Photis Dais | University of Crete (original) (raw)

Papers by Photis Dais

Research paper thumbnail of Separation and Identification of Phenolic Compounds in Olive Oil by Coupling High-Performance Liquid Chromatography with Postcolumn Solid-Phase Extraction to Nuclear Magnetic Resonance Spectroscopy (LC-SPE-NMR)

Journal of Agricultural and Food Chemistry, May 12, 2005

Research paper thumbnail of Detection and quantification of phenolic compounds in olive oil by high resolution 1H nuclear magnetic resonance spectroscopy

Analytica Chimica Acta, Feb 1, 2009

High resolution (1)H NMR spectroscopy has been employed as a versatile and rapid method to analyz... more High resolution (1)H NMR spectroscopy has been employed as a versatile and rapid method to analyze the polar fraction of extra virgin olive oils containing various classes of phenolic compounds. The strategy for identification of phenolic compounds is based on the NMR chemical shifts of a large number of model compounds assigned by using two-dimensional (2D) NMR spectroscopy. Furthermore, 2D NMR was applied to phenolic extracts in an attempt to discover additional phenolic compounds. The (1)H NMR methodology was successful in detecting simple phenols, such as p-coumaric acid, vanillic acid, homovanillyl alcohol, vanillin, free tyrosol, and free hydroxytyrosol, the flavonols apigenin and luteolin, the lignans (+) pinoresinol, (+) 1-acetoxypinoresinol and syringaresinol, two isomers of the aldehydic form of oleuropein and ligstroside, the dialdehydic form of oleuropein and ligstroside lacking a carboxymethyl group, and finally total hydroxytyrosol and total tyrosol reflecting the total amounts of free and esterified hydroxytyrol and tyrosol, respectively. The absolute amount of each phenolic constituent was determined in the polar fraction by using anhydrous 1,3,5-triazine as an internal standard.

Research paper thumbnail of High Resolution-magic Angle Spinning NMR Study of Olive Leaves

Magnetic Resonance in Food Science, 2013

Research paper thumbnail of Impact of Gibbs’ and Duhem’s approaches to thermodynamics on the development of chemical thermodynamics

Archive for History of Exact Sciences, 2020

From 1873 to 1878, the American physicist Josiah Willard Gibbs offered to the scientific communit... more From 1873 to 1878, the American physicist Josiah Willard Gibbs offered to the scientific community three great articles that proved to be a milestone for the science of thermodynamics. On the other hand, between 1886 and 1896, the French physicist Pierre Maurice Marie Duhem translated thermodynamics into the language of Lagrange’s analytical mechanics. At the same time, he expanded its scope to include thermal phenomena, electromagnetic phenomena, and all kinds of irreversible processes. Duhem formulated a version of thermodynamics characterized by the conceptual unification of mechanics, physics, and chemistry. Overall, the work of both physicists on thermodynamics is tremendous, full of axioms, theorems, corollaries, proofs, and hundreds of equations. Therefore, it would be a utopian aim to provide a short analysis of their work. Instead, the present study will attempt to give a brief outline of the main tools and concepts used by the two physicists. I will argue that each scientist approaches thermodynamics in a new and unique way, which reveals their scientific styles as reflected in their personalities, the writing styles, their behavior toward publicity, and their inclination for publication. Finally, I will examine the influence of their theories on the development of chemical thermodynamics.

Research paper thumbnail of Contents lists available at SciVerse ScienceDirect

Awareness on how and where energy is consumed is being increasingly recognized as the key to prev... more Awareness on how and where energy is consumed is being increasingly recognized as the key to prevent waste in next-generation smart buildings. However, while several solutions exist to monitor energy consumption patterns for commercial and industrial users, energy reporting systems currently available to residential users require time-consuming and intrusive installation procedures, or are otherwise unable to provide device-level reports on energy consumption. To fill this gap, this paper discusses the design and performance evaluation of the Tiny Energy Accounting and Reporting System (TinyEARS), an energy monitoring system that generates device-level power consumption reports primarily based on the acoustic signatures of household appliances detected by wireless sensors. Experiments demonstrate that TinyEARS is able to report the power consumption of individual household appliances within a 10% error margin.

Research paper thumbnail of Chemical Analysis of Food: Techniques and Applications edited by Yolanda Picó ( Chapter 13) page Nos. 407-464 ISBN: 97801238486208

Research paper thumbnail of Progress in Colloid & Polymer Science

Progress in Colloid & Polymer Science, 1978

Research paper thumbnail of Polymerization of Allyldimethyl-Dodecylammonium Bromide Liquid Crystalline Monomer to its Liquid Crystalline Polymer

Recent Advances in Liquid Crystalline Polymers, 1985

Recently we have introduced1 a novel class of thermotropic liquid crystalline compounds comprised... more Recently we have introduced1 a novel class of thermotropic liquid crystalline compounds comprised of quaternary ammonium salts, bearing the dimethyldodecylamine moiety as the basic unit.

Research paper thumbnail of Impact of Gibbs' and Duhem's approaches to thermodynamics on the development of chemical thermodynamics

Archive for History of Exact Sciences (2021) 75:175–248, 2021

From 1873 to 1878, the American physicist Josiah Willard Gibbs offered to the scientific communit... more From 1873 to 1878, the American physicist Josiah Willard Gibbs offered to the scientific community three great articles that proved to be a milestone for the science of thermodynamics. On the other hand, between 1886 and 1896, the French physicist Pierre Maurice Marie Duhem translated thermodynamics into the language of Lagrange's analytical mechanics. At the same time, he expanded its scope to include thermal phenomena, electromagnetic phenomena, and all kinds of irreversible processes. Duhem formulated a version of thermodynamics characterized by the conceptual unification of mechanics, physics, and chemistry. Overall, the work of both physicists on thermodynamics is tremendous, full of axioms, theorems, corollaries, proofs, and hundreds of equations. Therefore, it would be a utopian aim to provide a short analysis of their work. Instead, the present study will attempt to give a brief outline of the main tools and concepts used by the two physicists. I will argue that each scientist approaches thermodynamics in a new and unique way, which reveals their scientific styles as reflected in their personalities, the writing styles, their behavior toward publicity, and their inclination for publication. Finally, I will examine the influence of their theories on the development of chemical thermodynamics.

Research paper thumbnail of The double transfer of thermodynamics: From physics to chemistry and from Europe to America

Studies in History and Philosophy of Science, 1919

The aim of this study is twofold: to explore, first, the influence of the intellectual and social... more The aim of this study is twofold: to explore, first, the influence of the intellectual and social conditions on the transfer of thermodynamics to chemistry and thereby the making of chemical thermodynamics, and second, the way that this knowledge was transferred from Europe to America. Consequently, it is of interest to examine the methodological approaches used by physicists and chemists to transfer thermodynamics to chemistry, to evaluate the potential of this science to offer solutions to existing chemical problems, and to discuss the attitude of the scientific community towards these new ideas. The development of chemical thermodynamics in America followed a different route compared to the European experience. Although it was transferred from Europe, it had distinctive characteristics imposed by a different traditional, intellectual and social milieu. This study focuses on the content of the transferred knowledge to America and the direction that this knowledge assumed by the American scientists. As a paradigm, the chemical thermodynamics of Gilbert Newton Lewis will be considered.

Research paper thumbnail of The double transfer of thermodynamics: From physics to chemistry and from Europe to America

Studies in History and Philosophy of Science Part A

The aim of this study is twofold: to explore, first, the influence of the intellectual and social... more The aim of this study is twofold: to explore, first, the influence of the intellectual and social conditions on the transfer of thermodynamics to chemistry and thereby the making of chemical thermodynamics, and second, the way that this knowledge was transferred from Europe to America. Consequently, it is of interest to examine the methodological approaches used by physicists and chemists to transfer ther-modynamics to chemistry, to evaluate the potential of this science to offer solutions to existing chemical problems, and to discuss the attitude of the scientific community towards these new ideas. The development of chemical thermodynamics in America followed a different route compared to the European experience. Although it was transferred from Europe, it had distinctive characteristics imposed by a different traditional, intellectual and social milieu. This study focuses on the content of the transferred knowledge to America and the direction that this knowledge assumed by the American scientists. As a paradigm, the chemical thermodynamics of Gilbert Newton Lewis will be considered.

Research paper thumbnail of NMR Spectroscopy Protocols for Food Metabolomics Applications

Methods in molecular biology (Clifton, N.J.), 2018

NMR spectroscopy has become an indispensable tool for the metabolic profiling of foods and food p... more NMR spectroscopy has become an indispensable tool for the metabolic profiling of foods and food products. In the present protocol, we report an analytical approach based on liquid-state NMR for the determination of polar and nonpolar metabolites in some common liquid (wine, spirits, juice) and solid (cheese, coffee, honey) foods. Although the diversity of foods precludes the use of a single protocol, with small modifications, the proposed methodologies can be adapted to a broader range of foodstuffs.

Research paper thumbnail of Chemical analysis of food: techniques and applications

Choice Reviews Online

ABSTRACT "The} book contains twenty three chapters written by experts on the subject, is... more ABSTRACT "The} book contains twenty three chapters written by experts on the subject, is structured in two parts: the first one describes the role of the latest developments in analytical and bioanalytical techniques, and the second one deals with the most innovative applications and issues in food analysis. The two first introductory chapters about sampling technique, from basic one to the most recent advances, which is still a food challenge because is responsible of the quality and assurance of the analysis, and on data analysis and chemometrics are followed by a review of the most recently applied techniques in process (on-line) control and in laboratories for the analysis of major or minor compounds of food. These techniques ranged from the non-invasive and non-destructive ones, such as infrared spectroscopy, magnetic resonance and ultrasounds, to emerging areas as nanotechnology, biosensors and electronic noses and tongues, including those already well-established in food analysis, such as chromatographic and electrophoretic techniques. These chapters also include two important tools for solving problems in chemical and biological analysis such as mass spectrometry and molecular-based techniques"--

Research paper thumbnail of Polymerization of vinylpyridinium salts. III. Further studies on the interfacial and isotropic polymerization of 4-vinyl-N-methylpyridinium methylsulfate

Journal of Polymer Science: Polymer Chemistry Edition

ABSTRACT

Research paper thumbnail of 13C NMR relaxation study on amylose in dimethyl sulfoxide

Research paper thumbnail of Structure and dynamics of poly(1-naphtyl acrylate) in solution by 13C NMR spectroscopy

Research paper thumbnail of High-field, 13C-N.M.R. spectroscopy of �-?-glucans, amylopectin, and glycogen

Research paper thumbnail of Effect of the Position of the Double Bond on the Polymerization of Micelle Forming Quaternary Ammonium Salts

Research paper thumbnail of Carbon-13 nuclear magnetic resonance relaxation of amylose and dynamic behavior of the hydroxymethyl group

Research paper thumbnail of POLYMERIZATION OF ORIENTED MONOMERS - 5. RADIATION-INDUCED POLYMERIZATION OF 3n-DODECYL-1-VINYLIMIDAZOLIUM IODIDE IN MICELLAR AGGREGATES

Research paper thumbnail of Separation and Identification of Phenolic Compounds in Olive Oil by Coupling High-Performance Liquid Chromatography with Postcolumn Solid-Phase Extraction to Nuclear Magnetic Resonance Spectroscopy (LC-SPE-NMR)

Journal of Agricultural and Food Chemistry, May 12, 2005

Research paper thumbnail of Detection and quantification of phenolic compounds in olive oil by high resolution 1H nuclear magnetic resonance spectroscopy

Analytica Chimica Acta, Feb 1, 2009

High resolution (1)H NMR spectroscopy has been employed as a versatile and rapid method to analyz... more High resolution (1)H NMR spectroscopy has been employed as a versatile and rapid method to analyze the polar fraction of extra virgin olive oils containing various classes of phenolic compounds. The strategy for identification of phenolic compounds is based on the NMR chemical shifts of a large number of model compounds assigned by using two-dimensional (2D) NMR spectroscopy. Furthermore, 2D NMR was applied to phenolic extracts in an attempt to discover additional phenolic compounds. The (1)H NMR methodology was successful in detecting simple phenols, such as p-coumaric acid, vanillic acid, homovanillyl alcohol, vanillin, free tyrosol, and free hydroxytyrosol, the flavonols apigenin and luteolin, the lignans (+) pinoresinol, (+) 1-acetoxypinoresinol and syringaresinol, two isomers of the aldehydic form of oleuropein and ligstroside, the dialdehydic form of oleuropein and ligstroside lacking a carboxymethyl group, and finally total hydroxytyrosol and total tyrosol reflecting the total amounts of free and esterified hydroxytyrol and tyrosol, respectively. The absolute amount of each phenolic constituent was determined in the polar fraction by using anhydrous 1,3,5-triazine as an internal standard.

Research paper thumbnail of High Resolution-magic Angle Spinning NMR Study of Olive Leaves

Magnetic Resonance in Food Science, 2013

Research paper thumbnail of Impact of Gibbs’ and Duhem’s approaches to thermodynamics on the development of chemical thermodynamics

Archive for History of Exact Sciences, 2020

From 1873 to 1878, the American physicist Josiah Willard Gibbs offered to the scientific communit... more From 1873 to 1878, the American physicist Josiah Willard Gibbs offered to the scientific community three great articles that proved to be a milestone for the science of thermodynamics. On the other hand, between 1886 and 1896, the French physicist Pierre Maurice Marie Duhem translated thermodynamics into the language of Lagrange’s analytical mechanics. At the same time, he expanded its scope to include thermal phenomena, electromagnetic phenomena, and all kinds of irreversible processes. Duhem formulated a version of thermodynamics characterized by the conceptual unification of mechanics, physics, and chemistry. Overall, the work of both physicists on thermodynamics is tremendous, full of axioms, theorems, corollaries, proofs, and hundreds of equations. Therefore, it would be a utopian aim to provide a short analysis of their work. Instead, the present study will attempt to give a brief outline of the main tools and concepts used by the two physicists. I will argue that each scientist approaches thermodynamics in a new and unique way, which reveals their scientific styles as reflected in their personalities, the writing styles, their behavior toward publicity, and their inclination for publication. Finally, I will examine the influence of their theories on the development of chemical thermodynamics.

Research paper thumbnail of Contents lists available at SciVerse ScienceDirect

Awareness on how and where energy is consumed is being increasingly recognized as the key to prev... more Awareness on how and where energy is consumed is being increasingly recognized as the key to prevent waste in next-generation smart buildings. However, while several solutions exist to monitor energy consumption patterns for commercial and industrial users, energy reporting systems currently available to residential users require time-consuming and intrusive installation procedures, or are otherwise unable to provide device-level reports on energy consumption. To fill this gap, this paper discusses the design and performance evaluation of the Tiny Energy Accounting and Reporting System (TinyEARS), an energy monitoring system that generates device-level power consumption reports primarily based on the acoustic signatures of household appliances detected by wireless sensors. Experiments demonstrate that TinyEARS is able to report the power consumption of individual household appliances within a 10% error margin.

Research paper thumbnail of Chemical Analysis of Food: Techniques and Applications edited by Yolanda Picó ( Chapter 13) page Nos. 407-464 ISBN: 97801238486208

Research paper thumbnail of Progress in Colloid & Polymer Science

Progress in Colloid & Polymer Science, 1978

Research paper thumbnail of Polymerization of Allyldimethyl-Dodecylammonium Bromide Liquid Crystalline Monomer to its Liquid Crystalline Polymer

Recent Advances in Liquid Crystalline Polymers, 1985

Recently we have introduced1 a novel class of thermotropic liquid crystalline compounds comprised... more Recently we have introduced1 a novel class of thermotropic liquid crystalline compounds comprised of quaternary ammonium salts, bearing the dimethyldodecylamine moiety as the basic unit.

Research paper thumbnail of Impact of Gibbs' and Duhem's approaches to thermodynamics on the development of chemical thermodynamics

Archive for History of Exact Sciences (2021) 75:175–248, 2021

From 1873 to 1878, the American physicist Josiah Willard Gibbs offered to the scientific communit... more From 1873 to 1878, the American physicist Josiah Willard Gibbs offered to the scientific community three great articles that proved to be a milestone for the science of thermodynamics. On the other hand, between 1886 and 1896, the French physicist Pierre Maurice Marie Duhem translated thermodynamics into the language of Lagrange's analytical mechanics. At the same time, he expanded its scope to include thermal phenomena, electromagnetic phenomena, and all kinds of irreversible processes. Duhem formulated a version of thermodynamics characterized by the conceptual unification of mechanics, physics, and chemistry. Overall, the work of both physicists on thermodynamics is tremendous, full of axioms, theorems, corollaries, proofs, and hundreds of equations. Therefore, it would be a utopian aim to provide a short analysis of their work. Instead, the present study will attempt to give a brief outline of the main tools and concepts used by the two physicists. I will argue that each scientist approaches thermodynamics in a new and unique way, which reveals their scientific styles as reflected in their personalities, the writing styles, their behavior toward publicity, and their inclination for publication. Finally, I will examine the influence of their theories on the development of chemical thermodynamics.

Research paper thumbnail of The double transfer of thermodynamics: From physics to chemistry and from Europe to America

Studies in History and Philosophy of Science, 1919

The aim of this study is twofold: to explore, first, the influence of the intellectual and social... more The aim of this study is twofold: to explore, first, the influence of the intellectual and social conditions on the transfer of thermodynamics to chemistry and thereby the making of chemical thermodynamics, and second, the way that this knowledge was transferred from Europe to America. Consequently, it is of interest to examine the methodological approaches used by physicists and chemists to transfer thermodynamics to chemistry, to evaluate the potential of this science to offer solutions to existing chemical problems, and to discuss the attitude of the scientific community towards these new ideas. The development of chemical thermodynamics in America followed a different route compared to the European experience. Although it was transferred from Europe, it had distinctive characteristics imposed by a different traditional, intellectual and social milieu. This study focuses on the content of the transferred knowledge to America and the direction that this knowledge assumed by the American scientists. As a paradigm, the chemical thermodynamics of Gilbert Newton Lewis will be considered.

Research paper thumbnail of The double transfer of thermodynamics: From physics to chemistry and from Europe to America

Studies in History and Philosophy of Science Part A

The aim of this study is twofold: to explore, first, the influence of the intellectual and social... more The aim of this study is twofold: to explore, first, the influence of the intellectual and social conditions on the transfer of thermodynamics to chemistry and thereby the making of chemical thermodynamics, and second, the way that this knowledge was transferred from Europe to America. Consequently, it is of interest to examine the methodological approaches used by physicists and chemists to transfer ther-modynamics to chemistry, to evaluate the potential of this science to offer solutions to existing chemical problems, and to discuss the attitude of the scientific community towards these new ideas. The development of chemical thermodynamics in America followed a different route compared to the European experience. Although it was transferred from Europe, it had distinctive characteristics imposed by a different traditional, intellectual and social milieu. This study focuses on the content of the transferred knowledge to America and the direction that this knowledge assumed by the American scientists. As a paradigm, the chemical thermodynamics of Gilbert Newton Lewis will be considered.

Research paper thumbnail of NMR Spectroscopy Protocols for Food Metabolomics Applications

Methods in molecular biology (Clifton, N.J.), 2018

NMR spectroscopy has become an indispensable tool for the metabolic profiling of foods and food p... more NMR spectroscopy has become an indispensable tool for the metabolic profiling of foods and food products. In the present protocol, we report an analytical approach based on liquid-state NMR for the determination of polar and nonpolar metabolites in some common liquid (wine, spirits, juice) and solid (cheese, coffee, honey) foods. Although the diversity of foods precludes the use of a single protocol, with small modifications, the proposed methodologies can be adapted to a broader range of foodstuffs.

Research paper thumbnail of Chemical analysis of food: techniques and applications

Choice Reviews Online

ABSTRACT "The} book contains twenty three chapters written by experts on the subject, is... more ABSTRACT "The} book contains twenty three chapters written by experts on the subject, is structured in two parts: the first one describes the role of the latest developments in analytical and bioanalytical techniques, and the second one deals with the most innovative applications and issues in food analysis. The two first introductory chapters about sampling technique, from basic one to the most recent advances, which is still a food challenge because is responsible of the quality and assurance of the analysis, and on data analysis and chemometrics are followed by a review of the most recently applied techniques in process (on-line) control and in laboratories for the analysis of major or minor compounds of food. These techniques ranged from the non-invasive and non-destructive ones, such as infrared spectroscopy, magnetic resonance and ultrasounds, to emerging areas as nanotechnology, biosensors and electronic noses and tongues, including those already well-established in food analysis, such as chromatographic and electrophoretic techniques. These chapters also include two important tools for solving problems in chemical and biological analysis such as mass spectrometry and molecular-based techniques"--

Research paper thumbnail of Polymerization of vinylpyridinium salts. III. Further studies on the interfacial and isotropic polymerization of 4-vinyl-N-methylpyridinium methylsulfate

Journal of Polymer Science: Polymer Chemistry Edition

ABSTRACT

Research paper thumbnail of 13C NMR relaxation study on amylose in dimethyl sulfoxide

Research paper thumbnail of Structure and dynamics of poly(1-naphtyl acrylate) in solution by 13C NMR spectroscopy

Research paper thumbnail of High-field, 13C-N.M.R. spectroscopy of �-?-glucans, amylopectin, and glycogen

Research paper thumbnail of Effect of the Position of the Double Bond on the Polymerization of Micelle Forming Quaternary Ammonium Salts

Research paper thumbnail of Carbon-13 nuclear magnetic resonance relaxation of amylose and dynamic behavior of the hydroxymethyl group

Research paper thumbnail of POLYMERIZATION OF ORIENTED MONOMERS - 5. RADIATION-INDUCED POLYMERIZATION OF 3n-DODECYL-1-VINYLIMIDAZOLIUM IODIDE IN MICELLAR AGGREGATES