IUPAC - homoconjugation (H02842) (original) (raw)

https://doi.org/10.1351/goldbook.H02842

1. [obsolete] @A00472@ between a base and its conjugate acid through a @H02899@ (B … HB+ or AH … A−). Homoassociation is a more appropriate term for this phenomenon.
2. The orbital overlap of two π-systems separated by a non-conjugating group, such as CH2.
   See also:
   conjugate acid–base pair
   ,
   conjugated system
   ,
   homoaromatic

Source:
PAC, 1994, 66, 1077. (Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)) on page 1121 [Terms] [Paper]

Citation: 'homoconjugation' in IUPAC Compendium of Chemical Terminology, 3rd ed. International Union of Pure and Applied Chemistry; 2006. Online version 3.0.1, 2019. https://doi.org/10.1351/goldbook.H02842 RIS BibTex EndNote