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Papers by Susana Rodriguez-Couto

Research paper thumbnail of Application of solid-state fermentation to ligninolytic enzyme production

Biochemical Engineering Journal, 2005

Research paper thumbnail of Special issue: Emerging microbial technologies for wastewater treatment

Journal of Basic Microbiology, 2022

Research paper thumbnail of Algal biorefinery: technoeconomic analysis

Handbook of Biofuels, 2022

Research paper thumbnail of Nanoadsorbents for scavenging emerging contaminants from wastewater

Development in Wastewater Treatment Research and Processes, 2022

Research paper thumbnail of Praseodymium-doped cadmium tungstate (CdWO4) nanoparticles for dye degradation with sonocatalytic process

Polyhedron, 2020

Abstract In the present work, praseodymium-doped cadmium tungstate (Pr-CdWO4) nanoparticles were ... more Abstract In the present work, praseodymium-doped cadmium tungstate (Pr-CdWO4) nanoparticles were synthesized, characterized and used as catalysts in a sonocatalytic process to degrade the toxic synthetic azo dye Remazol Black B (RBB). RBB was degraded by 93.9% operating at optimal conditions (pH=3, C=100 mg/L, catalyst dosage=0.35 g/L, T=298 K and irradiation time100 min) under an ultrasonic bath at 60 kHz. Further, the addition of different radical scavengers and enhancers to the reaction was assessed. It was found that the addition of the radical scavengers sodium sulfate, sodium carbonate, and sodium chloride decreased RBB degradation from 93.9% to 86.0%, 78.0%, and 71.2%, respectively. On the contrary, the addition of the enhancers potassium periodate, peroxydisulfate and hydrogen peroxide slightly increased the RBB degradation from 93.9% to 95.3%, 96.1%, and 98.7%, respectively. The sonocatalytic process resulted in higher RBB degradation than by applying separately sonolysis (34.7%) and the catalyst as an adsorbent (39.5%). The experimental data followed both the pseudo-first-order (PFO) and Langmuir-Hinshelwood (L-H) kinetics models. However, the PFO gave better fitting (R2=0.993) than the L-H kinetic model (R2=0.9025) at the same optimum experimental conditions. The obtained results pointed out the sonocatalytic process with Pr-doped CdWO4 nanoparticles as a promising process for the degradation of azo dyes and other hazardous organic compounds existing in wastewater.

Research paper thumbnail of Corrigendum to "Surfactant modified kaolinite (MK-BZK) as an adsorbent for the removal of diazinon from aqueous solutions" published in vol. 196, August 2020, pp. 137-145 (doi: 10.5004/dwt.2020.25922)

DESALINATION AND WATER TREATMENT, 2020

Research paper thumbnail of Enzymatic potential for the valorization of agro-industrial by-products

Biotechnology Letters, 2020

Agro-industrial residues and by-products are a crescent environmental problem since they are ofte... more Agro-industrial residues and by-products are a crescent environmental problem since they are often discarded without proper treatment, and still have growing production. These residues are rich from a nutritional point of view and contain various industrial relevant compounds, such as phenolic compounds, fibers, vitamins, sugars and others. The crescent worrying about environmental issues has led researchers and industries to focus on “eco-friendly” solutions for everyday problems. In this sense, the use of enzymes for the valorization of agro-industrial residues is a safe and green alternative technology. Hence, this review aims to show the enzyme potential for the use and valorization of several agro-industrial residues, focusing on the most produced residues worldwide, such as fruits, grains and lignocellulosic residues, as well as a brief explanation of microbial enzymes, its production and optimization, altogether with tools to identify producing microorganisms.

Research paper thumbnail of Synthesis of FeNi3/SiO2/CuS magnetic nano-composite as a novel adsorbent for Congo Red dye removal

International Journal of Environmental Analytical Chemistry, 2020

In the present study the magnetic nanocomposite FeNi3/SiO2/CuS was synthesised to be applied as a... more In the present study the magnetic nanocomposite FeNi3/SiO2/CuS was synthesised to be applied as a dye adsorbent. The synthesised nanocomposite was characterised using Transmission Electron Microsco...

Research paper thumbnail of Preparation of activated carbon@ZnO composite and its application as a novel catalyst in catalytic ozonation process for metronidazole degradation

Advanced Powder Technology, 2019

Research paper thumbnail of Degradation of azinphos-methyl and chlorpyrifos from aqueous solutions by ultrasound treatment

Journal of Molecular Liquids, 2016

Research paper thumbnail of Space Architecture at ICES 2010

Research paper thumbnail of Adsorption of ethidium bromide (EtBr) from aqueous solutions by natural pumice and aluminium-coated pumice

Journal of Molecular Liquids, 2016

Abstract In the present paper, the removal of ethidium bromide (EtBr) from aqueous solutions in a... more Abstract In the present paper, the removal of ethidium bromide (EtBr) from aqueous solutions in a batch system using natural (NP) and aluminium-coated pumice (ACP) as alternative low-cost adsorbents was investigated. The maximum adsorption capacity, q m (mg/g) was 58.82 and 76.92 mg/g for NP and ACP, respectively, operating at an initial pH of 8, an adsorbent dose of 8 g/L, a contact time of 210 min and an initial EtBr concentration of 30 mg/L. The equilibrium data of both adsorbents fitted the Freundlich isotherm model, indicating the heterogeneity of the adsorbent surface. In addition, the adsorption rate of both adsorbents was well described by the pseudo-second-order kinetics model. This indicated chemisorption was the rate-controlling step of the adsorption process which occurred by ion exchange. Within the performed study, a three-layer artificial neural network (ANN) model was also developed to predict the efficiency of EtBr removal. Computational results clearly demonstrated that the ANN model was able to predict the combined effect of initial pH, adsorbent dose, contact time and initial EtBr concentration on the adsorption efficiency with a very high determination coefficient ( R 2 = 0.998) and a low relative error (RE = 0.037).

Research paper thumbnail of S. Rodríguez Couto, A. Domínguez and A. Sanromán (2001). Utilisation of lignocellulosic wastes for lignin peroxidase production by semi-solid-state cultures of Phanerochaete chrysosporium. Biodegradation, 12: 283-289

Research paper thumbnail of S. Rodríguez Couto, I. Rivela, M. R. Muñoz and A. Sanromán (2000). Ligninolytic enzymes production and the ability of decolourisation of Poly R-478 in packed-bed bioreactors by Phanerochaete chrysosporium. Bioprocess Engineering, 23: 287-293

Research paper thumbnail of D. R. Cabaleiro, S. Rodríguez Couto, A. Sanromán and M. A. Longo (2001). Characterisation of deactivating agents and their influence on the stability of MnPs from Phanerochaete chrysosporium. Journal of Chemical Technology and Biotechnology, 76: 867-872

Journal of Chemical Technology & Biotechnology

Research paper thumbnail of R. Maceiras, S. Rodríguez Couto and A. Sanromán (2001). Influence of several inducers on the synthesis of extracellular laccase and in vivo decolourisation of Poly R-478 by semi-solid-state cultures of Trametes versicolor. Acta Biotechnologica, 21: 255-264

Research paper thumbnail of S. Rodríguez Couto, M. A. Longo, C. Cameselle and A. Sanromán (1999). Production of manganese peroxidase and laccase in laboratory-scale bioreactors by Phanerochaete chrysosporium. Bioprocess Engineering, 20: 531-535

Research paper thumbnail of A modeling study by artificial neural network on ethidium bromide adsorption optimization using natural pumice and iron-coated pumice

Desalination and Water Treatment, 2015

Research paper thumbnail of Biodegradation of bisphenol A by the newly-isolated Enterobacter gergoviae strain BYK-7 enhanced using genetic manipulation

RSC Adv., 2015

Endogenous bacterial strains possessing a high bisphenol A (BPA)-tolerance/degradation activity w... more Endogenous bacterial strains possessing a high bisphenol A (BPA)-tolerance/degradation activity were isolated from different outlets of petrochemical wastewater in Iran using the enrichment cultivation approach.

Research paper thumbnail of In vivodecolourization of the polymeric dye poly R-478 by corncob cultures ofPhanerochaete chrysosporium

Acta Biotechnologica, 2000

ABSTRACT

Research paper thumbnail of Application of solid-state fermentation to ligninolytic enzyme production

Biochemical Engineering Journal, 2005

Research paper thumbnail of Special issue: Emerging microbial technologies for wastewater treatment

Journal of Basic Microbiology, 2022

Research paper thumbnail of Algal biorefinery: technoeconomic analysis

Handbook of Biofuels, 2022

Research paper thumbnail of Nanoadsorbents for scavenging emerging contaminants from wastewater

Development in Wastewater Treatment Research and Processes, 2022

Research paper thumbnail of Praseodymium-doped cadmium tungstate (CdWO4) nanoparticles for dye degradation with sonocatalytic process

Polyhedron, 2020

Abstract In the present work, praseodymium-doped cadmium tungstate (Pr-CdWO4) nanoparticles were ... more Abstract In the present work, praseodymium-doped cadmium tungstate (Pr-CdWO4) nanoparticles were synthesized, characterized and used as catalysts in a sonocatalytic process to degrade the toxic synthetic azo dye Remazol Black B (RBB). RBB was degraded by 93.9% operating at optimal conditions (pH=3, C=100 mg/L, catalyst dosage=0.35 g/L, T=298 K and irradiation time100 min) under an ultrasonic bath at 60 kHz. Further, the addition of different radical scavengers and enhancers to the reaction was assessed. It was found that the addition of the radical scavengers sodium sulfate, sodium carbonate, and sodium chloride decreased RBB degradation from 93.9% to 86.0%, 78.0%, and 71.2%, respectively. On the contrary, the addition of the enhancers potassium periodate, peroxydisulfate and hydrogen peroxide slightly increased the RBB degradation from 93.9% to 95.3%, 96.1%, and 98.7%, respectively. The sonocatalytic process resulted in higher RBB degradation than by applying separately sonolysis (34.7%) and the catalyst as an adsorbent (39.5%). The experimental data followed both the pseudo-first-order (PFO) and Langmuir-Hinshelwood (L-H) kinetics models. However, the PFO gave better fitting (R2=0.993) than the L-H kinetic model (R2=0.9025) at the same optimum experimental conditions. The obtained results pointed out the sonocatalytic process with Pr-doped CdWO4 nanoparticles as a promising process for the degradation of azo dyes and other hazardous organic compounds existing in wastewater.

Research paper thumbnail of Corrigendum to "Surfactant modified kaolinite (MK-BZK) as an adsorbent for the removal of diazinon from aqueous solutions" published in vol. 196, August 2020, pp. 137-145 (doi: 10.5004/dwt.2020.25922)

DESALINATION AND WATER TREATMENT, 2020

Research paper thumbnail of Enzymatic potential for the valorization of agro-industrial by-products

Biotechnology Letters, 2020

Agro-industrial residues and by-products are a crescent environmental problem since they are ofte... more Agro-industrial residues and by-products are a crescent environmental problem since they are often discarded without proper treatment, and still have growing production. These residues are rich from a nutritional point of view and contain various industrial relevant compounds, such as phenolic compounds, fibers, vitamins, sugars and others. The crescent worrying about environmental issues has led researchers and industries to focus on “eco-friendly” solutions for everyday problems. In this sense, the use of enzymes for the valorization of agro-industrial residues is a safe and green alternative technology. Hence, this review aims to show the enzyme potential for the use and valorization of several agro-industrial residues, focusing on the most produced residues worldwide, such as fruits, grains and lignocellulosic residues, as well as a brief explanation of microbial enzymes, its production and optimization, altogether with tools to identify producing microorganisms.

Research paper thumbnail of Synthesis of FeNi3/SiO2/CuS magnetic nano-composite as a novel adsorbent for Congo Red dye removal

International Journal of Environmental Analytical Chemistry, 2020

In the present study the magnetic nanocomposite FeNi3/SiO2/CuS was synthesised to be applied as a... more In the present study the magnetic nanocomposite FeNi3/SiO2/CuS was synthesised to be applied as a dye adsorbent. The synthesised nanocomposite was characterised using Transmission Electron Microsco...

Research paper thumbnail of Preparation of activated carbon@ZnO composite and its application as a novel catalyst in catalytic ozonation process for metronidazole degradation

Advanced Powder Technology, 2019

Research paper thumbnail of Degradation of azinphos-methyl and chlorpyrifos from aqueous solutions by ultrasound treatment

Journal of Molecular Liquids, 2016

Research paper thumbnail of Space Architecture at ICES 2010

Research paper thumbnail of Adsorption of ethidium bromide (EtBr) from aqueous solutions by natural pumice and aluminium-coated pumice

Journal of Molecular Liquids, 2016

Abstract In the present paper, the removal of ethidium bromide (EtBr) from aqueous solutions in a... more Abstract In the present paper, the removal of ethidium bromide (EtBr) from aqueous solutions in a batch system using natural (NP) and aluminium-coated pumice (ACP) as alternative low-cost adsorbents was investigated. The maximum adsorption capacity, q m (mg/g) was 58.82 and 76.92 mg/g for NP and ACP, respectively, operating at an initial pH of 8, an adsorbent dose of 8 g/L, a contact time of 210 min and an initial EtBr concentration of 30 mg/L. The equilibrium data of both adsorbents fitted the Freundlich isotherm model, indicating the heterogeneity of the adsorbent surface. In addition, the adsorption rate of both adsorbents was well described by the pseudo-second-order kinetics model. This indicated chemisorption was the rate-controlling step of the adsorption process which occurred by ion exchange. Within the performed study, a three-layer artificial neural network (ANN) model was also developed to predict the efficiency of EtBr removal. Computational results clearly demonstrated that the ANN model was able to predict the combined effect of initial pH, adsorbent dose, contact time and initial EtBr concentration on the adsorption efficiency with a very high determination coefficient ( R 2 = 0.998) and a low relative error (RE = 0.037).

Research paper thumbnail of S. Rodríguez Couto, A. Domínguez and A. Sanromán (2001). Utilisation of lignocellulosic wastes for lignin peroxidase production by semi-solid-state cultures of Phanerochaete chrysosporium. Biodegradation, 12: 283-289

Research paper thumbnail of S. Rodríguez Couto, I. Rivela, M. R. Muñoz and A. Sanromán (2000). Ligninolytic enzymes production and the ability of decolourisation of Poly R-478 in packed-bed bioreactors by Phanerochaete chrysosporium. Bioprocess Engineering, 23: 287-293

Research paper thumbnail of D. R. Cabaleiro, S. Rodríguez Couto, A. Sanromán and M. A. Longo (2001). Characterisation of deactivating agents and their influence on the stability of MnPs from Phanerochaete chrysosporium. Journal of Chemical Technology and Biotechnology, 76: 867-872

Journal of Chemical Technology & Biotechnology

Research paper thumbnail of R. Maceiras, S. Rodríguez Couto and A. Sanromán (2001). Influence of several inducers on the synthesis of extracellular laccase and in vivo decolourisation of Poly R-478 by semi-solid-state cultures of Trametes versicolor. Acta Biotechnologica, 21: 255-264

Research paper thumbnail of S. Rodríguez Couto, M. A. Longo, C. Cameselle and A. Sanromán (1999). Production of manganese peroxidase and laccase in laboratory-scale bioreactors by Phanerochaete chrysosporium. Bioprocess Engineering, 20: 531-535

Research paper thumbnail of A modeling study by artificial neural network on ethidium bromide adsorption optimization using natural pumice and iron-coated pumice

Desalination and Water Treatment, 2015

Research paper thumbnail of Biodegradation of bisphenol A by the newly-isolated Enterobacter gergoviae strain BYK-7 enhanced using genetic manipulation

RSC Adv., 2015

Endogenous bacterial strains possessing a high bisphenol A (BPA)-tolerance/degradation activity w... more Endogenous bacterial strains possessing a high bisphenol A (BPA)-tolerance/degradation activity were isolated from different outlets of petrochemical wastewater in Iran using the enrichment cultivation approach.

Research paper thumbnail of In vivodecolourization of the polymeric dye poly R-478 by corncob cultures ofPhanerochaete chrysosporium

Acta Biotechnologica, 2000

ABSTRACT