Auxetic materials: Avoiding the shrink (original) (raw)

Nature volume 425, page 667 (2003)Cite this article

The Poisson ratio (defined as −1 times the ratio of lateral to applied elastic strains) describes the behaviour of stretched materials — positive Poisson ratios characterize the expected normal behaviour, whereas auxetic materials have a negative value. Although Poisson's ratio for cubic phases must be between −1 and +2, there is no theoretical limitation on this ratio for materials with less internal symmetry. Although few crystals have negative Poisson's ratios for all stretch and lateral directions, such behaviour can be obtained for foams of most materials.

The behaviour of some auxetic materials seems more fitting for Alice's Wonderland than for the real world. After an initial elongation, stretching the porous polytetrafluoroethylene used as artificial arteries generates up to an 11-fold higher relative expansion in one lateral direction. Although the direct effect of a negative Poisson's ratio is to cause an expansion that decreases density during stretching, a small fraction of auxetic crystals actually increase in density when stretched. This behaviour is quite rare, but all 13 observed stretch-densified crystals (out of 500 investigated crystals) are auxetic.

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  1. NanoTech Institute and Department of Chemistry, University of Texas, Dallas, Richardson, 75083-0688, Texas, USA
    Ray H. Baughman

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Baughman, R. Auxetic materials: Avoiding the shrink.Nature 425, 667 (2003). https://doi.org/10.1038/425667a

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