Cyanamide Formation under Primitive Earth Conditions (original) (raw)

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Science

8 Jan 1965

Vol 147, Issue 3654

pp. 149-150

Abstract

The dimer of cyanamide, dicyandiamide, is formed upon ultraviolet irradiation of dilute cyanide solutions, and by the electron irradiation of a mixture of methane, ammonia, and water. Thus cyanamide may have had an important role in chemical evolution.

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References

MILLER, S.L., PRODUCTION OF SOME ORGANIC COMPOUNDS UNDER POSSIBLE PRIMITIVE EARTH CONDITIONS, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 77: 2351 (1955).

ORO, J, SYNTHESIS OF PURINES UNDER POSSIBLE PRIMITIVE EARTH CONDITIONS .1. ADENINE FROM HYDROGEN CYANIDE, ARCHIVES OF BIOCHEMISTRY AND BIOPHYSICS 94: 217 (1961).

PONNAMPERUMA, C, CHEMICAL EVOLUTION + ORIGIN OF LIFE, NATURE 201: 337 (1964).

PONNAMPERUMA, C, FORMATION OF ADENINE BY ELECTRON IRRADIATION OF METHANE, AMMONIA, AND WATER, PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA 49: 737 (1963).

STEINMAN, G, CYANAMIDE - POSSIBLE KEY COMPOUND IN CHEMICAL EVOLUTION, PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA 52: 27 (1964).

Williams, H. E., Cyanogen Compounds 2 19 (1948).

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