Akrochordite (original) (raw)

A valid IMA mineral species - grandfathered

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About AkrochorditeHide

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Formula:

MnMn2Mn2(AsO4)2(OH)4(H2O)4

Simplified: (Mn2+)5(AsO4)2(OH)4 · 4H2O.
Type material contains some Mg replacing Mn.

Colour:

Yellowish red-brown, pale to dark brown, pale pink,

Lustre:

Sub-Vitreous, Resinous, Dull

Specific Gravity:

3.194 - 3.35

Crystal System:

Monoclinic

Name:

Named by Gustav Flink in 1922 from Greek ακρόχορδον (akrochordon) = "a wart," in allusion to the appearance of its form of aggregation.

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:72:3

5f250b01-9289-4e5b-9d33-762bd3487422

IMA Classification of AkrochorditeHide

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Approved, 'Grandfathered' (first described prior to 1959)

Type description reference:

Classification of AkrochorditeHide

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8.DD.10

8 : PHOSPHATES, ARSENATES, VANADATES
D : Phosphates, etc. with additional anions, with H2O
D : With only medium-sized cations, (OH, etc.):RO4= 2:1

42.4.1.1

42 : HYDRATED PHOSPHATES, ETC.CONTAINING HYDROXYL OR HALOGEN
4 : (AB)5(XO4)2Zq·xH2O

20.8.11

20 : Arsenates (also arsenates with phosphate, but without other anions)
8 : Arsenates of Mn

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol Source Reference
Akr IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of AkrochorditeHide

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Sub-Vitreous, Resinous, Dull

Colour:

Yellowish red-brown, pale to dark brown, pale pink,

Cleavage:

Perfect
On {010} , perfect; a second, perpendicular to the first.

Density:

3.194 - 3.35 g/cm3 (Measured) 3.26 g/cm3 (Calculated)

Optical Data of AkrochorditeHide

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RI values:

_n_α = 1.672 _n_β = 1.676 _n_γ = 1.683

δ = 0.011

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.

Dispersion:

r < v relatively strong

Optical Extinction:

Y^c ~ 45°, X = b

Pleochroism:

Non-pleochroic

Chemistry of AkrochorditeHide

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Mindat Formula:

MnMn2Mn2(AsO4)2(OH)4(H2O)4

Simplified: (Mn2+)5(AsO4)2(OH)4 · 4H2O.
Type material contains some Mg replacing Mn.

Crystallography of AkrochorditeHide

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Crystal System:

Monoclinic

Class (H-M):

2/m - Prismatic

Cell Parameters:

a = 5.682 Å, b = 17.627 Å, c = 6.832 Å
β = 99.5°

Ratio:

a:b:c = 0.322 : 1 : 0.388

Unit Cell V:

674.89 ų (Calculated from Unit Cell)

Morphology:

Crystals are prismatic to lathlike, elongated along [201], generally splayed or tapered, to 2 mm; may be in radial aggregates and subparallel sheaves. Typically as wartlike or spherical aggregates of minute crystals.

Crystal StructureHide

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ID Species Reference Link Year Locality Pressure (GPa) Temp (K)
0001206 Akrochordite Moore P B, Sen Gupta P K, Schlemper E O (1989) Akrochordite, (Mn,Mg)5(OH)4(H2O)4(AsO4)2: A sheet structure with amphibole walls American Mineralogist 74 256-262 1989 0 293

CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

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Powder Diffraction Data:

d-spacing Intensity
8.79 Å (80)
5.31 Å (35)
4.40 Å (100)
3.62 Å (40)
3.112 Å (35)
3.062 Å (35)
2.750 Å (50)

Geological EnvironmentHide

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Geological Setting:

in fractures in a metamorphosed zinc orebody (Sterling Hill, New Jersey, USA).

Type Occurrence of AkrochorditeHide

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General Appearance of Type Material:

Small, rounded wartlike aggregates

Place of Conservation of Type Material:

National Museum of Natural History, Washington, D.C., USA, 162614, R5396.

Chemical Analysis of Type Material:

P2O5 0.42 %
As2O5 33.51 %
MnO 38.98 %
Mn2O3 0.50 %
FeO 0.46 %
MgO 6.94 %
K2O 0.55 %
Na2O 1.18 %
CaO 0.99 %
H2O 16.78 %
Total: 100.31 %

Geological Setting of Type Material:

A rare mineral in hausmannite ore from a metamorphosed Fe–Mn orebody

Associated Minerals at Type Locality:

Reference:

Flink, G. (1922) Akrochordit, ett nytt mineral från Långbans gruvor. Geologiska Föreningens i Stockholm Förhandlinger: 44: 773-776.

Synonyms of AkrochorditeHide

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Other Language Names for AkrochorditeHide

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Relationship of Akrochordite to other SpeciesHide

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Other Members of this group:

Guanacoite MgCu2Mg2(AsO4)2(OH)4(H2O)4 Mon. 2/m : _P_21/b

Common AssociatesHide

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Associated Minerals Based on Photo Data:

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8.DD. Penberthycroftite [Al6(AsO4)3(OH)9(H2O)5] · 8H2O Mon. 2/m : _P_21/b
8.DD. Bettertonite [Al6(AsO4)3(OH)9(H2O)5] · 11H2O Mon. 2/m : _P_21/b
8.DD. Vargite MnCu2Mn2(AsO4)2(OH)4(H2O)4 Mon. 2/m : _P_21/b
8.DD. Galeaclolusite Al6(AsO4)3(OH)9(H2O)4 · 8H2O Orth. m m m _(_2/_m_2/_m_2/m ) : P n m a
8.DD.05 Luetheite Cu2Al2(AsO4)2(OH)4 Mon. 2/m : _P_21/m
8.DD.05 Chenevixite Cu2Fe3+2(AsO4)2(OH)4 Mon. 2/m : _P_21/m
8.DD.10 Guanacoite MgCu2Mg2(AsO4)2(OH)4(H2O)4 Mon. 2/m : _P_21/b
8.DD.15 UM1981-32-PO:FeH Fe2+Fe3+6(PO4)4-x[PO3(OH)]x(OH)8 · 4H2O
8.DD.15 Afmite Al3(OH)4(H2O)3(PO4)(PO3OH) · H2O Tric. 1 : _P_1
8.DD.15 Aheylite (Fe2+,Zn)Al6(PO4)4(OH)8 · 4H2O Tric. 1 : _P_1
8.DD.15 Coeruleolactite Tric. 1 : _P_1
8.DD.15 Faustite ZnAl6(PO4)4(OH)8 · 4H2O Tric. 1 : _P_1
8.DD.15 Planerite Al6(PO4)2(PO3OH)2(OH)8 · 4H2O Tric. 1 : _P_1
8.DD.15 Chalcosiderite CuFe3+6(PO4)4(OH)8 · 4H2O Tric. 1 : _P_1
8.DD.15 Turquoise CuAl6(PO4)4(OH)8 · 4H2O Tric. 1 : _P_1
8.DD.20 Eosphorite Mn2+Al(PO4)(OH)2 · H2O Orth. m m m _(_2/_m_2/_m_2/m ) : C m c a
8.DD.20 Ernstite (Mn2+,Fe3+)Al(PO4)(OH,O)2 · H2O Mon.
8.DD.20 Lefontite Fe2Al2Be(PO4)2(OH)6 Orth. m m m _(_2/_m_2/_m_2/m ) : C m c a
8.DD.20 Childrenite Fe2+Al(PO4)(OH)2 · H2O Orth. m _m_2 : C c _c_2
8.DD.25 Kobokoboite Al6(PO4)4(OH)6 · 11H2O Tric.
8.DD.30 Smamite Ca2Sb(OH)4[H(AsO4)2] · 6H2O Tric. 1 : _P_1
8.DD.35 Gutsevichite Al3(PO4)2(OH)3 · 8H2O Iso.
8.DD.40 Laubmannite (of Moore) (Fe3+,Fe2+,M)8+x(OH,H2O)9(H2O)2(PO4)5, M = Fe3+, Cu2+ or other metal cation, x ~ 0.1. Orth. m m m _(_2/_m_2/_m_2/m ) : P b c m

Fluorescence of AkrochorditeHide

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Other InformationHide

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Notes:

Readily soluble in dilute H2SO4, yielding a purple (lilac) solution.

Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

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References for AkrochorditeHide

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Reference List:

Palache, Charles, Berman, Harry, Frondel, Clifford (1951) The System of Mineralogy (7th ed.) Vol. 2 - Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, Ect. John Wiley and Sons, New York.

Gaines, Richard V., Skinner, H. Catherine W., Foord, Eugene E., Mason, Brian, Rosenzweig, Abraham, King, Vandall T. (1997) Dana's New Mineralogy (8th ed.). Wiley-Interscience. p.1872

Localities for AkrochorditeHide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

Germany
Lower Saxony Göttingen District Bad Grund Bergstadt Bad Grund Grund mine Haack et al. (1987)
Sweden (TL)
Värmland County Filipstad Långban Ore District Långban Mine (TL) Flink (1922) +3 other references
Japan working Flink (1922)
Nordmark Odal Field Moss mine Langhof (2003)
USA
New Jersey Sussex County Ogdensburg Sterling Hill Sterling Mine Dunn (1981) +1 other reference