Directed assembly of nanoscale Co(II)-substituted {Co9[P2W15]3} and {Co14[P2W15]4} polyoxometalates (original) (raw)
* Corresponding authors
a WestCHEM, School of Chemistry, University of Glasgow, UK
E-mail: Lee.Cronin@glasgow.ac.uk
Web: www.croninlab.com
b Institute for Materials Research, Tohoku University, Katahira 2-1-1, Aobaku, Japan
Abstract
Herein we report two structurally intriguing Co(II)-substituted polyoxometalates, a {Co9[P2W15]3} and {Co14[P2W15]4} (compounds 1 and 2) that are formed from the same building blocks under subtly different conditions. Compound 1 displays a structure previously predicted but never before realised, whilst compound 2 is the first Co-containing Dawson-based single-molecule magnet and has a unique cruciform structure.
![Graphical abstract: Directed assembly of nanoscale Co(ii)-substituted {Co9[P2W15]3} and {Co14[P2W15]4} polyoxometalates](https://doi.org/en/Image/Get?imageInfo.ImageType=GA&imageInfo.ImageIdentifier.ManuscriptID=C2CC34865A&imageInfo.ImageIdentifier.Year=2012)
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Article information
DOI
https://doi.org/10.1039/C2CC34865A
Article type
Communication
Submitted
08 Jul 2012
Accepted
14 Aug 2012
First published
30 Aug 2012
Download Citation
Chem. Commun., 2012,48, 9819-9821
Permissions
Directed assembly of nanoscale Co(II)-substituted {Co9[P2W15]3} and {Co14[P2W15]4} polyoxometalates
C. Lydon, M. M. Sabi, M. D. Symes, D. Long, M. Murrie, S. Yoshii, H. Nojiri and L. Cronin,Chem. Commun., 2012, 48, 9819DOI: 10.1039/C2CC34865A
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