Boncho Bonev | The Catholic University of America (original) (raw)

Papers by Boncho Bonev

Research paper thumbnail of First Comet Observations with NIRSPEC-2 at Keck: Outgassing Sources of Parent Volatiles and Abundances Based on Alternative Taxonomic Compositional Baselines in 46P/Wirtanen

The Planetary Science Journal, 2021

A major upgrade to the NIRSPEC instrument at the Keck II telescope was successfully completed in ... more A major upgrade to the NIRSPEC instrument at the Keck II telescope was successfully completed in time for near-infrared spectroscopic observations of comet 46P/Wirtanen during its exceptionally close flyby of Earth in 2018 December. These studies determined the abundances of several volatiles, including C2H2, C2H6, CH3OH, NH3, HCN, H2CO, and H2O. Long-slit spatial distributions of gas rotational temperature and column density are diagnostic for the presence of icy grains in the coma and understanding if different volatiles are associated with common or distinct outgassing sources. These spatial distributions suggest that C2H2, C2H6, and HCN have a common outgassing source, whereas H2O and CH3OH have additional, more extended sources. The synergy of these findings with observations by space missions (Rosetta and EPOXI) motivates continuing studies to address whether or not C2H6, C2H2, and HCN have a common source of release (plausibly associated with CO2) in a larger sample of comets...

Research paper thumbnail of Probing the Evolutionary History of Comets: An Investigation of the Hypervolatiles CO, CH4, and C2H6 in the Jupiter-family Comet 21P/Giacobini–Zinner

The Astronomical Journal, 2020

Research paper thumbnail of The Peculiar Volatile Composition of CO-dominated Comet C/2016 R2 (PanSTARRS)

The Astronomical Journal, 2019

Research paper thumbnail of Beyond 3 au from the Sun: The Hypervolatiles CH4, C2H6, and CO in the Distant Comet C/2006 W3 (Christensen)

The Astronomical Journal, 2017

Research paper thumbnail of Spin Temperature of H2O in Comets - A Cosmogonic Indicator?

Research paper thumbnail of C/2013 R1 (Lovejoy) at Ir Wavelengths and the Variability of Co Abundances Among Oort Cloud Comets

The Astrophysical Journal, 2014

Research paper thumbnail of Water Production Rates, Rotational Temperatures, and Spin Temperatures in Comets C/1999 H1 (Lee), C/1999 S4, and C/2001 A2

The Astrophysical Journal, 2005

Research paper thumbnail of Infrared OH Prompt Emission as a Proxy of Water Production in Comets: Quantitative Analysis of the Multiplet Near 3046 cm−1in Comets C/1999 H1 (Lee) and C/2001 A2 (LINEAR)

The Astrophysical Journal, 2004

Research paper thumbnail of The Unusual Volatile Composition of the Halley-Type Comet 8P/Tuttle: Addressing the Existence of an Inner Oort Cloud

The Astrophysical Journal, 2008

Research paper thumbnail of The Volatile Composition of the Split Ecliptic comet 73P/Schwassmann-Wachmann 3: A Comparison of Fragments C and B

The Astrophysical Journal, 2006

Research paper thumbnail of Depleted Carbon Monoxide in Fragment C of the Jupiter-Family Comet 73P/Schwassmann-Wachmann 3

The Astrophysical Journal, 2007

Research paper thumbnail of Chemical Composition of Comet C/2007 N3 (Lulin): Another ‘‘Atypical’’ Comet

The Astrophysical Journal, 2012

Research paper thumbnail of The Peculiar Volatile Composition of Comet 8P/Tuttle: A Contact Binary of Chemically Distinct Cometesimals?

The Astrophysical Journal, 2008

Research paper thumbnail of Organic Volatiles in Comet 73P-B/Schwassmann-Wachmann 3 Observed during Its Outburst: A Clue to the Formation Region of the Jupiter-Family Comets

The Astrophysical Journal, 2007

Research paper thumbnail of A Comprehensive Study of Infrared OH Prompt Emission in Two Comets. II. Implications for Unimolecular Dissociation of H2O

The Astrophysical Journal, 2006

Research paper thumbnail of A Search for Variation in the H 2 O Ortho-Para Ratio and Rotational Temperature in the Inner Coma of Comet C/2004 Q2 (Machholz)

The Astrophysical Journal, 2007

We present spatially resolved measurements of the rotational temperature and ortho-para ratio for... more We present spatially resolved measurements of the rotational temperature and ortho-para ratio for H 2 O in the inner coma of the Oort Cloud comet C/2004 Q2 (Machholz). Our results are based on direct simultaneous detections of ortho-H 2 O and para-H 2 O via "hot-band" fluorescence near 2.9 mm. We find a well-defined decline in rotational temperature with increasing nucleocentric distance (up to ∼1000 km). The ortho-para ratio remains constant (within stochastic uncertainty) with increasing nucleocentric distance and is close to the statistical equilibrium value of 3.0 ( [0.17], including, respectively, stochastic [systematic] uncertainty), resulting 2.86 ‫ע‬ 0.06 in spin temperature K. We compare the present results with those reported for other comets and discuss T ≥ 34 spin the difficulties in interpreting spin temperatures deduced from measured ortho-para ratios. Improved understanding of the special conditions that enable nuclear spin conversion would test the extent to which derived spin temperatures reflect the formative history or the processing record of cometary ices.

Research paper thumbnail of Ground-Based Infrared Detections of Co in the Centaur-Comet 29P/SCHWASSMANN-WACHMANN 1 at 6.26 Au from the Sun

The Astrophysical Journal, 2013

Research paper thumbnail of The Unexpectedly Bright Comet C/2012 F6 (Lemmon) Unveiled at Near-Infrared Wavelengths

The Astronomical Journal, 2013

We acquired near-infrared spectra of the Oort cloud comet C/2012 F6 (Lemmon) at three different h... more We acquired near-infrared spectra of the Oort cloud comet C/2012 F6 (Lemmon) at three different heliocentric distances (R h ) during the comet's 2013 perihelion passage, providing a comprehensive measure of the outgassing behavior of parent volatiles and cosmogonic indicators. Our observations were performed pre-perihelion at R h = 1.2 AU with CRIRES (on 2013 February 2 and 4), and post-perihelion at R h = 0.75 AU with CSHELL (on March 31 and April 1) and R h = 1.74 AU with NIRSPEC (on June 20). We detected 10 volatile species (H 2 O, OH * prompt emission, C 2 H 6 , CH 3 OH, H 2 CO, HCN, CO, CH 4 , NH 3 , and NH 2 ), and obtained upper limits for two others (C 2 H 2 and HDO). One-dimensional spatial profiles displayed different distributions for some volatiles, confirming either the existence of polar and apolar ices, or of chemically distinct active vents in the nucleus. The ortho-para ratio for water was 3.31 ± 0.33 (weighted mean of CRIRES and NIRSPEC results), implying a spin temperature >37 K at the 95% confidence limit. Our (3σ ) upper limit for HDO corresponds to D/H < 2.45 × 10 -3 (i.e., <16 Vienna Standard Mean Ocean Water, VSMOW). At R h = 1.2 AU (CRIRES), the production rate for water was Q(H 2 O) = 1.9 ± 0.1 × 10 29 s -1 and its rotational temperature was T rot ∼ 69 K. At R h = 0.75 AU (CSHELL), we measured Q(H 2 O) = 4.6 ± 0.6 × 10 29 s -1 and T rot = 80 K on March 31, and 6.6 ± 0.9 × 10 29 s -1 and T rot = 100 K on April 1. At R h = 1.74 AU (NIRSPEC), we obtained Q(H 2 O) = 1.1 ± 0.1 × 10 29 s -1 and T rot ∼ 50 K. The measured volatile abundance ratios classify comet C/2012 F6 as rather depleted in C 2 H 6 and CH 3 OH, while HCN, CH 4 , and CO displayed abundances close to their median values found among comets. H 2 CO was the only volatile showing a relative enhancement. The relative paucity of C 2 H 6 and CH 3 OH (with respect to H 2 O) suggests formation within warm regions of the nebula. However, the normal abundance of HCN and hypervolatiles CH 4 and CO, and the enhancement of H 2 CO, may indicate a possible heterogeneous nucleus of comet C/2012 F6 (Lemmon), possibly as a result of radial mixing within the protoplanetary disk.

Research paper thumbnail of Parent Volatiles in Comet 9P/Tempel 1: Before and After Impact

Science, 2005

We quantified eight parent volatiles (H 2 O, C 2 H 6 , HCN, CO, CH 3 OH, H 2 CO, C 2 H 2 , and CH... more We quantified eight parent volatiles (H 2 O, C 2 H 6 , HCN, CO, CH 3 OH, H 2 CO, C 2 H 2 , and CH 4 ) in the Jupiter-family comet Tempel 1 using high-dispersion infrared spectroscopy in the wavelength range 2.8 to 5.0 micrometers. The abundance ratio for ethane was significantly higher after impact, whereas those for methanol and hydrogen cyanide were unchanged. The abundance ratios in the ejecta are similar to those for most Oort cloud comets, but methanol and acetylene are lower in Tempel 1 by a factor of about 2. These results suggest that the volatile ices in Tempel 1 and in most Oort cloud comets originated in a common region of the protoplanetary disk.

Research paper thumbnail of Temporal and Spatial Aspects of Gas Release During the 2010 Apparition of Comet 103P/HARTLEY 2

The Astrophysical Journal, 2011

Research paper thumbnail of First Comet Observations with NIRSPEC-2 at Keck: Outgassing Sources of Parent Volatiles and Abundances Based on Alternative Taxonomic Compositional Baselines in 46P/Wirtanen

The Planetary Science Journal, 2021

A major upgrade to the NIRSPEC instrument at the Keck II telescope was successfully completed in ... more A major upgrade to the NIRSPEC instrument at the Keck II telescope was successfully completed in time for near-infrared spectroscopic observations of comet 46P/Wirtanen during its exceptionally close flyby of Earth in 2018 December. These studies determined the abundances of several volatiles, including C2H2, C2H6, CH3OH, NH3, HCN, H2CO, and H2O. Long-slit spatial distributions of gas rotational temperature and column density are diagnostic for the presence of icy grains in the coma and understanding if different volatiles are associated with common or distinct outgassing sources. These spatial distributions suggest that C2H2, C2H6, and HCN have a common outgassing source, whereas H2O and CH3OH have additional, more extended sources. The synergy of these findings with observations by space missions (Rosetta and EPOXI) motivates continuing studies to address whether or not C2H6, C2H2, and HCN have a common source of release (plausibly associated with CO2) in a larger sample of comets...

Research paper thumbnail of Probing the Evolutionary History of Comets: An Investigation of the Hypervolatiles CO, CH4, and C2H6 in the Jupiter-family Comet 21P/Giacobini–Zinner

The Astronomical Journal, 2020

Research paper thumbnail of The Peculiar Volatile Composition of CO-dominated Comet C/2016 R2 (PanSTARRS)

The Astronomical Journal, 2019

Research paper thumbnail of Beyond 3 au from the Sun: The Hypervolatiles CH4, C2H6, and CO in the Distant Comet C/2006 W3 (Christensen)

The Astronomical Journal, 2017

Research paper thumbnail of Spin Temperature of H2O in Comets - A Cosmogonic Indicator?

Research paper thumbnail of C/2013 R1 (Lovejoy) at Ir Wavelengths and the Variability of Co Abundances Among Oort Cloud Comets

The Astrophysical Journal, 2014

Research paper thumbnail of Water Production Rates, Rotational Temperatures, and Spin Temperatures in Comets C/1999 H1 (Lee), C/1999 S4, and C/2001 A2

The Astrophysical Journal, 2005

Research paper thumbnail of Infrared OH Prompt Emission as a Proxy of Water Production in Comets: Quantitative Analysis of the Multiplet Near 3046 cm−1in Comets C/1999 H1 (Lee) and C/2001 A2 (LINEAR)

The Astrophysical Journal, 2004

Research paper thumbnail of The Unusual Volatile Composition of the Halley-Type Comet 8P/Tuttle: Addressing the Existence of an Inner Oort Cloud

The Astrophysical Journal, 2008

Research paper thumbnail of The Volatile Composition of the Split Ecliptic comet 73P/Schwassmann-Wachmann 3: A Comparison of Fragments C and B

The Astrophysical Journal, 2006

Research paper thumbnail of Depleted Carbon Monoxide in Fragment C of the Jupiter-Family Comet 73P/Schwassmann-Wachmann 3

The Astrophysical Journal, 2007

Research paper thumbnail of Chemical Composition of Comet C/2007 N3 (Lulin): Another ‘‘Atypical’’ Comet

The Astrophysical Journal, 2012

Research paper thumbnail of The Peculiar Volatile Composition of Comet 8P/Tuttle: A Contact Binary of Chemically Distinct Cometesimals?

The Astrophysical Journal, 2008

Research paper thumbnail of Organic Volatiles in Comet 73P-B/Schwassmann-Wachmann 3 Observed during Its Outburst: A Clue to the Formation Region of the Jupiter-Family Comets

The Astrophysical Journal, 2007

Research paper thumbnail of A Comprehensive Study of Infrared OH Prompt Emission in Two Comets. II. Implications for Unimolecular Dissociation of H2O

The Astrophysical Journal, 2006

Research paper thumbnail of A Search for Variation in the H 2 O Ortho-Para Ratio and Rotational Temperature in the Inner Coma of Comet C/2004 Q2 (Machholz)

The Astrophysical Journal, 2007

We present spatially resolved measurements of the rotational temperature and ortho-para ratio for... more We present spatially resolved measurements of the rotational temperature and ortho-para ratio for H 2 O in the inner coma of the Oort Cloud comet C/2004 Q2 (Machholz). Our results are based on direct simultaneous detections of ortho-H 2 O and para-H 2 O via "hot-band" fluorescence near 2.9 mm. We find a well-defined decline in rotational temperature with increasing nucleocentric distance (up to ∼1000 km). The ortho-para ratio remains constant (within stochastic uncertainty) with increasing nucleocentric distance and is close to the statistical equilibrium value of 3.0 ( [0.17], including, respectively, stochastic [systematic] uncertainty), resulting 2.86 ‫ע‬ 0.06 in spin temperature K. We compare the present results with those reported for other comets and discuss T ≥ 34 spin the difficulties in interpreting spin temperatures deduced from measured ortho-para ratios. Improved understanding of the special conditions that enable nuclear spin conversion would test the extent to which derived spin temperatures reflect the formative history or the processing record of cometary ices.

Research paper thumbnail of Ground-Based Infrared Detections of Co in the Centaur-Comet 29P/SCHWASSMANN-WACHMANN 1 at 6.26 Au from the Sun

The Astrophysical Journal, 2013

Research paper thumbnail of The Unexpectedly Bright Comet C/2012 F6 (Lemmon) Unveiled at Near-Infrared Wavelengths

The Astronomical Journal, 2013

We acquired near-infrared spectra of the Oort cloud comet C/2012 F6 (Lemmon) at three different h... more We acquired near-infrared spectra of the Oort cloud comet C/2012 F6 (Lemmon) at three different heliocentric distances (R h ) during the comet's 2013 perihelion passage, providing a comprehensive measure of the outgassing behavior of parent volatiles and cosmogonic indicators. Our observations were performed pre-perihelion at R h = 1.2 AU with CRIRES (on 2013 February 2 and 4), and post-perihelion at R h = 0.75 AU with CSHELL (on March 31 and April 1) and R h = 1.74 AU with NIRSPEC (on June 20). We detected 10 volatile species (H 2 O, OH * prompt emission, C 2 H 6 , CH 3 OH, H 2 CO, HCN, CO, CH 4 , NH 3 , and NH 2 ), and obtained upper limits for two others (C 2 H 2 and HDO). One-dimensional spatial profiles displayed different distributions for some volatiles, confirming either the existence of polar and apolar ices, or of chemically distinct active vents in the nucleus. The ortho-para ratio for water was 3.31 ± 0.33 (weighted mean of CRIRES and NIRSPEC results), implying a spin temperature >37 K at the 95% confidence limit. Our (3σ ) upper limit for HDO corresponds to D/H < 2.45 × 10 -3 (i.e., <16 Vienna Standard Mean Ocean Water, VSMOW). At R h = 1.2 AU (CRIRES), the production rate for water was Q(H 2 O) = 1.9 ± 0.1 × 10 29 s -1 and its rotational temperature was T rot ∼ 69 K. At R h = 0.75 AU (CSHELL), we measured Q(H 2 O) = 4.6 ± 0.6 × 10 29 s -1 and T rot = 80 K on March 31, and 6.6 ± 0.9 × 10 29 s -1 and T rot = 100 K on April 1. At R h = 1.74 AU (NIRSPEC), we obtained Q(H 2 O) = 1.1 ± 0.1 × 10 29 s -1 and T rot ∼ 50 K. The measured volatile abundance ratios classify comet C/2012 F6 as rather depleted in C 2 H 6 and CH 3 OH, while HCN, CH 4 , and CO displayed abundances close to their median values found among comets. H 2 CO was the only volatile showing a relative enhancement. The relative paucity of C 2 H 6 and CH 3 OH (with respect to H 2 O) suggests formation within warm regions of the nebula. However, the normal abundance of HCN and hypervolatiles CH 4 and CO, and the enhancement of H 2 CO, may indicate a possible heterogeneous nucleus of comet C/2012 F6 (Lemmon), possibly as a result of radial mixing within the protoplanetary disk.

Research paper thumbnail of Parent Volatiles in Comet 9P/Tempel 1: Before and After Impact

Science, 2005

We quantified eight parent volatiles (H 2 O, C 2 H 6 , HCN, CO, CH 3 OH, H 2 CO, C 2 H 2 , and CH... more We quantified eight parent volatiles (H 2 O, C 2 H 6 , HCN, CO, CH 3 OH, H 2 CO, C 2 H 2 , and CH 4 ) in the Jupiter-family comet Tempel 1 using high-dispersion infrared spectroscopy in the wavelength range 2.8 to 5.0 micrometers. The abundance ratio for ethane was significantly higher after impact, whereas those for methanol and hydrogen cyanide were unchanged. The abundance ratios in the ejecta are similar to those for most Oort cloud comets, but methanol and acetylene are lower in Tempel 1 by a factor of about 2. These results suggest that the volatile ices in Tempel 1 and in most Oort cloud comets originated in a common region of the protoplanetary disk.

Research paper thumbnail of Temporal and Spatial Aspects of Gas Release During the 2010 Apparition of Comet 103P/HARTLEY 2

The Astrophysical Journal, 2011