Zhigang Suo | Harvard University (original) (raw)
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Papers by Zhigang Suo
Journal of the Mechanics and Physics of Solids, May 31, 2008
A large quantity of small molecules may migrate into a network of long polymers, causing the netw... more A large quantity of small molecules may migrate into a network of long polymers, causing the network to swell, forming an aggregate known as a polymeric gel. This paper formulates a theory of the coupled mass transport and large deformation. The free energy of the gel results from two molecular processes: stretching the network and mixing the network with the small molecules. Both the small molecules and the long polymers are taken to be incompressible, a constraint that we enforce by using a Lagrange multiplier, which ...
International Journal of Solids and Structures, 2009
A network of polymers can imbibe a large quantity of a solvent and swell, resulting in a gel. The... more A network of polymers can imbibe a large quantity of a solvent and swell, resulting in a gel. The swelling process can be markedly influenced by a mechanical load and geometric constraint. When the network, solvent, and mechanical load equilibrate, inside the gel the chemical potential of the solvent is homogeneous, but the concentration of the solvent and the deformation of the network can be inhomogeneous. We use the chemical potential of the solvent and the deformation gradient of the network as the independent variables of the free-energy function, and show that the boundary value problem of the swollen gel is equivalent to that of a hyperelastic solid. We implement this approach in the finite-element package, ABAQUS, and analyze examples of swelling-induced deformation, contact, and bifurcation. Because commercial software like ABAQUS is widely available, this work may provide a powerful tool to study complex phenomena in gels.
Journal of the Mechanics and Physics of Solids, May 31, 2008
A large quantity of small molecules may migrate into a network of long polymers, causing the netw... more A large quantity of small molecules may migrate into a network of long polymers, causing the network to swell, forming an aggregate known as a polymeric gel. This paper formulates a theory of the coupled mass transport and large deformation. The free energy of the gel results from two molecular processes: stretching the network and mixing the network with the small molecules. Both the small molecules and the long polymers are taken to be incompressible, a constraint that we enforce by using a Lagrange multiplier, which ...
International Journal of Solids and Structures, 2009
A network of polymers can imbibe a large quantity of a solvent and swell, resulting in a gel. The... more A network of polymers can imbibe a large quantity of a solvent and swell, resulting in a gel. The swelling process can be markedly influenced by a mechanical load and geometric constraint. When the network, solvent, and mechanical load equilibrate, inside the gel the chemical potential of the solvent is homogeneous, but the concentration of the solvent and the deformation of the network can be inhomogeneous. We use the chemical potential of the solvent and the deformation gradient of the network as the independent variables of the free-energy function, and show that the boundary value problem of the swollen gel is equivalent to that of a hyperelastic solid. We implement this approach in the finite-element package, ABAQUS, and analyze examples of swelling-induced deformation, contact, and bifurcation. Because commercial software like ABAQUS is widely available, this work may provide a powerful tool to study complex phenomena in gels.