Manouchehr Nikazar | AmirKabir University Of Technology (original) (raw)
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Papers by Manouchehr Nikazar
Petroleum Science and Technology, 2016
Journal of Petroleum Science and Engineering, 2016
Iranian Journal of Chemistry and Chemical Engineering, Dec 1, 2008
ABSTRACT: In this report, experimental investigation of waste water treatment by reverse osmosis ... more ABSTRACT: In this report, experimental investigation of waste water treatment by reverse osmosis to enable its reuse in cooling tower is presented. A polyamide spiral wound RO membrane followed by three filters as RO pretreatment (two activated carbon and one cartridge filter) and ...
approach based on kinetic gelation model is used to simulate the kinetics of non-linear free radi... more approach based on kinetic gelation model is used to simulate the kinetics of non-linear free radical copolymerization of vinyl-divinyl monomer mixtures or chemical gelation, and to characterize kinetic effects on polymerization statistics and microstructures. New algorithm for random selection of the next neighbour site in a self-avoiding random walk and efficient mechanisms of mobility of components are introduced to improve the universality of the predictions by removing commonly occurring simulation deficiencies due to early trapping of radicals. The model has the capability of predicting the onset of the sol-gel transition and the effect of chemical composition on the transition point. It is shown that there is attained a better understanding of microstructure evolution and appearance of gel phase during polymerization and chemical gelation. Finally, one important benefit of the simulation method is the ability of characterizing system in which, the dominant combination reaction leads to highly branched structure.
approach based on kinetic gelation model is used to simulate the kinetics of non-linear free radi... more approach based on kinetic gelation model is used to simulate the kinetics of non-linear free radical copolymerization of vinyl-divinyl monomer mixtures or chemical gelation, and to characterize kinetic effects on polymerization statistics and microstructures. New algorithm for random selection of the next neighbour site in a self-avoiding random walk and efficient mechanisms of mobility of components are introduced to improve the universality of the predictions by removing commonly occurring simulation deficiencies due to early trapping of radicals. The model has the capability of predicting the onset of the sol-gel transition and the effect of chemical composition on the transition point. It is shown that there is attained a better understanding of microstructure evolution and appearance of gel phase during polymerization and chemical gelation. Finally, one important benefit of the simulation method is the ability of characterizing system in which, the dominant combination reaction leads to highly branched structure.
Journal of Environmental Science and Health, Part A, 2014
The photocatalytic degradation of synthetic dye solution of Reactive Blue 2 was investigated usin... more The photocatalytic degradation of synthetic dye solution of Reactive Blue 2 was investigated using UV irradiation in aqueous suspension of nanotitania as photocatalyst and H2O2 as electron acceptor in a slurry photoreactor. To determine the optimum condition of decolorization, the influential parameters including initial dye concentration, catalyst quantity, hydrogen peroxide concentration, pH value and UV light intensity were evaluated using the Taguchi statistical method. The results indicated that compared to the other parameters, UV light intensity was the most effective. The theoretically predicted value of decolorization efficiency (95.48%) was confirmed by the experimental value (95.22%). The mineralization was considered significant with regard to the obtained values of total organic carbon (TOC) analysis (92.52%) and chemical oxygen demand (COD) analysis (94.05%) in the optimum condition. Investigations were also carried out to determine the appropriate adsorption isotherm and kinetic model in the optimum condition. The obtained optimum condition for dye removal was finally examined applying a real sample of textile wastewater containing the dye.
JOURNAL OF CHEMICAL ENGINEERING OF JAPAN, 2009
The adsorption of liquid aromatic/alkane mixtures on NaY (Si/Al 2.43) has been investigated using... more The adsorption of liquid aromatic/alkane mixtures on NaY (Si/Al 2.43) has been investigated using a batch technique. The adsorption of aromatics (benzene and toluene) from hexane, heptanes and octane was measured at room temperature. Already at low concentrations, the aromatics were selectively adsorbed on NaY from their binary mixture with an alkane. In NaY zeolite, benzene and toluene are preferentially adsorbed over C6, C7 and C8 n-alkanes (benzene/n-C6 and toluene/C6 selectivity as high as 1000), because benzene and toluene have a higher heat of adsorption and pack more efficiently in the NaY super cages. Results for aromatics are consistent with specific interaction of its π π π π π electrons with Na atoms on the zeolite surface. These interactions increase the heat of adsorption for aromatics with NaY zeolite. Also, the interaction of n-alkanes with active sites on the surface indicates the heat of adsorption is lower than that for aromatics.
International Journal of Scientific Research, 2008
Desalination, 2008
In this investigation photocatalytic degradation of azo dye Acid Red 114 in water was studied. Ti... more In this investigation photocatalytic degradation of azo dye Acid Red 114 in water was studied. Titanium (IV) oxide was supported on clinoptilolite (CP) (Iranian natural zeolite) using solid-state dispersion (SSD) method. The results show that the TiO 2 /clinoptilolite (SSD) are an active photocatalyst. The maximum effect of photodegradation was observed at 10 wt.% TiO 2 , 90 wt% clinoptilolite. A first order reaction with K = 0.0127 min !1 was observed for the photocatalytic degradation reaction. The effects of some parameters such as pH, amount of photocatalyst, and initial concentration of dye were also examined. Based on the results, a model was proposed for photodegradation of dyes using immobilized [TiO 2 /clinoptilolite (SSD)]. This model can be useful for the development of this technology for wastewater treatment applications.
Journal of the Chinese Chemical Society, 2007
1 ، رﺳﺘﻤﯽ ﻣﺤﻤﺪﺣﺴﯿﻦ 2 * ، روﻏﻨﯽ ﻣﺤﻤﺪﯾﻮﺳﻒ 3 آذر ﻧﯿﮏ ﻣﻨﻮﭼﻬﺮ ، 4 1 ﺷﯿﻤﯽ ﻣﻬﻨﺪﺳﯽ ارﺷ... more 1 ، رﺳﺘﻤﯽ ﻣﺤﻤﺪﺣﺴﯿﻦ 2 * ، روﻏﻨﯽ ﻣﺤﻤﺪﯾﻮﺳﻒ 3 آذر ﻧﯿﮏ ﻣﻨﻮﭼﻬﺮ ، 4 1 ﺷﯿﻤﯽ ﻣﻬﻨﺪﺳﯽ ارﺷﺪ ﮐﺎرﺷﻨﺎﺳﯽ داﻧﺸﺠﻮي ﭘﯿﺸﺮﻓﺘﻪ اﻣﯿﺮﮐﺒﯿﺮ ﺻﻨﻌﺘﯽ داﻧﺸﮕﺎه 2 ﺷﯿﻤﯽ ﻣﻬﻨﺪﺳﯽ ارﺷﺪ ﮐﺎرﺷﻨﺎﺳﯽ داﻧﺸﺠﻮي اﻣﯿﺮﮐﺒﯿﺮ ﺻﻨﻌﺘﯽ داﻧﺸﮕﺎه زﯾﺴﺖ ﻣﺤﯿﻂ 3 ﮐﺎرﺷﻨﺎس ﺻﻨﻌﺘﯽ داﻧﺸﮕﺎه زﯾﺴﺖ ﻣﺤﯿﻂ ﺷﯿﻤﯽ ﻣﻬﻨﺪﺳﯽ ارﺷﺪ ﺷﺮﯾﻒ 4 اﺳﺘﺎد داﻧﺸﮑﺪه ﺷﯿﻤﯽ ﻣﻬﻨﺪﺳﯽ ﮐﺒﯿﺮ اﻣﯿﺮ ﺻﻨﻌﺘﯽ داﻧﺸﮕﺎه ﭼﮑﯿﺪه ﻣﯽ ﺻﻮرت ﻣﺤﺪود ﺑﺴﯿﺎر ﺑﺼﻮرت زﺑﺎﻟﻪ اﺳﺘﺎﻧﺪارد و ﺑﻬﺪاﺷﺘﯽ دﻓﻦ ﮐﻪ اﯾﺮان در ﺑﺨﺼﻮص ﺷﯿﺮاﺑﻪ ﺗﺼﻔﯿﻪ و ﺣﺴﺎس ﺑﺴﯿﺎر ﮔﯿﺮد ﺑﺎﺷﺪ ﻣﯽ ﺣﯿﺎﺗﯽ . ﻣﻄﺎﻟﻌﻪ اﯾﻦ ﺷﺪه ﻏﻨﯽ ذرات ﻧﺎﻧﻮ از اﺳﺘﻔﺎده ﺑﺎ ﮐﻬﺮﯾﺰك زﺑﺎﻟﻪ دﻓﻦ ﻣﺮﮐﺰ از ﺣﺎﺻﻞ ﺷﯿﺮاﺑﻪ ﺗﺼﻔﯿﻪ ﺑﺮرﺳﯽ ﺑﻪ Fe 3+ -TiO 2 و اوﻟﯿﻪ آﻟﯽ ﺑﺎر ورودي، ﮐﺎﺗﺎﻟﯿﺴﺖ ﻣﯿﺰان ﭘﺎراﻣﺘﺮﻫﺎي ﺑﺮرﺳﯽ ﺑﺎ pH ، ﺳﻄﺤﯽ ﭘﺎﺳﺦ روش ﺗﻮﺳﻂ ) (RSM اﺳﺖ ﭘﺮداﺧﺘﻪ . ﺣﺬف ﻣﯿﺰان آﻣﺪه ﺑﺪﺳﺖ ﻣﺪل 33 / 53 ا درﺻﺪ آﻟﯽ ﺑﺎر ز ورودي، ﮔﺬﺷﺖ از ﭘﺲ 24 ﺳﺎﻋﺖ دﻣﺎﯾﯽ ﻣﯿﺎﻧﮕﯿﻦ در و 27 درﺟﻪ را ﺳﺎﻧﺘﯿﮕﺮاد ﺷﺮاﯾ در ﺷﺪه ﺑﺮرﺳﯽ ﻫﺎي ﭘﺎراﻣﺘﺮ ﺑﻬﯿﻨﻪ ﻂ ، دﻫﺪ ﻣﯽ ﻧﺸﺎن . ﮐﻠﯿﺪي ﮐﻠﻤﺎت ﺳﻄﺤﯽ ﭘﺎﺳﺦ روش ذره، ﻧﺎﻧﻮ ﻓﻮﺗﻮﮐﺎﺗﺎﻟﯿﺴﺖ، ﺷﯿﺮاﺑﻪ، ﭘﮋوﻫﺶ ﺑﺮﺟﺴﺘﻪ ﻧﮑﺎت ﭘ ﺷﯿﺮاﺑﻪ ﻓﻮﺗﻮﮐﺎﺗﺎﻟﯿﺴﺘﯽ ﺗﺠﺰﯾﻪ ﺑﺮرﺳﯽ ﺑﻪ ﻣﻄﺎﻟﻌﻪ اﯾﻦ در اﺳﺖ ﺷﺪه ﺮداﺧﺘﻪ . ﻧﺎﻧﻮذرات ﺳﺎزي ﻏﻨﯽ اﺛﺮ TiO 2 آﻫﻦ ذرات ﻧﺎﻧﻮ ﺑﺎ اﺳﺖ ﮔﺮﺗﻪ ﻗﺮار ﺑﺮرﺳﯽ ﻣﻮرد . ﺳﻄﺤﯽ ﭘﺎﺳﺦ روش ﮐﻤﮏ ﺑﻪ آزﻣﺎﯾﺶ ﻃﺮاﺣﯽ از آزﻣﺎﯾﺶ اﻧﺠﺎم ﺟﻬﺖ (RSM) اﺳﺖ ﺷﺪه ﮔﺮﻓﺘﻪ ﺑﻬﺮه . ١ -ﻣﻘﺪﻣﮫ در ﺷﯿ ﺧﺼﻮص ﺑﻪ ﻣﺼﺮف و ﺗﻮﻟﯿﺪ رﻓﺘﺎرﻫﺎي اﻧﺴﺎﻧﯽ ﺟﺎﻣﻌﻪ و ﺟﻤﻌﯿﺖ ﻧﻤﺎﯾﯽ رﺷﺪ ﮔﺬﺷﺘﻪ دﻫﻪ ﭼﻨﺪ را ﻣﺼﺮف ﻣﻨﺎﺑﻊ و زﻧﺪﮔﯽ ﻮه اﺳﺖ ﺷﺪه ﻫﻤﺮاه ﺻﻨﻌﺘﯽ و ﺷﻬﺮي زﺑﺎﻟﻪ اﻓﺰاﯾﺶ ﺑﺎ ﻧﺘﯿﺠﻪ در و داده ﺗﻐﯿﯿﺮ . ﺳﺎل در 1994 ﺟﻬﺎﻧﯽ ﺧﺎﻧﮕﯽ زﺑﺎﻟﻪ ﺗﻮﻟﯿﺪ ﻧﺮخ 1.3 ﺳﺎل در ﮐﻪ ﺑﻮده روز در ﺗﻦ ﻣﯿﻠﯿﺎرد 2008 رﺷﺪ ﺑﺎ آن ﻧﻤﻮدار 31.1 % ﻧﺮخ ﺑﻪ 1.7 ﻣﯿﻠﯿﺎر اﺳﺖ رﺳﯿﺪه روز در ﺗﻦ د } 1 { . ﺷﯿﺮاﺑﻪ ﺷﺪه ﺗﻮﻟﯿﺪ ﻋﻤﺮ و ﻧﺸﯿﺘﯽ ﺗﻪ ﺧﺎك، ﻧﻮع ﻣﯿﮑﺮوﺑﯽ، ﻓﻌﺎﻟﯿﺖ ﺟﺎﻣﺪ، ﻧﻮع ﺑﻪ واﺑﺴﺘﻪ ﺧﺼﻮﺻﯿﺖ و ﮐﯿﻔﯿﺖ ﻟﺤﺎظ از ﭘﺴﻤﺎﻧﺪ اﯾﻦ از زﺑﺎﻟﻪ ﺷﺪه دﻓﻦ دارد . ﻧﺸﻮد ﺗﺼﻔﯿﻪ ﻣﻨﺎﺳﺐ ﺑﻄﻮر اﮔﺮ ﮐﻪ ﺑﺎﻻﺳﺖ ً ﻧﺴﺒﺘﺎ ﻫﺎي ﻏﻠﻈﺖ ﺑﺎ آﻟﯽ ﺗﺮﮐﯿﺒﺎت از زﯾﺎدي ﺗﻌﺪاد ﺷﺎﻣﻞ ﺷﯿﺮاﺑﻪ اﯾﻦ
Chemical Engineering Communications, 2014
Journal of environmental health science & engineering, 2014
The photocatalysis of phenol was studied using Fe3O4/ZnO core/shell magnetic nanoparticles (MNPs)... more The photocatalysis of phenol was studied using Fe3O4/ZnO core/shell magnetic nanoparticles (MNPs). The photocatalysts were synthesized by coating of ZnO onto the magnetite by precipitation method and characterized by XRD, SEM and FTIR measurements. Using the Taguchi method, this study analyzes the effect of parameters such as calcinations time, calcinations temperature and molar ratio of Fe3O4:ZnO on the photo activity of Fe3O4/ZnO MNPs. XRD and FTIR analysis confirm that coating process was done successfully. SEM images show that the average particle size of synthesized Fe3O4/ZnO nanoparticles was about 50 nm. The phenol removal efficiency of 88% can be achieved by using a photocatalyst which is synthesized through the optimum conditions: calcinations temperature of 550°C, calcinations time of 2 hours and molar ratio of 1:10 for Fe3O4:ZnO.
Proceedings of the 1998 American Control Conference. ACC (IEEE Cat. No.98CH36207), 1998
In a batch reactor for the methyl methacrylate polymerization (MMA), temperature control was stud... more In a batch reactor for the methyl methacrylate polymerization (MMA), temperature control was studied. Three methods of heat-release estimation (HRE), namely, kinetic model (KM), online energy balance (OLEB) and calorimetric-state estimator (CSE) were investigated. The following three criteria were used to assess these methods: (i) Ability to adjust kinetic errors. (ii) Ability to adjust against dynamic errors. (iii) Sensitivity to temperature noises. The results indicate that the CSE method has a better performance with respect to kinetic and dynamic errors. Additionally, by using this method, the temperature control design becomes self-tuning
Chemical Engineering Research and Design, 2014
ABSTRACT The kinetics of simultaneous dehydrogenation of propane and isobutane over a commercialP... more ABSTRACT The kinetics of simultaneous dehydrogenation of propane and isobutane over a commercialPt-Sn-K/Al2O3 catalyst is reported. The experiments were carried out in a laboratory-scale plug flow reactor over the temperature range of 560-600˚C at atmospheric pressure. Several Langmuir-Hinshelwood mechanisms for C3 and iC4 were tested. Models were derived with the assumption of propane, isobutane and hydrogen adsorption on the same type of active site. A simple deactivation model was used for fitting the kinetic data, then the best fit for these reactions was found with the rate determining step (RDS) of surface reaction for propane and adsorption on the catalyst surface for isobutane. The results showed a good agreement between experimental and calculated data for these simultaneous reactions.
Journal of Thermal Science, 2000
ABSTRACT By using the fractal geometry it is possible to calculate the actual AP (Ammonium Perchl... more ABSTRACT By using the fractal geometry it is possible to calculate the actual AP (Ammonium Perchlorate) surface area and oxidizer-binder interface fractal dimension in the prediction of burning rate of composite solid propellants. In this investigation, the fractal dimension was determined by a procedure known as the “Box Counting Method”. Using this dimension, surface area relations were developed for the rough particles. This method was implemented in the PEM (Petite Ensemble Model) burning rate model. The comparison of burning rates for a typical propellant by the PEM and fractal model shows that the burning rates obtained by using the fractal geometry are slightly less than those obtained by the PEM model.
Petroleum Science and Technology, 2016
Journal of Petroleum Science and Engineering, 2016
Iranian Journal of Chemistry and Chemical Engineering, Dec 1, 2008
ABSTRACT: In this report, experimental investigation of waste water treatment by reverse osmosis ... more ABSTRACT: In this report, experimental investigation of waste water treatment by reverse osmosis to enable its reuse in cooling tower is presented. A polyamide spiral wound RO membrane followed by three filters as RO pretreatment (two activated carbon and one cartridge filter) and ...
approach based on kinetic gelation model is used to simulate the kinetics of non-linear free radi... more approach based on kinetic gelation model is used to simulate the kinetics of non-linear free radical copolymerization of vinyl-divinyl monomer mixtures or chemical gelation, and to characterize kinetic effects on polymerization statistics and microstructures. New algorithm for random selection of the next neighbour site in a self-avoiding random walk and efficient mechanisms of mobility of components are introduced to improve the universality of the predictions by removing commonly occurring simulation deficiencies due to early trapping of radicals. The model has the capability of predicting the onset of the sol-gel transition and the effect of chemical composition on the transition point. It is shown that there is attained a better understanding of microstructure evolution and appearance of gel phase during polymerization and chemical gelation. Finally, one important benefit of the simulation method is the ability of characterizing system in which, the dominant combination reaction leads to highly branched structure.
approach based on kinetic gelation model is used to simulate the kinetics of non-linear free radi... more approach based on kinetic gelation model is used to simulate the kinetics of non-linear free radical copolymerization of vinyl-divinyl monomer mixtures or chemical gelation, and to characterize kinetic effects on polymerization statistics and microstructures. New algorithm for random selection of the next neighbour site in a self-avoiding random walk and efficient mechanisms of mobility of components are introduced to improve the universality of the predictions by removing commonly occurring simulation deficiencies due to early trapping of radicals. The model has the capability of predicting the onset of the sol-gel transition and the effect of chemical composition on the transition point. It is shown that there is attained a better understanding of microstructure evolution and appearance of gel phase during polymerization and chemical gelation. Finally, one important benefit of the simulation method is the ability of characterizing system in which, the dominant combination reaction leads to highly branched structure.
Journal of Environmental Science and Health, Part A, 2014
The photocatalytic degradation of synthetic dye solution of Reactive Blue 2 was investigated usin... more The photocatalytic degradation of synthetic dye solution of Reactive Blue 2 was investigated using UV irradiation in aqueous suspension of nanotitania as photocatalyst and H2O2 as electron acceptor in a slurry photoreactor. To determine the optimum condition of decolorization, the influential parameters including initial dye concentration, catalyst quantity, hydrogen peroxide concentration, pH value and UV light intensity were evaluated using the Taguchi statistical method. The results indicated that compared to the other parameters, UV light intensity was the most effective. The theoretically predicted value of decolorization efficiency (95.48%) was confirmed by the experimental value (95.22%). The mineralization was considered significant with regard to the obtained values of total organic carbon (TOC) analysis (92.52%) and chemical oxygen demand (COD) analysis (94.05%) in the optimum condition. Investigations were also carried out to determine the appropriate adsorption isotherm and kinetic model in the optimum condition. The obtained optimum condition for dye removal was finally examined applying a real sample of textile wastewater containing the dye.
JOURNAL OF CHEMICAL ENGINEERING OF JAPAN, 2009
The adsorption of liquid aromatic/alkane mixtures on NaY (Si/Al 2.43) has been investigated using... more The adsorption of liquid aromatic/alkane mixtures on NaY (Si/Al 2.43) has been investigated using a batch technique. The adsorption of aromatics (benzene and toluene) from hexane, heptanes and octane was measured at room temperature. Already at low concentrations, the aromatics were selectively adsorbed on NaY from their binary mixture with an alkane. In NaY zeolite, benzene and toluene are preferentially adsorbed over C6, C7 and C8 n-alkanes (benzene/n-C6 and toluene/C6 selectivity as high as 1000), because benzene and toluene have a higher heat of adsorption and pack more efficiently in the NaY super cages. Results for aromatics are consistent with specific interaction of its π π π π π electrons with Na atoms on the zeolite surface. These interactions increase the heat of adsorption for aromatics with NaY zeolite. Also, the interaction of n-alkanes with active sites on the surface indicates the heat of adsorption is lower than that for aromatics.
International Journal of Scientific Research, 2008
Desalination, 2008
In this investigation photocatalytic degradation of azo dye Acid Red 114 in water was studied. Ti... more In this investigation photocatalytic degradation of azo dye Acid Red 114 in water was studied. Titanium (IV) oxide was supported on clinoptilolite (CP) (Iranian natural zeolite) using solid-state dispersion (SSD) method. The results show that the TiO 2 /clinoptilolite (SSD) are an active photocatalyst. The maximum effect of photodegradation was observed at 10 wt.% TiO 2 , 90 wt% clinoptilolite. A first order reaction with K = 0.0127 min !1 was observed for the photocatalytic degradation reaction. The effects of some parameters such as pH, amount of photocatalyst, and initial concentration of dye were also examined. Based on the results, a model was proposed for photodegradation of dyes using immobilized [TiO 2 /clinoptilolite (SSD)]. This model can be useful for the development of this technology for wastewater treatment applications.
Journal of the Chinese Chemical Society, 2007
1 ، رﺳﺘﻤﯽ ﻣﺤﻤﺪﺣﺴﯿﻦ 2 * ، روﻏﻨﯽ ﻣﺤﻤﺪﯾﻮﺳﻒ 3 آذر ﻧﯿﮏ ﻣﻨﻮﭼﻬﺮ ، 4 1 ﺷﯿﻤﯽ ﻣﻬﻨﺪﺳﯽ ارﺷ... more 1 ، رﺳﺘﻤﯽ ﻣﺤﻤﺪﺣﺴﯿﻦ 2 * ، روﻏﻨﯽ ﻣﺤﻤﺪﯾﻮﺳﻒ 3 آذر ﻧﯿﮏ ﻣﻨﻮﭼﻬﺮ ، 4 1 ﺷﯿﻤﯽ ﻣﻬﻨﺪﺳﯽ ارﺷﺪ ﮐﺎرﺷﻨﺎﺳﯽ داﻧﺸﺠﻮي ﭘﯿﺸﺮﻓﺘﻪ اﻣﯿﺮﮐﺒﯿﺮ ﺻﻨﻌﺘﯽ داﻧﺸﮕﺎه 2 ﺷﯿﻤﯽ ﻣﻬﻨﺪﺳﯽ ارﺷﺪ ﮐﺎرﺷﻨﺎﺳﯽ داﻧﺸﺠﻮي اﻣﯿﺮﮐﺒﯿﺮ ﺻﻨﻌﺘﯽ داﻧﺸﮕﺎه زﯾﺴﺖ ﻣﺤﯿﻂ 3 ﮐﺎرﺷﻨﺎس ﺻﻨﻌﺘﯽ داﻧﺸﮕﺎه زﯾﺴﺖ ﻣﺤﯿﻂ ﺷﯿﻤﯽ ﻣﻬﻨﺪﺳﯽ ارﺷﺪ ﺷﺮﯾﻒ 4 اﺳﺘﺎد داﻧﺸﮑﺪه ﺷﯿﻤﯽ ﻣﻬﻨﺪﺳﯽ ﮐﺒﯿﺮ اﻣﯿﺮ ﺻﻨﻌﺘﯽ داﻧﺸﮕﺎه ﭼﮑﯿﺪه ﻣﯽ ﺻﻮرت ﻣﺤﺪود ﺑﺴﯿﺎر ﺑﺼﻮرت زﺑﺎﻟﻪ اﺳﺘﺎﻧﺪارد و ﺑﻬﺪاﺷﺘﯽ دﻓﻦ ﮐﻪ اﯾﺮان در ﺑﺨﺼﻮص ﺷﯿﺮاﺑﻪ ﺗﺼﻔﯿﻪ و ﺣﺴﺎس ﺑﺴﯿﺎر ﮔﯿﺮد ﺑﺎﺷﺪ ﻣﯽ ﺣﯿﺎﺗﯽ . ﻣﻄﺎﻟﻌﻪ اﯾﻦ ﺷﺪه ﻏﻨﯽ ذرات ﻧﺎﻧﻮ از اﺳﺘﻔﺎده ﺑﺎ ﮐﻬﺮﯾﺰك زﺑﺎﻟﻪ دﻓﻦ ﻣﺮﮐﺰ از ﺣﺎﺻﻞ ﺷﯿﺮاﺑﻪ ﺗﺼﻔﯿﻪ ﺑﺮرﺳﯽ ﺑﻪ Fe 3+ -TiO 2 و اوﻟﯿﻪ آﻟﯽ ﺑﺎر ورودي، ﮐﺎﺗﺎﻟﯿﺴﺖ ﻣﯿﺰان ﭘﺎراﻣﺘﺮﻫﺎي ﺑﺮرﺳﯽ ﺑﺎ pH ، ﺳﻄﺤﯽ ﭘﺎﺳﺦ روش ﺗﻮﺳﻂ ) (RSM اﺳﺖ ﭘﺮداﺧﺘﻪ . ﺣﺬف ﻣﯿﺰان آﻣﺪه ﺑﺪﺳﺖ ﻣﺪل 33 / 53 ا درﺻﺪ آﻟﯽ ﺑﺎر ز ورودي، ﮔﺬﺷﺖ از ﭘﺲ 24 ﺳﺎﻋﺖ دﻣﺎﯾﯽ ﻣﯿﺎﻧﮕﯿﻦ در و 27 درﺟﻪ را ﺳﺎﻧﺘﯿﮕﺮاد ﺷﺮاﯾ در ﺷﺪه ﺑﺮرﺳﯽ ﻫﺎي ﭘﺎراﻣﺘﺮ ﺑﻬﯿﻨﻪ ﻂ ، دﻫﺪ ﻣﯽ ﻧﺸﺎن . ﮐﻠﯿﺪي ﮐﻠﻤﺎت ﺳﻄﺤﯽ ﭘﺎﺳﺦ روش ذره، ﻧﺎﻧﻮ ﻓﻮﺗﻮﮐﺎﺗﺎﻟﯿﺴﺖ، ﺷﯿﺮاﺑﻪ، ﭘﮋوﻫﺶ ﺑﺮﺟﺴﺘﻪ ﻧﮑﺎت ﭘ ﺷﯿﺮاﺑﻪ ﻓﻮﺗﻮﮐﺎﺗﺎﻟﯿﺴﺘﯽ ﺗﺠﺰﯾﻪ ﺑﺮرﺳﯽ ﺑﻪ ﻣﻄﺎﻟﻌﻪ اﯾﻦ در اﺳﺖ ﺷﺪه ﺮداﺧﺘﻪ . ﻧﺎﻧﻮذرات ﺳﺎزي ﻏﻨﯽ اﺛﺮ TiO 2 آﻫﻦ ذرات ﻧﺎﻧﻮ ﺑﺎ اﺳﺖ ﮔﺮﺗﻪ ﻗﺮار ﺑﺮرﺳﯽ ﻣﻮرد . ﺳﻄﺤﯽ ﭘﺎﺳﺦ روش ﮐﻤﮏ ﺑﻪ آزﻣﺎﯾﺶ ﻃﺮاﺣﯽ از آزﻣﺎﯾﺶ اﻧﺠﺎم ﺟﻬﺖ (RSM) اﺳﺖ ﺷﺪه ﮔﺮﻓﺘﻪ ﺑﻬﺮه . ١ -ﻣﻘﺪﻣﮫ در ﺷﯿ ﺧﺼﻮص ﺑﻪ ﻣﺼﺮف و ﺗﻮﻟﯿﺪ رﻓﺘﺎرﻫﺎي اﻧﺴﺎﻧﯽ ﺟﺎﻣﻌﻪ و ﺟﻤﻌﯿﺖ ﻧﻤﺎﯾﯽ رﺷﺪ ﮔﺬﺷﺘﻪ دﻫﻪ ﭼﻨﺪ را ﻣﺼﺮف ﻣﻨﺎﺑﻊ و زﻧﺪﮔﯽ ﻮه اﺳﺖ ﺷﺪه ﻫﻤﺮاه ﺻﻨﻌﺘﯽ و ﺷﻬﺮي زﺑﺎﻟﻪ اﻓﺰاﯾﺶ ﺑﺎ ﻧﺘﯿﺠﻪ در و داده ﺗﻐﯿﯿﺮ . ﺳﺎل در 1994 ﺟﻬﺎﻧﯽ ﺧﺎﻧﮕﯽ زﺑﺎﻟﻪ ﺗﻮﻟﯿﺪ ﻧﺮخ 1.3 ﺳﺎل در ﮐﻪ ﺑﻮده روز در ﺗﻦ ﻣﯿﻠﯿﺎرد 2008 رﺷﺪ ﺑﺎ آن ﻧﻤﻮدار 31.1 % ﻧﺮخ ﺑﻪ 1.7 ﻣﯿﻠﯿﺎر اﺳﺖ رﺳﯿﺪه روز در ﺗﻦ د } 1 { . ﺷﯿﺮاﺑﻪ ﺷﺪه ﺗﻮﻟﯿﺪ ﻋﻤﺮ و ﻧﺸﯿﺘﯽ ﺗﻪ ﺧﺎك، ﻧﻮع ﻣﯿﮑﺮوﺑﯽ، ﻓﻌﺎﻟﯿﺖ ﺟﺎﻣﺪ، ﻧﻮع ﺑﻪ واﺑﺴﺘﻪ ﺧﺼﻮﺻﯿﺖ و ﮐﯿﻔﯿﺖ ﻟﺤﺎظ از ﭘﺴﻤﺎﻧﺪ اﯾﻦ از زﺑﺎﻟﻪ ﺷﺪه دﻓﻦ دارد . ﻧﺸﻮد ﺗﺼﻔﯿﻪ ﻣﻨﺎﺳﺐ ﺑﻄﻮر اﮔﺮ ﮐﻪ ﺑﺎﻻﺳﺖ ً ﻧﺴﺒﺘﺎ ﻫﺎي ﻏﻠﻈﺖ ﺑﺎ آﻟﯽ ﺗﺮﮐﯿﺒﺎت از زﯾﺎدي ﺗﻌﺪاد ﺷﺎﻣﻞ ﺷﯿﺮاﺑﻪ اﯾﻦ
Chemical Engineering Communications, 2014
Journal of environmental health science & engineering, 2014
The photocatalysis of phenol was studied using Fe3O4/ZnO core/shell magnetic nanoparticles (MNPs)... more The photocatalysis of phenol was studied using Fe3O4/ZnO core/shell magnetic nanoparticles (MNPs). The photocatalysts were synthesized by coating of ZnO onto the magnetite by precipitation method and characterized by XRD, SEM and FTIR measurements. Using the Taguchi method, this study analyzes the effect of parameters such as calcinations time, calcinations temperature and molar ratio of Fe3O4:ZnO on the photo activity of Fe3O4/ZnO MNPs. XRD and FTIR analysis confirm that coating process was done successfully. SEM images show that the average particle size of synthesized Fe3O4/ZnO nanoparticles was about 50 nm. The phenol removal efficiency of 88% can be achieved by using a photocatalyst which is synthesized through the optimum conditions: calcinations temperature of 550°C, calcinations time of 2 hours and molar ratio of 1:10 for Fe3O4:ZnO.
Proceedings of the 1998 American Control Conference. ACC (IEEE Cat. No.98CH36207), 1998
In a batch reactor for the methyl methacrylate polymerization (MMA), temperature control was stud... more In a batch reactor for the methyl methacrylate polymerization (MMA), temperature control was studied. Three methods of heat-release estimation (HRE), namely, kinetic model (KM), online energy balance (OLEB) and calorimetric-state estimator (CSE) were investigated. The following three criteria were used to assess these methods: (i) Ability to adjust kinetic errors. (ii) Ability to adjust against dynamic errors. (iii) Sensitivity to temperature noises. The results indicate that the CSE method has a better performance with respect to kinetic and dynamic errors. Additionally, by using this method, the temperature control design becomes self-tuning
Chemical Engineering Research and Design, 2014
ABSTRACT The kinetics of simultaneous dehydrogenation of propane and isobutane over a commercialP... more ABSTRACT The kinetics of simultaneous dehydrogenation of propane and isobutane over a commercialPt-Sn-K/Al2O3 catalyst is reported. The experiments were carried out in a laboratory-scale plug flow reactor over the temperature range of 560-600˚C at atmospheric pressure. Several Langmuir-Hinshelwood mechanisms for C3 and iC4 were tested. Models were derived with the assumption of propane, isobutane and hydrogen adsorption on the same type of active site. A simple deactivation model was used for fitting the kinetic data, then the best fit for these reactions was found with the rate determining step (RDS) of surface reaction for propane and adsorption on the catalyst surface for isobutane. The results showed a good agreement between experimental and calculated data for these simultaneous reactions.
Journal of Thermal Science, 2000
ABSTRACT By using the fractal geometry it is possible to calculate the actual AP (Ammonium Perchl... more ABSTRACT By using the fractal geometry it is possible to calculate the actual AP (Ammonium Perchlorate) surface area and oxidizer-binder interface fractal dimension in the prediction of burning rate of composite solid propellants. In this investigation, the fractal dimension was determined by a procedure known as the “Box Counting Method”. Using this dimension, surface area relations were developed for the rough particles. This method was implemented in the PEM (Petite Ensemble Model) burning rate model. The comparison of burning rates for a typical propellant by the PEM and fractal model shows that the burning rates obtained by using the fractal geometry are slightly less than those obtained by the PEM model.