ikenna Anugwom | Åbo Akademi (original) (raw)
Papers by ikenna Anugwom
Daddy hope I made you proud? iv PREFACE The present work was carried out at
ChemSusChem, Jan 23, 2015
The integration of highly efficient enzymatic catalysis with the solvation properties of ionic li... more The integration of highly efficient enzymatic catalysis with the solvation properties of ionic liquids for an environmentally friendly and efficient use of raw materials such as wood requires fundamental knowledge about the influence of relevant ionic liquids on enzymes. Switchable ionic liquids (SIL) are promising candidates for implementation of enzymatic treatments of raw materials. One industrially interesting SIL is constituted by monoethanol amine (MEA) and 1,8-diazabicyclo-[5.4.0]-undec-7-ene (DBU) formed with sulfur dioxide (SO2 ) as the coupling media (DBU-SO2 -MEASIL). It has the ability to solubilize the matrix of lignocellulosic biomass while leaving the cellulose backbone intact. Using a novel (31) P NMR-based real-time assay we show that this SIL is compatible with enzymatic catalysis because a model enzyme, adenylate kinase, retains its activity in up to at least 25 wt % of DBU-SO2 -MEASIL. Thus this SIL appears suitable for, for example, enzymatic degradation of hemi...
Biotechnology for Biofuels, 2015
Pretreatment is a vital step upon biochemical conversion of lignocellulose materials into biofuel... more Pretreatment is a vital step upon biochemical conversion of lignocellulose materials into biofuels. An acid catalyzed thermochemical treatment is the most commonly employed method for this purpose. Alternatively, ionic liquids (ILs), a class of neoteric solvents, provide unique opportunities as solvents for the pretreatment of a wide range of lignocellulose materials. In the present study, four ionic liquid solvents (ILs), two switchable ILs (SILs) DBU-MEA-SO2 and DBU-MEA-CO2, as well as two 'classical' ILs [Amim][HCO2] and [AMMorp][OAc], were applied in the pretreatment of five different lignocellulosic materials: Spruce (Picea abies) wood, Pine (Pinus sylvestris) stem wood, Birch (Betula pendula) wood, Reed canary grass (RCG, Phalaris arundinacea), and Pine bark. Pure cellulosic substrate, Avicel, was also included in the study. The investigations were carried out in comparison to acid pretreatments. The efficiency of different pretreatments was then evaluated in terms of sugar release and ethanol fermentation. Excellent glucan-to-glucose conversion levels (between 75 and 97 %, depending on the biomass and pretreatment process applied) were obtained after the enzymatic hydrolysis of IL-treated substrates. This corresponded between 13 and 77 % for the combined acid treatment and enzymatic hydrolysis. With the exception of 77 % for pine bark, the glucan conversions for the non-treated lignocelluloses were much lower. Upon enzymatic hydrolysis of IL-treated lignocelluloses, a maximum of 92 % hemicelluloses were also released. As expected, the ethanol production upon fermentation of hydrolysates reflected their sugar concentrations, respectively. Utilization of various ILs as pretreatment solvents for different lignocelluloses was explored. SIL DBU-MEA-SO2 was found to be superior solvent for the pretreatment of lignocelluloses, especially in case of softwood substrates (i.e., spruce and pine). In case of birch and RCG, the hydrolysis efficiency of the SIL DBU-MEA-CO2 was similar or even better than that of DBU-MEA-SO2. Further, the IL [AMMorp][OAc] was found as comparably efficient as DBU-MEA-CO2. Pine bark was highly amorphous and none of the pretreatments applied resulted in clear benefits to improve the product yields.
RSC Advances, 2011
... Ikenna Anugwom*a, Päivi Mäki-Arvelaa, Pasi Virtanena, Pia Damlind, Rainer Sjöholmc and Jyri-P... more ... Ikenna Anugwom*a, Päivi Mäki-Arvelaa, Pasi Virtanena, Pia Damlind, Rainer Sjöholmc and Jyri-Pekka Mikkola*ab. a Laboratory of Industrial ... 1, L. Phan, D. Chiu, DJ Heldebrant, H. Huttenhower, E. John, L. Xiaowang, P. Pollet, R. Wang, CA Eckert, CL Liotta and PG Jessop, ...
Journal of Environmental Protection, 2011
Removal of air pollutants, such as nitrogen and sulphur containing compounds from a model oil (do... more Removal of air pollutants, such as nitrogen and sulphur containing compounds from a model oil (dodecane) was studied. An ionic liquid (1-ethyl-3-methylimidazolium chloride [C 2 mim] [Cl]) was used as an extractant. Liquid-liquid extraction by using 1-ethyl-3-methylimidazolium chloride [C 2 mim] [Cl] was found to be a very promising method for the removal of N-and S-compounds. This was evaluated by using a model oil (dodecane) with indole as a neutral nitrogen compound and pyridine as a basic nitrogen compound. Dibenzothiophene (DBT) was used as a sulphur compound. An extraction capacity of up to 90 wt% was achieved for the model oil containing pyridine, while only 76 wt% of indole in the oil was extracted. The extraction capacity of a model sulphur compound DBT was found to be up to 99 wt%. Regeneration of the spent ionic liquid was carried out with toluene back-extraction. A 1:1 toluene-to-IL wt ratio was performed at room temperature. It was observed that, for the spent ionic liquid containing DBT as a model compound more than 85 wt% (corresponding 3852 mg/kg) could be removed from the oil. After the second regeneration cycle, 86 wt% of the DBT was recovered from the ionic liquid to toluene. In the case of indole as the nitrogen containing species, more than 99 wt%, (corresponding to 2993 mg/kg) of the original indole was transferred from the model oil to the ionic liquid. After the first-regeneration cycle of the spent ionic liquid, 54 wt% of the indole-in-IL was transferred to toluene. Thus, both extractions of nitrogen and sulphur model compounds were successfully carried out from model oil and the back-extraction of these compounds from the ionic liquids to toluene demonstrated the proved the concept of the regeneration point of view.
Industrial Crops and Products, 2014
ABSTRACT The fractionation of lignocellulosic biomass to its major components is the primary step... more ABSTRACT The fractionation of lignocellulosic biomass to its major components is the primary step towards the conversion of biomass-based biopolymers to commodity chemicals in the integrated biorefinery process. Wood chips encased in a SpinChem® device and attached to the stirrer of a batch autoclave were used together with switchable ionic liquids (SILs) for the selective fractionation of hemicelluloses and lignin. Stirring of the wood chips in the SpinChem® device facilitated the diffusion of SIL into the chips through forced recirculation and at the same time avoiding mechanical fibrillation. The treatment of birch chips (Betula pendula) with SILs comprising 1,8-diazabicyclo-[5.4.0]-undec-7-ene (DBU), monoethanolamine (MEA) and CO2 at 120 °C in a SpinChem® device resulted in the fractionation of 82 wt.% hemicelluloses and 90 wt.% lignin, leaving the cellulose-rich non-dissolved material partially fibrillated and softened. The dissolved hemicelluloses and lignin were selectively precipitated using isopropanol and recovered from the spent SIL.
Industrial Crops and Products, 2010
The state of art from the dissolution of cellulose, lignin and wood using ionic liquids is presen... more The state of art from the dissolution of cellulose, lignin and wood using ionic liquids is presented in this work. The emphasis is put on the relationship between the properties of ionic liquids and the dissolution capacity. The impact of the following solvation parameters, namely Hildebrand solubility parameter and hydrogen bond basicity are related to the dissolution of lignocellulosic material. Good solvents for cellulose are 1-butyl-and 1-allyl-3-methylimidazolium chlorides as well as 1-ethyl-3-methylimidazolium acetate, whereas for lignocellulosic material the best solvents are 1-ethyl-3-methylimidazolium acetate and 1-allyl-3-methylimidazolium chloride. In allyl group the ethylene functionality facilitates Binteractions with the aromatic lignin structure. Furthermore, small polarizable anions are also powerful when aiming at dissolution of cellulose. The properties of regenerated cellulose and reconstituted lignin are also given and compared with those of the native materials. Furthermore, the results from the regeneration and reuse of ionic liquids are presented here.
Holzforschung, 2000
ABSTRACT The suitability of a new switchable ionic liquid (SIL) has been investigated as a solven... more ABSTRACT The suitability of a new switchable ionic liquid (SIL) has been investigated as a solvent for fractionation of lignocellulosic materials. SIL was prepared from inexpensive chemicals, e.g., glycerol, CO2, and 1,8-diazabicyclo-[5.4.0]-undec-7-ene (DBU). Fresh Nordic birch wood (B. pendula) was treated with the SIL for a time period of 1–5 days at 100°C and under atmospheric pressure. Upon SIL treatment, at best, 57% of the hemicelluloses were dissolved and 50% of lignins were dissolved from the native birch. The slightly fibrillated SIL treated chips contained about 55% cellulose. Up to 76% of the recovered species removed from the spent SIL liquor was originating from hemicelluloses, mainly from xylan. The spent SILs were reused for fresh wood dissolution in four consecutive cycles and each time the wood dissolution efficiency was similar. SILs could offer affordable (easy-to-synthesize) solvent systems for partial elimination of hemicelluloses and lignin from wood. SILs can also be prepared in-situ and on-site.
ChemSusChem, 2014
The transformation of lignocellulosic materials into potentially valuable resources is compromise... more The transformation of lignocellulosic materials into potentially valuable resources is compromised by their complicated structure. Consequently, new economical and feasible conversion/fractionation techniques that render value-added products are intensely investigated. Herein an unorthodox and feasible fractionation method of birch chips (B. pendula) using a switchable ionic liquid (SIL) derived from an alkanol amine (monoethanol amine, MEA) and an organic super base (1,8-diazabicyclo-[5.4.0]-undec-7-ene, DBU) with two different trigger acid gases (CO2 and SO2 ) is studied. After SIL treatment, the dissolved fractions were selectively separated by a step-wise method using an antisolvent to induce precipitation. The SIL was recycled after concentration and evaporation of anti-solvent. The composition of undissolved wood after MEA-SO2 -SIL treatment resulted in 80 wt % cellulose, 10 wt % hemicelluloses, and 3 wt % lignin, whereas MEA-CO2 -SIL treatment resulted in 66 wt % cellulose, 12 wt % hemicelluloses and 11 wt % lignin. Thus, the MEA-SO2 -SIL proved more efficient than the MEA-CO2 -SIL, and a better solvent for lignin removal. All fractions were analyzed by gas chromatography (GC), Fourier transform infrared spectroscopy (FT-IR), (13) C nuclear magnetic resonance spectroscopy (NMR) and Gel permeation chromatography (GPC).
Chemical Engineering Journal, 2014
ABSTRACT
Carbohydrate Polymers, 2012
Switchable ionic liquids (SILs) made from alcohols, either hexanol or butanol, and CO 2 together ... more Switchable ionic liquids (SILs) made from alcohols, either hexanol or butanol, and CO 2 together with an amidine (1,8-diazabicyclo-[5.4.0]-undec-7-ene (DBU)) were investigated as dissolution/fractionation solvents for wood material. Both native spruce (Picea abies), and pre-extracted spruce were treated with either butanol SIL (SIL1) or hexanol SIL (SIL2) for 5 days at 55 • C under normal pressure. The SILs were formed by bubbling CO 2 through an equimolar mixture of either 1-hexanol or 1-butanol and DBU. The viscosity of the mixture increased from 7.1 mPa s to 2980 mPa s for SIL2 and 5.1 to 1600 mPa s for SIL1. Melting points of the SILs 1 and 2 were at 8 and 14 • C, respectively. After the treatment time (5 days), the undissolved fraction contained 38 wt.% less hemicelluloses compared to native spruce. There was an increase in the glucose content of the milled spruce treated with both SILs, since the milling step reduced the cellulose crystallinity of the wood and facilitated an easier SIL access into the wood. The solvents were very neutral in terms of lignin removal. Consequently, only about 2% of the lignin was removed from native wood. Moreover, a priori removal of the wood extractives did not influence the lignin removal.
CO2 - Ionic Liquids synergies: Reactive capture and conversion of CO2 to chemicals Valerie Etaa, ... more CO2 - Ionic Liquids synergies: Reactive capture and conversion of CO2 to chemicals Valerie Etaa, Pasi Virtanena, Ikenna Anugwoma, Pivi Mki-Arvelaa, Jyri-Pekka Mikkolaa,b aLaboratory of Industrial Chemistry and Reaction Engineering, Process Chemistry Centre, bo Akademi University, Biskopsgatan 8, 20500 Turku/bo, Finland. bTechnical Chemistry, Department of Chemistry, Chemical Biological Center, Ume University, SE-90187 Ume. Novel technologies based on the utilization of abundant and non-toxic carbon dioxide (CO2) for the synthesis of materials and chemicals may significantly contribute towards the development of sustainable industrial practices. Naturally, myriad substances are synthesized from CO2 and consumed by humans. The conversion of CO2 to fuels and chemicals is an attractive method of utilizing CO2 from the viewpoint of green chemistry and sustainable development. The use of CO2 in the synthesis of chemicals such as dimethyl carbonate (DMC) or switchable ionic liquids (SILs) ...
Green Processing and Synthesis, 2014
Biomass and Bioenergy, 2014
Daddy hope I made you proud? iv PREFACE The present work was carried out at
ChemSusChem, Jan 23, 2015
The integration of highly efficient enzymatic catalysis with the solvation properties of ionic li... more The integration of highly efficient enzymatic catalysis with the solvation properties of ionic liquids for an environmentally friendly and efficient use of raw materials such as wood requires fundamental knowledge about the influence of relevant ionic liquids on enzymes. Switchable ionic liquids (SIL) are promising candidates for implementation of enzymatic treatments of raw materials. One industrially interesting SIL is constituted by monoethanol amine (MEA) and 1,8-diazabicyclo-[5.4.0]-undec-7-ene (DBU) formed with sulfur dioxide (SO2 ) as the coupling media (DBU-SO2 -MEASIL). It has the ability to solubilize the matrix of lignocellulosic biomass while leaving the cellulose backbone intact. Using a novel (31) P NMR-based real-time assay we show that this SIL is compatible with enzymatic catalysis because a model enzyme, adenylate kinase, retains its activity in up to at least 25 wt % of DBU-SO2 -MEASIL. Thus this SIL appears suitable for, for example, enzymatic degradation of hemi...
Biotechnology for Biofuels, 2015
Pretreatment is a vital step upon biochemical conversion of lignocellulose materials into biofuel... more Pretreatment is a vital step upon biochemical conversion of lignocellulose materials into biofuels. An acid catalyzed thermochemical treatment is the most commonly employed method for this purpose. Alternatively, ionic liquids (ILs), a class of neoteric solvents, provide unique opportunities as solvents for the pretreatment of a wide range of lignocellulose materials. In the present study, four ionic liquid solvents (ILs), two switchable ILs (SILs) DBU-MEA-SO2 and DBU-MEA-CO2, as well as two 'classical' ILs [Amim][HCO2] and [AMMorp][OAc], were applied in the pretreatment of five different lignocellulosic materials: Spruce (Picea abies) wood, Pine (Pinus sylvestris) stem wood, Birch (Betula pendula) wood, Reed canary grass (RCG, Phalaris arundinacea), and Pine bark. Pure cellulosic substrate, Avicel, was also included in the study. The investigations were carried out in comparison to acid pretreatments. The efficiency of different pretreatments was then evaluated in terms of sugar release and ethanol fermentation. Excellent glucan-to-glucose conversion levels (between 75 and 97 %, depending on the biomass and pretreatment process applied) were obtained after the enzymatic hydrolysis of IL-treated substrates. This corresponded between 13 and 77 % for the combined acid treatment and enzymatic hydrolysis. With the exception of 77 % for pine bark, the glucan conversions for the non-treated lignocelluloses were much lower. Upon enzymatic hydrolysis of IL-treated lignocelluloses, a maximum of 92 % hemicelluloses were also released. As expected, the ethanol production upon fermentation of hydrolysates reflected their sugar concentrations, respectively. Utilization of various ILs as pretreatment solvents for different lignocelluloses was explored. SIL DBU-MEA-SO2 was found to be superior solvent for the pretreatment of lignocelluloses, especially in case of softwood substrates (i.e., spruce and pine). In case of birch and RCG, the hydrolysis efficiency of the SIL DBU-MEA-CO2 was similar or even better than that of DBU-MEA-SO2. Further, the IL [AMMorp][OAc] was found as comparably efficient as DBU-MEA-CO2. Pine bark was highly amorphous and none of the pretreatments applied resulted in clear benefits to improve the product yields.
RSC Advances, 2011
... Ikenna Anugwom*a, Päivi Mäki-Arvelaa, Pasi Virtanena, Pia Damlind, Rainer Sjöholmc and Jyri-P... more ... Ikenna Anugwom*a, Päivi Mäki-Arvelaa, Pasi Virtanena, Pia Damlind, Rainer Sjöholmc and Jyri-Pekka Mikkola*ab. a Laboratory of Industrial ... 1, L. Phan, D. Chiu, DJ Heldebrant, H. Huttenhower, E. John, L. Xiaowang, P. Pollet, R. Wang, CA Eckert, CL Liotta and PG Jessop, ...
Journal of Environmental Protection, 2011
Removal of air pollutants, such as nitrogen and sulphur containing compounds from a model oil (do... more Removal of air pollutants, such as nitrogen and sulphur containing compounds from a model oil (dodecane) was studied. An ionic liquid (1-ethyl-3-methylimidazolium chloride [C 2 mim] [Cl]) was used as an extractant. Liquid-liquid extraction by using 1-ethyl-3-methylimidazolium chloride [C 2 mim] [Cl] was found to be a very promising method for the removal of N-and S-compounds. This was evaluated by using a model oil (dodecane) with indole as a neutral nitrogen compound and pyridine as a basic nitrogen compound. Dibenzothiophene (DBT) was used as a sulphur compound. An extraction capacity of up to 90 wt% was achieved for the model oil containing pyridine, while only 76 wt% of indole in the oil was extracted. The extraction capacity of a model sulphur compound DBT was found to be up to 99 wt%. Regeneration of the spent ionic liquid was carried out with toluene back-extraction. A 1:1 toluene-to-IL wt ratio was performed at room temperature. It was observed that, for the spent ionic liquid containing DBT as a model compound more than 85 wt% (corresponding 3852 mg/kg) could be removed from the oil. After the second regeneration cycle, 86 wt% of the DBT was recovered from the ionic liquid to toluene. In the case of indole as the nitrogen containing species, more than 99 wt%, (corresponding to 2993 mg/kg) of the original indole was transferred from the model oil to the ionic liquid. After the first-regeneration cycle of the spent ionic liquid, 54 wt% of the indole-in-IL was transferred to toluene. Thus, both extractions of nitrogen and sulphur model compounds were successfully carried out from model oil and the back-extraction of these compounds from the ionic liquids to toluene demonstrated the proved the concept of the regeneration point of view.
Industrial Crops and Products, 2014
ABSTRACT The fractionation of lignocellulosic biomass to its major components is the primary step... more ABSTRACT The fractionation of lignocellulosic biomass to its major components is the primary step towards the conversion of biomass-based biopolymers to commodity chemicals in the integrated biorefinery process. Wood chips encased in a SpinChem® device and attached to the stirrer of a batch autoclave were used together with switchable ionic liquids (SILs) for the selective fractionation of hemicelluloses and lignin. Stirring of the wood chips in the SpinChem® device facilitated the diffusion of SIL into the chips through forced recirculation and at the same time avoiding mechanical fibrillation. The treatment of birch chips (Betula pendula) with SILs comprising 1,8-diazabicyclo-[5.4.0]-undec-7-ene (DBU), monoethanolamine (MEA) and CO2 at 120 °C in a SpinChem® device resulted in the fractionation of 82 wt.% hemicelluloses and 90 wt.% lignin, leaving the cellulose-rich non-dissolved material partially fibrillated and softened. The dissolved hemicelluloses and lignin were selectively precipitated using isopropanol and recovered from the spent SIL.
Industrial Crops and Products, 2010
The state of art from the dissolution of cellulose, lignin and wood using ionic liquids is presen... more The state of art from the dissolution of cellulose, lignin and wood using ionic liquids is presented in this work. The emphasis is put on the relationship between the properties of ionic liquids and the dissolution capacity. The impact of the following solvation parameters, namely Hildebrand solubility parameter and hydrogen bond basicity are related to the dissolution of lignocellulosic material. Good solvents for cellulose are 1-butyl-and 1-allyl-3-methylimidazolium chlorides as well as 1-ethyl-3-methylimidazolium acetate, whereas for lignocellulosic material the best solvents are 1-ethyl-3-methylimidazolium acetate and 1-allyl-3-methylimidazolium chloride. In allyl group the ethylene functionality facilitates Binteractions with the aromatic lignin structure. Furthermore, small polarizable anions are also powerful when aiming at dissolution of cellulose. The properties of regenerated cellulose and reconstituted lignin are also given and compared with those of the native materials. Furthermore, the results from the regeneration and reuse of ionic liquids are presented here.
Holzforschung, 2000
ABSTRACT The suitability of a new switchable ionic liquid (SIL) has been investigated as a solven... more ABSTRACT The suitability of a new switchable ionic liquid (SIL) has been investigated as a solvent for fractionation of lignocellulosic materials. SIL was prepared from inexpensive chemicals, e.g., glycerol, CO2, and 1,8-diazabicyclo-[5.4.0]-undec-7-ene (DBU). Fresh Nordic birch wood (B. pendula) was treated with the SIL for a time period of 1–5 days at 100°C and under atmospheric pressure. Upon SIL treatment, at best, 57% of the hemicelluloses were dissolved and 50% of lignins were dissolved from the native birch. The slightly fibrillated SIL treated chips contained about 55% cellulose. Up to 76% of the recovered species removed from the spent SIL liquor was originating from hemicelluloses, mainly from xylan. The spent SILs were reused for fresh wood dissolution in four consecutive cycles and each time the wood dissolution efficiency was similar. SILs could offer affordable (easy-to-synthesize) solvent systems for partial elimination of hemicelluloses and lignin from wood. SILs can also be prepared in-situ and on-site.
ChemSusChem, 2014
The transformation of lignocellulosic materials into potentially valuable resources is compromise... more The transformation of lignocellulosic materials into potentially valuable resources is compromised by their complicated structure. Consequently, new economical and feasible conversion/fractionation techniques that render value-added products are intensely investigated. Herein an unorthodox and feasible fractionation method of birch chips (B. pendula) using a switchable ionic liquid (SIL) derived from an alkanol amine (monoethanol amine, MEA) and an organic super base (1,8-diazabicyclo-[5.4.0]-undec-7-ene, DBU) with two different trigger acid gases (CO2 and SO2 ) is studied. After SIL treatment, the dissolved fractions were selectively separated by a step-wise method using an antisolvent to induce precipitation. The SIL was recycled after concentration and evaporation of anti-solvent. The composition of undissolved wood after MEA-SO2 -SIL treatment resulted in 80 wt % cellulose, 10 wt % hemicelluloses, and 3 wt % lignin, whereas MEA-CO2 -SIL treatment resulted in 66 wt % cellulose, 12 wt % hemicelluloses and 11 wt % lignin. Thus, the MEA-SO2 -SIL proved more efficient than the MEA-CO2 -SIL, and a better solvent for lignin removal. All fractions were analyzed by gas chromatography (GC), Fourier transform infrared spectroscopy (FT-IR), (13) C nuclear magnetic resonance spectroscopy (NMR) and Gel permeation chromatography (GPC).
Chemical Engineering Journal, 2014
ABSTRACT
Carbohydrate Polymers, 2012
Switchable ionic liquids (SILs) made from alcohols, either hexanol or butanol, and CO 2 together ... more Switchable ionic liquids (SILs) made from alcohols, either hexanol or butanol, and CO 2 together with an amidine (1,8-diazabicyclo-[5.4.0]-undec-7-ene (DBU)) were investigated as dissolution/fractionation solvents for wood material. Both native spruce (Picea abies), and pre-extracted spruce were treated with either butanol SIL (SIL1) or hexanol SIL (SIL2) for 5 days at 55 • C under normal pressure. The SILs were formed by bubbling CO 2 through an equimolar mixture of either 1-hexanol or 1-butanol and DBU. The viscosity of the mixture increased from 7.1 mPa s to 2980 mPa s for SIL2 and 5.1 to 1600 mPa s for SIL1. Melting points of the SILs 1 and 2 were at 8 and 14 • C, respectively. After the treatment time (5 days), the undissolved fraction contained 38 wt.% less hemicelluloses compared to native spruce. There was an increase in the glucose content of the milled spruce treated with both SILs, since the milling step reduced the cellulose crystallinity of the wood and facilitated an easier SIL access into the wood. The solvents were very neutral in terms of lignin removal. Consequently, only about 2% of the lignin was removed from native wood. Moreover, a priori removal of the wood extractives did not influence the lignin removal.
CO2 - Ionic Liquids synergies: Reactive capture and conversion of CO2 to chemicals Valerie Etaa, ... more CO2 - Ionic Liquids synergies: Reactive capture and conversion of CO2 to chemicals Valerie Etaa, Pasi Virtanena, Ikenna Anugwoma, Pivi Mki-Arvelaa, Jyri-Pekka Mikkolaa,b aLaboratory of Industrial Chemistry and Reaction Engineering, Process Chemistry Centre, bo Akademi University, Biskopsgatan 8, 20500 Turku/bo, Finland. bTechnical Chemistry, Department of Chemistry, Chemical Biological Center, Ume University, SE-90187 Ume. Novel technologies based on the utilization of abundant and non-toxic carbon dioxide (CO2) for the synthesis of materials and chemicals may significantly contribute towards the development of sustainable industrial practices. Naturally, myriad substances are synthesized from CO2 and consumed by humans. The conversion of CO2 to fuels and chemicals is an attractive method of utilizing CO2 from the viewpoint of green chemistry and sustainable development. The use of CO2 in the synthesis of chemicals such as dimethyl carbonate (DMC) or switchable ionic liquids (SILs) ...
Green Processing and Synthesis, 2014
Biomass and Bioenergy, 2014