Andrew Grimsdale - Academia.edu (original) (raw)
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Papers by Andrew Grimsdale
Acs Symposium Series, Sep 1, 1997
Macromolecular Chemistry and Physics, Oct 26, 2015
Chemistry of Materials, Feb 17, 2022
Physical review, Jun 15, 1996
Elsevier eBooks, 2013
Abstract: In this chapter the discovery, formation, effects and suppression of fluorenone defects... more Abstract: In this chapter the discovery, formation, effects and suppression of fluorenone defects in fluorene-based conjugated polymers are discussed. The discovery of how these defects are responsible for the formation of green emission from these polymers enabled methods, including improved synthesis methods and the design of new molecular and device structures, to be devised for its suppression. Comparisons are made to the behaviour of other bridged phenylene polymers which also illustrate the widespread applicability of the methods used for suppression of fluorenone defects to the optimisation of other classes of polymers.
Chemistry of Materials, Mar 15, 2019
ACS applied energy materials, Jan 27, 2023
Elsevier eBooks, 2016
The efficiency of LEDs based on conjugated polymers have been enhanced so that they are now comme... more The efficiency of LEDs based on conjugated polymers have been enhanced so that they are now commercially viable. This has occurred in large part by better synthetic design of emissive materials, based on an improved understanding of reaction mechanisms and how these permit defect formation through side reactions, thus enabling their prevention by modification of synthetic route or monomer structure. The performance of polymer-based solar cells has also been improved so that they are now close to commercialization. Again this has been due to synthetic design based on an enhanced knowledge of the underlying processes affecting efficiency, enabling a better understanding of structure-property relationships. The prospects for the future of both classes of device are assessed.
Angewandte Chemie, Feb 16, 1998
ABSTRACT
Australian Journal of Chemistry, 1990
Wiley-VCH Verlag GmbH & Co. KGaA eBooks, Jan 20, 2017
Current Organic Chemistry, Nov 1, 2010
ChemInform, Jun 22, 2010
ABSTRACT
Acs Symposium Series, Sep 1, 1997
Macromolecular Chemistry and Physics, Oct 26, 2015
Chemistry of Materials, Feb 17, 2022
Physical review, Jun 15, 1996
Elsevier eBooks, 2013
Abstract: In this chapter the discovery, formation, effects and suppression of fluorenone defects... more Abstract: In this chapter the discovery, formation, effects and suppression of fluorenone defects in fluorene-based conjugated polymers are discussed. The discovery of how these defects are responsible for the formation of green emission from these polymers enabled methods, including improved synthesis methods and the design of new molecular and device structures, to be devised for its suppression. Comparisons are made to the behaviour of other bridged phenylene polymers which also illustrate the widespread applicability of the methods used for suppression of fluorenone defects to the optimisation of other classes of polymers.
Chemistry of Materials, Mar 15, 2019
ACS applied energy materials, Jan 27, 2023
Elsevier eBooks, 2016
The efficiency of LEDs based on conjugated polymers have been enhanced so that they are now comme... more The efficiency of LEDs based on conjugated polymers have been enhanced so that they are now commercially viable. This has occurred in large part by better synthetic design of emissive materials, based on an improved understanding of reaction mechanisms and how these permit defect formation through side reactions, thus enabling their prevention by modification of synthetic route or monomer structure. The performance of polymer-based solar cells has also been improved so that they are now close to commercialization. Again this has been due to synthetic design based on an enhanced knowledge of the underlying processes affecting efficiency, enabling a better understanding of structure-property relationships. The prospects for the future of both classes of device are assessed.
Angewandte Chemie, Feb 16, 1998
ABSTRACT
Australian Journal of Chemistry, 1990
Wiley-VCH Verlag GmbH & Co. KGaA eBooks, Jan 20, 2017
Current Organic Chemistry, Nov 1, 2010
ChemInform, Jun 22, 2010
ABSTRACT