Equations of state of ice VI and ice VII at high pressure and high temperature (original) (raw)

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Research Article| September 10 2014

Lucile Bezacier;

1

European Synchrotron Radiation Facility

, 6 rue Jules Horowitz, 38000 Grenoble,

France

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Baptiste Journaux;

2Laboratoire de Géologie de Lyon, UMR 5276 CNRS,

Ecole Normale Supérieure de Lyon – Université Claude Bernard Lyon 1

, 2 rue Raphael Dubois, 69622 Villeurbanne Cedex,

France

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Jean-Philippe Perrillat;

2Laboratoire de Géologie de Lyon, UMR 5276 CNRS,

Ecole Normale Supérieure de Lyon – Université Claude Bernard Lyon 1

, 2 rue Raphael Dubois, 69622 Villeurbanne Cedex,

France

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Hervé Cardon;

2Laboratoire de Géologie de Lyon, UMR 5276 CNRS,

Ecole Normale Supérieure de Lyon – Université Claude Bernard Lyon 1

, 2 rue Raphael Dubois, 69622 Villeurbanne Cedex,

France

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Michael Hanfland;

1

European Synchrotron Radiation Facility

, 6 rue Jules Horowitz, 38000 Grenoble,

France

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Isabelle Daniel

2Laboratoire de Géologie de Lyon, UMR 5276 CNRS,

Ecole Normale Supérieure de Lyon – Université Claude Bernard Lyon 1

, 2 rue Raphael Dubois, 69622 Villeurbanne Cedex,

France

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Crossmark: Check for Updates

J. Chem. Phys. 141, 104505 (2014)

High-pressure H2O polymorphs among which ice VI and ice VII are abundant in the interiors of large icy satellites and exo-planets. Knowledge of the elastic properties of these pure H2O ices at high-temperature and high-pressure is thus crucial to decipher the internal structure of icy bodies. In this study we assess for the first time the pressure-volume-temperature (PVT) relations of both polycrystalline pure ice VI and ice VII at high pressures and temperatures from 1 to 9 GPa and 300 to 450 K, respectively, by using in situ synchrotron X-ray diffraction. The PVT data are adjusted to a second-order Birch-Murnaghan equation of state and give _V_0 = 14.17(2) cm3 mol−1, _K_0 = 14.05(23) GPa, and _α_0 = 14.6(14) × 10−5 K−1 for ice VI and _V_0 = 12.49(1) cm3 mol−1, _K_0 = 20.15(16) GPa, and _α_0 = 11.6(5) × 10−5 K−1 for ice VII.

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