata City Maze (Mazé) (TL) Am. Mineral. 52 +1 other reference
Tokyo Metropolis Ogasawara Subprefecture Ogasawara Islands Chichijima Group Chichi Island (Chichijima) Ryoji Tanaka specimens
New Zealand
Northland Region Kaipara District Hukatere Peninsula Hukatere Volcano T. Saunderson collection
Otago Region Moeraki Point RRUFF database- Specimen I.D R060836
Russia
Krasnoyarsk Krai Evenkiysky District Nizhnyaya Tunguska River Basin Dogan et al. (2008)
Slovakia
Prešov Region Vranov nad Topľou District Vechec Vechec quarry Martin Števko-unpublished
Turkey
Nevşehir Province Gülşehir District Tuzköy (Tuzkoy) USGS Open File report 10-1286
UK
Northern Ireland Co. Antrim Antrim Lady Hill Quarry Dogan et al. (2008)
Parkgate Quarry Maggie Wilson
Ballyclare Dogan et al. (2008)
Carnmoney Glengormley Paolo Grosso
Templepatrick Hightown Quarry J. Skupiewski
Scotland Highland Eilean á Chèo Isle of Skye Dogan et al. (2008)
USA
Arizona Pima County Ajo Mining District O. Dzillas
New Mexico Rio Arriba County Chili Patrick Haynes
North Dakota Dunn County Killdeer Mountains USGS Open File report 10-1286
Slope County JAMES MacPHERSON (Associated Press Writer)
Stark County JAMES MacPHERSON (Associated Press Writer)
Oregon Clackamas County Milwaukie SE Lava Drive Wise et al. (1976)
Grant County Mount Vernon Beech Creek Quarry Dogan et al. (2008)
Tillamook County Netarts Cape Lookout Quarry Micro Probe Volume IX Number 3