Equation of State for Supercooled Water at Pressures up to 400 MPa (original) (raw)
Research Article| October 09 2014
Institute for Physical Science and Technology and Department of Chemical and Biomolecular Engineering,
University of Maryland
, College Park, Maryland 20742,
USA
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Institute for Physical Science and Technology and Department of Chemical and Biomolecular Engineering,
University of Maryland
, College Park, Maryland 20742,
USA
Search for other works by this author on:
Institute for Physical Science and Technology and Department of Chemical and Biomolecular Engineering,
University of Maryland
, College Park, Maryland 20742,
USA
Search for other works by this author on:
J. Phys. Chem. Ref. Data 43, 043101 (2014)
An equation of state is presented for the thermodynamic properties of cold and supercooled water. It is valid for temperatures from the homogeneous ice nucleation temperature up to 300 K and for pressures up to 400 MPa, and can be extrapolated up to 1000 MPa. The equation of state is compared with experimental data for the density, expansion coefficient, isothermal compressibility, speed of sound, and heat capacity. Estimates for the accuracy of the equation are given. The melting curve of ice I is calculated from the phase-equilibrium condition between the proposed equation and an existing equation of state for ice I.
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