Dolomitization and the genesis of the Woodcutters lead-zinc prospect, Northern Territory, Australia (original) (raw)
Abstract
The Woodcutters L. 5 lead-zinc prospect in the Northern Territory, Australia, occurs in the Golden Dyke Formation, a sequence of carbonaceous siltstone, dolomite, and greywacke forming part of the Lower Proterozoic Goodparla Group, which was deposited on an Archaean granitic basement. An attempt has been made to show how those factors which are considered to have been significant in the formation of dolomite were also important in the genesis of the Woodcutters deposit. These factors are: 1. An evaporitic environment which favoured dolomite formation concentrated lead and zinc in the overlying solutions. 2. The base metals were further concentrated, and fixed in the sediments, by co-precipitation with the precursors of dolomite, Mg-calcite and/or aragonite. 3. The formation of dolomite during diagenesis resulted in either a structural change if the precursor was aragonite, or an ordering if the precursor was Mg-calcite. The dolomite could not accommodate the relatively large amount of base metal associated with its precursors, and as a consequence, during dolomitization these were released to the pore solutions. The metals in the pore solutions possibly complexed with organic materials such as those from the degradation of algal protein, and so remained in solution during lithification. During folding, the metal-enriched solutions were transported to fractures, and metal sulphides precipitated when the organic complexes became unstable. After lithification the carbonate-quartz-sulphide veins were zones of weakness along which shearing took place, probably over a considerable period of time. This shearing, as well as slight rise in temperature, resulted in fracturing, recrystallization, and reaction between the first-formed simple sulphides to produce the ore in its present form.
Zusammenfassung
Die Woodcutters L. 5 Blei-Zink-Lagerstätte im Northern Territory, Australien, tritt in der Golden Dyke Formation auf, die aus kohlenstoffhaltigem Siltstein, Dolomit und Grauwacke besteht. Dieselbe bildet einen Teil der Unter-Proterozoischen Sedimente der Goodparla group, welche auf einem Archaischen Granit-Untergrund abgelagert wurden. In dieser Arbeit ist der Versuch gemacht worden, zu zeigen, wie diese Faktoren, welche also wichtig in der Bildung von Dolomit betrachtet werden, auch bedeutend in der Genesis der Woodcutters Lagerstätte waren. Diese Faktoren sind: 1. Die evaporitische Umgebung, welche die Bildung von Dolomit begünstigt, konzentriert ebenfalls Blei-Zink in den darüberliegenden Lösungen. 2. Die Metalle wurden weiter angereichert und mit den Sedimenten durch Co-Precipitation mit den Vorläufern des Dolomits, Mg-Calcit oder Aragonit, verbunden. 3. Die Bildung von Dolomit während der Diagenese führte entweder zu einem strukturellen Wechsel, wenn Aragonit der Vorläufer war, oder zu einem Einbau im Falle von Mg-Calcit. Der gut geordnete Dolomit war nicht in der Lage, die verhältnismäßig große Menge von Blei-Zink, verbunden mit seinen Vorläufern, zu behalten und demzufolge wurden diese während der Dolomitisierung an die Porenlösungen abgegeben. Die Metalle in den Porenlösungen, möglicherweise zusammengesetzt mit organischem Material, wie diejenigen von der Degradation von Algen Protein, verblieben löslich während der Konsolidation. Während der Faltung wurden die mit Metall angereicherten Lösungen zu Spalten transportiert und als Metall-Sulphide niedergeschlagen, als die organischen Komplexe instabil wurden. Nach der Verfestigung wurden die Karbonat-Quarz-Sulphid-Gänge Schwächezonen, entlang denen Scherung stattfand, wahrscheinlich über eine große Zeitspanne hinweg. Sowohl diese Scherung als auch ein leichter Temperaturanstieg verursachten Brüche, Rekristallisationen und Reaktion zwischen den zuerst geformten einfachen Sulphiden, um das Erz in seiner jetzigen Form zu bilden.
Access this article
Subscribe and save
- Get 10 units per month
- Download Article/Chapter or eBook
- 1 Unit = 1 Article or 1 Chapter
- Cancel anytime Subscribe now
Buy Now
Price excludes VAT (USA)
Tax calculation will be finalised during checkout.
Instant access to the full article PDF.
Similar content being viewed by others
References
- Abelson, P. H.: Some aspects of palaeobiochemistry. Ann. N. Y. Acad. Sci., 69, 276–285 (1957).
Google Scholar - Alderman, A. R., Skinner, H., Catherine, W.: Dolomite sedimentation in the south east of South Australia. Am. J. Sci. 255, 561–567 (1957).
Google Scholar - Barbat, W. M.: Crude oil correlations and their role in exploration. Bull. Am. Assoc. Petrol. Geologists 51, 7, 1255–1292 (1967).
Google Scholar - Bondarenko, G. P.: An experimental study of the solubility of galena in the presence of fulvic acids. Geokhimiya 5, 631–636 (1968).
Google Scholar - Bonner, N. A., Kahn, M.: Behaviour of carrierfree tracers. In: Radioactivity applied to chemistry, 604 pp.; Arthur C. Wahl and Norman A. Bonner, eds. John Wiley New York: John Wiley 1951.
Google Scholar - Brooks, R. R., Kaplan, I. R., Peterson, M. N. A.: Trace element composition of Red Sea geothermal brine and interstitial water. In: Hot brines and recent heavy metal deposits in the Red Sea, p. 180–203; Egon T. Degens and David A. Ross, eds. Berlin-Heidelberg-New York: Springer 1969.
Google Scholar - Chilingar, G. R., Bissel, H. J.: Is dolomite favoured by high or low pH? Sedimentology 2, 171–172 (1963a).
Google Scholar - Degens, E. T., Knetsch, G., Reuter, H.: Ein geochemisches Buntsandstein-Profil vom Schwarzwald bis zur Rhön. Neues Jahrb. Geol. Palaentol., Abhandl. 111, 181–233 (1960).
Google Scholar - — Epstein, S.: Oxygen and carbon isotope ratios in coexisting calcites and dolomites from recent and ancient sediments. Geochem. Cosmochem. Acta. 28, 23–44 (1964).
Google Scholar - Dunnet, D., Moore, J. McM.: Inhomogeneous strain and the remobilisation of ores and minerals. Conference on Remobilization of ores and minerals, Cagliari, 81–100 (1969).
- Evans, W. E.: The organic solubilisation of minerals in sediments. In: Advances in Organic Geochemistry, 488 pp.; Umberto Colombo and G. D. Hobson, eds. London: Pergamon Press 1964.
Google Scholar - Friedman, G. M., Sanders, J. E.: Origin and occurrence of Dolostones. In: Developments in sedimentology, 9A, 471 pp.; G. V. Chilingar, H. J. Bissell, and R. W. Fairbridge, eds. Amsterdam: Elsevier 1967.
Google Scholar - — Occurrence and origin of Quaternary dolomite at Salt Flat, west Texas. J. Sediment Petrol. 36, 263–267 (1968).
Google Scholar - Germann, Klaus.: Diagenetic patterns in the Wettersteinkalk (Ladinian, Middle Trias) Northern limestone Alps, Bavaria and Tyrol. J. Sediment Petrol. 38, 2, 490–500 (1968).
Google Scholar - Goldberg, E. D.: The oceans as a chemical system. In: The Sea Interscience N. Y.; M. N. Hill, ed. 3–25 (1963).
- Goleva, G. A., Polyakov, V. A., Nechayeva, T. P.: Distribution and migration of lead in groundwaters. Geochemistry Intern. 7, 2 256–268 (1970).
Google Scholar - Goldsmith, J. R., Graf, D. L., Joensuu, O. I.: The occurrence of magnesian calcite in nature. Geochim. Cosmochim. Acta. 7, 5, 212–230 (1955).
Google Scholar - Graeser, S.: Die Mineralfundstellen in Dolomit des Binnatales. Schweiz. Mineral Petrog. Mitt. 45, 2, 597–795 (1965).
Google Scholar - Graf, D. L., Goldsmith, J. R.: Some hydrothermal syntheses of Dolomite and Protodolomite. J. Geol. 64, 173–186 (1956).
Google Scholar - — Eardley, A. J., Shimp, N. F.: A preliminary report on magnesium carbonate formation in glacial Lake Bonneville. J. Geol. 69, 219–223 (1961).
Google Scholar - Gruner, John W.: The decomposition of ilmenite. Econ. Geol. 54, 1315–1323 (1959).
Google Scholar - Heinrich, E. W.: The geology of carbonatites. Rand McNally Coy. Chicago, 555 pp. (1966).
- Hewitt, D. F.: Dolomitization and ore deposition. Econ. Geol. 32, 821–863 (1928).
Google Scholar - Howe, W. B.: The stratigraphic succession in Missouri. Missouri Geol. Surv. Water Resources, Rep. Invest. XL, 2nd Series, 17 (1961).
- Hunt, J. M.: The origin of petroleum in carbonate rocks. In: Developments in Sedimentology, Vol. 9B, 471 pp. Amsterdam: Elsevier 1967.
Google Scholar - Jackson, S. A., Beales, F. W.: An aspect of sedimentary basin evolution: the concentration of Mississippi Valley-type ores during late stages of diagenesis. Bull. Can. Petrol. Geol. 15, 4, 383–433 (1967).
Google Scholar - Kennedy, G. C.: A portion of the system silica-water. Econ. Geol. 45, 629–653 (1950).
Google Scholar - Krynine, Paul D.: The tourmaline group in sediments, J. Geol. 54, 65–87 (1946).
Google Scholar - Kvenvolden, K. A., Squires, R. M.: Carbon isotope composition of crude oils from Ellenberger Group (Lower Ordovician), Permian Basin, West Texas and Eastern New Mexico. Bull. Am. Assoc. Petrol. Geologists 51, 7, 1293–1303 (1967).
Google Scholar - Larsen, G., Chilingar, G. V.: Introduction to diagenesis in sediments. In: Developments in Sedimentology, Vol. 8, 551 pp. Amsterdam: Elsevier 1967.
Google Scholar - Lerman, A.: Chemical equilibria and evolution of chloride brines. Fiftieth Anniversary Symposia: Mineralogy and Petrology of the Upper Mantle, Sulphides, Mineralogy and Geochemistry of Non-Marine Evaporties. Mineralogical Soc. of America Special Publication 3, 291–306 (1970).
Google Scholar - Marschner, H.: Relationship between carbonate grainsize and non-carbonate content in carbonate sedimentary rocks. In: Recent developments in carbonate sedimentology in Central Europe, pp. 55–57; Muller, G., and Friedman, G. M., eds. (1968).
- Moh, G. H.: Blue remaining covellite and its relations to phases in the sulphur-rich portion of the copper-sulphur system at low temperatures. Mineral. Soc. Japan Spec. I, 226–232 (1971). (Prac. IMA-IAGOD meetings 1970 IMA Vol.).
- Müller, G., Irion, G.: Huntite, dolomite, magnesite, and polyhalite of recent age from Tuz Gölü, Turkey. Nature 220, 1209–1310 (1968).
Google Scholar - — High magnesian calcite and protodolomite in Lake Balaton (Hungary) sediments. Nature 226, 5247, 749–750 (1970).
Google Scholar - Neuberg,Carl,Mandl,Ines.: Beachtliche Wirkung von Salzen organischer Säuren auf unlösliche anorganische Verbindungen. Z. Vitamin-, Hormon-Fermentforsch. 2, 480–492 (1948).
Google Scholar - Owen, E. W.: Petroleum in carbonate rocks. Bull. Am. Assoc. Petrol. Geologists 48, 1727–1730 (1964).
Google Scholar - Palache, Ch., Berman, H., Frondel, C. eds.: Dana's system of mineralogy seventh edition, Vol II, 1124 pp. New York: John Wiley 1951.
Google Scholar - Paterson, M. N. A., von der Borch, C. C.: Chert: modern inorganic deposition in a carbonate-precipitating locality. Science 149, 1501–1503 (1965).
Google Scholar - Roberts, W. M. B.: Recrystallization and mobilization of sulphides at 2,000 atmospheres and in the temperature range 50°–145°. Econ. Geol. 60, 168–171 (1965).
Google Scholar - Roedder, E.: Environment of deposition of stratiform (Mississippi Valley type) ore deposits, from studies of fluid inclusions. Econ. Geol. Monograph 3. Genesis of Stratiform Lead-Zinc-Barite-Fluorite deposits, pp. 349–360; J. S. Brown, ed. (1967).
- Sangster, D. F.: Metallogenesis of some Canadian lead-zinc deposits in carbonate rocks. Proc. Geol. Assoc. Can. 22, 27–36 (1970).
Google Scholar - Skinner, H. C. W., Skinner, B. J., Rubin, M.: Age and accumulation rate of dolomite-bearing carbonate sediments in South Australia. Science 139, 335–336 (1963).
Google Scholar - Snyder, F. G.: Criteria for origin of stratiform ore bodies with application to North East Missouri. In: Genesis of stratiform lead-zinc-barite-fluorite deposits in carbonate rocks. Econ. Geol. Monograph W. 3, 1–13 (1967).
Google Scholar - Taube, A.: Report on investigation of the Woodcutters L. 5 prospect, Rum Jungle area, during 1969. Geopeko Ltd, Gondwana Project (unpubl.).
- Walpole, B. P., Crohn, P. W., Dunn, P. R., Randal, M. A.: Geology of the Katherine-Darwin Region, Northern Territory. Bur. Min. Resour. Aust. Bull. 82 (1968).
- Wyllie, P. J.: Experimental studies of carbonatite problems: The origin and differentiation of carbonatite magmas, pp. 311–352. In: Carbonatites, 591 pp.; O. F. Tuttle, J. Gittins, eds. New York: Interscience Publishers 1966.
Google Scholar - Yoder, H. S., Eugster, H. P.: Synthetic and natural muscovites. Geochim. Cosmochim. Acta. 8, 225, (1955).
Google Scholar - Zwierzicki, J.: Lead and Zinc Ores in Poland. Inst. Geol. Congr. 18th Session Part VII 314–324 (1948).
Author information
Authors and Affiliations
- Canberra City, Australia
W. M. B. Roberts
Authors
- W. M. B. Roberts
You can also search for this author inPubMed Google Scholar
Additional information
Published by permission of the Director, Bureau of Mineral Resources, Geology and Geophysics, Canberra, Australia.
Rights and permissions
About this article
Cite this article
Roberts, W.M.B. Dolomitization and the genesis of the Woodcutters lead-zinc prospect, Northern Territory, Australia.Mineral. Deposita 8, 35–56 (1973). https://doi.org/10.1007/BF00203348
- Received: 04 January 1972
- Issue Date: March 1973
- DOI: https://doi.org/10.1007/BF00203348