hydroxychloroquinoline - Weblio 英和・和英辞典 (original) (raw)

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hydroxychloroquinoline

名詞

hydroxychloroquinoline (uncountable)

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   • 1964 January 4, S. J. Hopkins, “Chemotherapy of Malaria: […]”, in The Chemist and Druggist, volume 181, number 4377, London: Allen & Hanburys Ltd, section “Therapeutic Treatment”, entry “Chloroquine”, page 12, column 2:
   • 1966, “Diarrhea”, in Cumulated Index Medicus, volume 7, part 1, “Subject Index D - M”, U.S. Department of Health, Education, and Welfare, section “Drug Therapy”, page S-1144, column 2:
   • 2020, Sara Szymkuć; Ewa P. Gajewska; Karol Molga; Agnieszka Wołos; Rafał Roszak; Wiktor Beker; Martyna Moskal; Piotr Dittwald; Bartosz A. Grzybowski, “Computer-generated “synthetic contingency” plans at times of logistics and supply problems: scenarios for hydroxychloroquine and remdesivir”, in Chemical Science, Royal Society of Chemistry, section “Results and discussion”, subsection “Known syntheses of hydroxychloroquine (HCQ)”, page 6738, column 2:
     The heterocyclic part of HCQ, 1, is rather inexpensive (1.50 $ per g from S-A, 0.26 $ per g from Biosynth Carbosynth) and in case of supply problems, can be sourced (in 94% yield, via chlorination using POCl₃) from hydroxychloroquinoline 13 which, in turn, can be made in ~40% yields in two steps either from 3-chloroaniline, diethyl malonate and ethyl orthoformate (respectively, 9.51 $ per g from S-A, 0.05 $ per g from Oakwood Chemical, OC; 0.04 $ per g from S-A, 0.015 $ per g from OC; 0.12 $ per g from S-A, 0.03 $ per g from OC) or from 3-chloroaniline, acrylic acid (または methyl acrylate) and tosyl chloride (respectively, 9.51 $ per g from S-A, 0.05 $ per g from OC; 1.48 $ per g from S-A, 0.02 $ per g from Gelest Inc.; 1.43 $ per g from S-A, 0.03 $ per g from Alfa Aesar; 0.02 $ per g from S-A, 0.04 $ per g from Alfa Aesar).

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