Effective classical partition functions (original) (raw)
Abstract
We present a method by which a quantum-mechanical partition function can be approximated from below by an effective classical partition function. The associated potential is obtained by a simple smearing procedure. For a strongly anharmonic oscillator and a double-well potential, the lowest approximation gives a free energy which is accurate to a few percent, even at zero temperature.
- Received 20 May 1986
DOI:https://doi.org/10.1103/PhysRevA.34.5080
©1986 American Physical Society
Authors & Affiliations
- Lauritsen Laboratory, California Institute of Technology, Pasadena, California 91125
- Department of Physics, University of California, San Diego, La Jolla, California 92093
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