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Papers by Barbara Kozub

10th MATBUD’2023 Scientific-Technical Conference

This article is an open access article distributed under the terms and conditions of the Creative... more This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY

Polymers for Advanced Technologies, 2015

The aim of the presented work is to show the influence of the various polymer matrices and the di... more The aim of the presented work is to show the influence of the various polymer matrices and the different amounts of the cellulose filler on the composites properties. Samples based on polypropylene, polystyrene, polyoxymethylene, acrylonitrile butadiene styrene, polyester resin, and polylactic acid with different contents of cellulose fibers were prepared by injection molding process. The mechanical and dielectric properties of these composites were studied in order to check whether investigated wood polymer composites fulfill requirements for their application in electrical devices. For all tested composites, a linear increase of modulus with cellulose content was observed. Addition of cellulose to the tested polymers significantly reduces strain at break. In the case of polypropylene and polyoxymethylene composites, the tensile strength increases with the content of the filler. For other materials, there is an inverse relationship, namely the addition of cellulose decreases the te...

Materials

This paper presents the effect of graphite addition on the pressing process and selected mechanic... more This paper presents the effect of graphite addition on the pressing process and selected mechanical properties of AISI 316L austenitic stainless steel. The graphite powders used in this study differed in the value of the specific surface area of the particles, which were 15 (micropowder), 350, and 400 m2/g (nanopowder). Mixtures with the addition of lubricants—stearic acid and Kenolube—were also created, for comparison purposes. The scope of the tests included compressibility of blends, measurements of the ejection force while removing the compacts from the die, micro-structural studies, a static tensile test, a three-point bending test, a Kc impact test, Rockwell hardness, and Vickers microhardness measurements. The study demonstrated that the addition of graphite nanopowder to the studied steel acts as a lubricant, providing a significant improvement in lubricity during the pressing process. Moreover, the addition of nanographite allowed for a significant increase in the mechanica...

Applied Sciences

Various types of coatings are applied to the surface of an object or substrate to improve surface... more Various types of coatings are applied to the surface of an object or substrate to improve surface properties or extend service life, which in turn is associated with cost reductions. The main objective of this study was to develop a technique for the additive application of foamed geopolymers to existing structures and vertical surfaces. The base material was a fly ash-based geopolymer modified with sand. Hydrogen peroxide and aluminum powder were used as foaming agents. In this study, the feasibility of using an air gun with variable nozzles to apply the layers of foamed geopolymers was assessed, and the effects of nozzle diameter and the spray gun’s operating pressure were analyzed. The next stage of the study was a visual assessment of the layering of the foamed material. The foamed geopolymer layering tests verified the occurrence of the foaming process, and the applied geopolymer surface showed a reasonably good adhesive bond with the vertical wall. In addition, in this paper, ...

10th MATBUD’2023 Scientific-Technical Conference

This article is an open access article distributed under the terms and conditions of the Creative... more This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY

Energies

Space missions will require the capability to build structures on site using local resources. Bef... more Space missions will require the capability to build structures on site using local resources. Before 2040, NASA and the European Space Agency want to ensure the possibility of a permanent human residence in shelters on the Moon or Mars. The article analyzed the state of the art in this area based on the literature research. It shows innovative and energy efficient solutions for manufacturing the lunar and Martian shelters based on geopolymer composites. Firstly, the possible materials solutions, with particular attention to the geopolymer composites, are discussed. Next, the previous research is presented, including work based on different kinds of simulants of lunar and Martian regolith. Then, a different approach for manufacturing technologies is presented and the advantages of 3D printing technology are clarified. Eventually, the challenges for further projects are discussed, including energy and cost efficiency problems.

Materialwissenschaft und Werkstofftechnik

Continuum Mechanics and Thermodynamics

Modern materials used in civil engineering should fulfill the numerous of requirements connected ... more Modern materials used in civil engineering should fulfill the numerous of requirements connected building standards, but not only. They should also be ecological and durable. Geopolymers are characterized by very good mechanical properties, high resistance against acids, chlorides and sulfates, high thermal resistance, and other properties confirmed by previous research. There is still a few amount of research connected with resistance, this materials for different environmental conditions, especially a lack of investigation connected with foamed geopolymers in this area. The main objective of the article is to analyze the possibilities of the development of new foamed geopolymer composites to increase durability, especially against degradation in corrosive water environments. This paper presents the influence on the mechanical properties of foamed geopolymer composites on the water environment. As raw materials, fly ash from the coal power plant ‘Skawina’ (located in: Skawina, Less...

Materials

The development of geopolymers is in line with the requirements of sustainable development. Creat... more The development of geopolymers is in line with the requirements of sustainable development. Creating a new type of material from various industrial and bio-based wastes and by-products can lead to reduced energy consumption, reduced waste generation, reduced global CO2 emissions, as well as reduced resource extraction of natural resources. In this study, geopolymer composites based on class F fly ash with the addition of fine quartz sand and ground walnut shells used as a substitute for sand were examined. The study focused on investigating the effects of different weight percentages of ground walnut shells and quartz sand on the density and strength properties, including compressive and flexural strength, thermal conductivity, efflorescence formation, and water absorption of the fly ash-based geopolymer composites. The microstructure of the studied geopolymers was also analyzed using a scanning electron microscope (SEM). It was observed that the addition of ground walnut shells con...

ABSTACT: Functionally Graded Materials (FGMs) are materials that can be characterized by the vari... more ABSTACT: Functionally Graded Materials (FGMs) are materials that can be characterized by the variation in composition and structure gradually over volume along at least one specific direction. These variations can occur as a result of the chosen manufacturing process and they cause corresponding changes in the properties of the material. Functionally graded materials can be designed for specific function and applications. Nowadays, the possibilities of using FGM seem to be almost limitless. According to the literature these materials can be used in engineering, optical, power, and even in nuclear physics and medicine applications. The problem of thermal residual stresses creation in sintered FGM material during cooling from sintering temperature was presented in this paper. The influence of transition zone layers number on the distribution of residual stress was analysed. The thermo-mechanical analysis was performed using the finite element method (FEM). During performed analyses th...

The paper presents results obtained from the complex destructive laboratory investigations on rea... more The paper presents results obtained from the complex destructive laboratory investigations on real pressure vessels’ carbon steels after long-term operation in the refinery industry. Tested materials contained structural defects. Detailed metallographic tests and static tensile tests were realized firstly. Then, complex tensile tests with acoustic emission signals registration, and material microstructure changes observation by light microscopy were conducted. The correlations between acoustic emission signals parameters and material microstructure damage during the tensile tests were developed. At the next stage, the destructive pressure tests with acoustic emission recording of real cylindrical pressure vessel were realized. The vessel has been operated in the refinery industry for 45 years. A lot of corrosion damages were present on the inner surface of the vessel shell as a result of long-term operation. The material’s microstructure of some shall plates was coarse-grained, whic...

Materials, 2021

This study examines foamed geopolymer composites based on fly ash from the Skawina coal-fired pow... more This study examines foamed geopolymer composites based on fly ash from the Skawina coal-fired power plant in Poland. The paper presents the effect of adding 3% and 5% by weight of glass wool waste on selected properties of foamed geopolymers. The scope of the tests carried out included density measurements, compressive and bending strength tests, measurements of the heat conduction coefficient, and the results of measurements of changes in thermal radiation in samples subjected to a temperature of 800 °C. The obtained results indicate that glass wool waste can be successfully used to lower the density and heat conduction coefficient of foamed geopolymer composites with a fly ash matrix. In addition, the results of changes in thermal radiation in the samples subjected to the temperature of 800 °C showed a positive effect of the addition of glass wool waste. Moreover, the introduction of the addition of glass wool waste made it possible to increase the compressive strength of the exam...

Materials

The paper deals with the possibility of using Phase Change Materials (PCM) in concretes and geopo... more The paper deals with the possibility of using Phase Change Materials (PCM) in concretes and geopolymer composites. The article presents the most important properties of PCM materials, their types, and their characteristics. A review of the latest research results related to their use in geopolymer materials is presented. The benefits of using PCM in building materials include the improvement of thermal comfort inside the building, and also the fact that the additive in the form of PCM reduces thermal gradients and unifies the temperature inside the concrete mix, which can reduce the risk of cracking. The paper also presents a critical analysis related to the feasibility of mass scale implementations of such composites. It was found that the use of PCM in sustainable construction is necessary and inevitable, and will bring a number of benefits, but it still requires large financial resources and time for more comprehensive research. Despite the fact that PCM materials have been known...

IOP Conference Series: Materials Science and Engineering

Materials

This study investigated the influence of the steel and melamine fibers hybridization on the flexu... more This study investigated the influence of the steel and melamine fibers hybridization on the flexural and compressive strength of a fly ash-based geopolymer. The applied reinforcement reduced the geopolymer brittleness. Currently, there are several types of polymer fibers available on the market. However, the authors did not come across information on the use of melamine fibers in geopolymer composites. Two systems of reinforcement for the composites were investigated in this work. Reinforcement with a single type of fiber and a hybrid system, i.e., two types of fibers. Both systems strengthened the base material. The research results showed the addition of melamine fibers as well as steel fibers increased the compressive and flexural strength in comparison to the plain matrix. In the case of a hybrid system, the achieved results showed a synergistic effect of the introduced fibers, which provided better strength results in relation to composites reinforced with a single type of fibe...

Materials

This paper presents the results of research on geopolymer composites based on fly ash with the ad... more This paper presents the results of research on geopolymer composites based on fly ash with the addition of melamine fibers in amounts of 0.5%, 1% and 2% by weight and, for comparison, without the addition of fibers. The melamine fibers used in the tests retain their melamine resin properties by 100% and are characterized by excellent acoustic and thermal insulation as well as excellent filtration. In addition, these fibers are nonflammable, resistant to chemicals, resistant to UV radiation, characterized by high temperature resistance and, most importantly, do not show thermal-related shrinking, melting and dripping. This paper presents the results of density measurements, compressive and flexural strength as well as the results of the measurement of thermal radiation changes in samples subjected to a temperature of 600 °C. The results indicate that melamine fibers can be used as geopolymer reinforcement. The best result was achieved for 0.5% by weight amount of reinforcement, appro...

Journal of Composites Science

Transformation of waste into resources is an important part of the circular economy. Nowadays, th... more Transformation of waste into resources is an important part of the circular economy. Nowadays, the recovery of materials in the most effective way is crucial for sustainable development. Composite materials offer great opportunities for product development and high performance in use, but their position in a circular economy system remains challenging, especially in terms of material recovery. Currently, the methods applied for recycling composites are not always effective. The aim of the article is to analyse the most important methods of material recovery from multilateral composites. The manuscript presents three case studies related to the recycling of products manufactured from composites: used tyres, wind turbine blades, and solar panels. It shows the advantages and disadvantages of currently applied methods for multilateral composite utilisation and presents further trends in composite recycling. The results show that increasing volumes of end-of-life composites have led to i...

Materials

The subject of this work was the study of processes occurring during sintering of water atomized ... more The subject of this work was the study of processes occurring during sintering of water atomized AISI 316L austenitic stainless steel powder modified by the addition of graphite nanoparticles. The main purpose of the work was to determine the effect of modification of the AISI 316L stainless steel austenitic powder by the addition of graphite nanopowder on the sintering kinetics and oxide reduction mechanism. The phenomena occurring during the sintering process and oxide reduction mechanisms were subjected to detailed characterizations. Mixtures with two types of nanopowder with a high BET (measurement technique of the specific surface area of materials based on Brunauer–Emmett–Teller theory) specific surface area of 350 and 400 m2/g and for comparison with graphite micropowder with a poorly developed BET specific surface area of 15 m2/g were tested. The conducted thermal analysis showed that the samples made of austenitic stainless steel doped with 0.2% and 0.3% by weight graphite ...

10th MATBUD’2023 Scientific-Technical Conference

This article is an open access article distributed under the terms and conditions of the Creative... more This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY

Polymers for Advanced Technologies, 2015

The aim of the presented work is to show the influence of the various polymer matrices and the di... more The aim of the presented work is to show the influence of the various polymer matrices and the different amounts of the cellulose filler on the composites properties. Samples based on polypropylene, polystyrene, polyoxymethylene, acrylonitrile butadiene styrene, polyester resin, and polylactic acid with different contents of cellulose fibers were prepared by injection molding process. The mechanical and dielectric properties of these composites were studied in order to check whether investigated wood polymer composites fulfill requirements for their application in electrical devices. For all tested composites, a linear increase of modulus with cellulose content was observed. Addition of cellulose to the tested polymers significantly reduces strain at break. In the case of polypropylene and polyoxymethylene composites, the tensile strength increases with the content of the filler. For other materials, there is an inverse relationship, namely the addition of cellulose decreases the te...

Materials

This paper presents the effect of graphite addition on the pressing process and selected mechanic... more This paper presents the effect of graphite addition on the pressing process and selected mechanical properties of AISI 316L austenitic stainless steel. The graphite powders used in this study differed in the value of the specific surface area of the particles, which were 15 (micropowder), 350, and 400 m2/g (nanopowder). Mixtures with the addition of lubricants—stearic acid and Kenolube—were also created, for comparison purposes. The scope of the tests included compressibility of blends, measurements of the ejection force while removing the compacts from the die, micro-structural studies, a static tensile test, a three-point bending test, a Kc impact test, Rockwell hardness, and Vickers microhardness measurements. The study demonstrated that the addition of graphite nanopowder to the studied steel acts as a lubricant, providing a significant improvement in lubricity during the pressing process. Moreover, the addition of nanographite allowed for a significant increase in the mechanica...

Applied Sciences

Various types of coatings are applied to the surface of an object or substrate to improve surface... more Various types of coatings are applied to the surface of an object or substrate to improve surface properties or extend service life, which in turn is associated with cost reductions. The main objective of this study was to develop a technique for the additive application of foamed geopolymers to existing structures and vertical surfaces. The base material was a fly ash-based geopolymer modified with sand. Hydrogen peroxide and aluminum powder were used as foaming agents. In this study, the feasibility of using an air gun with variable nozzles to apply the layers of foamed geopolymers was assessed, and the effects of nozzle diameter and the spray gun’s operating pressure were analyzed. The next stage of the study was a visual assessment of the layering of the foamed material. The foamed geopolymer layering tests verified the occurrence of the foaming process, and the applied geopolymer surface showed a reasonably good adhesive bond with the vertical wall. In addition, in this paper, ...

10th MATBUD’2023 Scientific-Technical Conference

This article is an open access article distributed under the terms and conditions of the Creative... more This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY

Energies

Space missions will require the capability to build structures on site using local resources. Bef... more Space missions will require the capability to build structures on site using local resources. Before 2040, NASA and the European Space Agency want to ensure the possibility of a permanent human residence in shelters on the Moon or Mars. The article analyzed the state of the art in this area based on the literature research. It shows innovative and energy efficient solutions for manufacturing the lunar and Martian shelters based on geopolymer composites. Firstly, the possible materials solutions, with particular attention to the geopolymer composites, are discussed. Next, the previous research is presented, including work based on different kinds of simulants of lunar and Martian regolith. Then, a different approach for manufacturing technologies is presented and the advantages of 3D printing technology are clarified. Eventually, the challenges for further projects are discussed, including energy and cost efficiency problems.

Materialwissenschaft und Werkstofftechnik

Continuum Mechanics and Thermodynamics

Modern materials used in civil engineering should fulfill the numerous of requirements connected ... more Modern materials used in civil engineering should fulfill the numerous of requirements connected building standards, but not only. They should also be ecological and durable. Geopolymers are characterized by very good mechanical properties, high resistance against acids, chlorides and sulfates, high thermal resistance, and other properties confirmed by previous research. There is still a few amount of research connected with resistance, this materials for different environmental conditions, especially a lack of investigation connected with foamed geopolymers in this area. The main objective of the article is to analyze the possibilities of the development of new foamed geopolymer composites to increase durability, especially against degradation in corrosive water environments. This paper presents the influence on the mechanical properties of foamed geopolymer composites on the water environment. As raw materials, fly ash from the coal power plant ‘Skawina’ (located in: Skawina, Less...

Materials

The development of geopolymers is in line with the requirements of sustainable development. Creat... more The development of geopolymers is in line with the requirements of sustainable development. Creating a new type of material from various industrial and bio-based wastes and by-products can lead to reduced energy consumption, reduced waste generation, reduced global CO2 emissions, as well as reduced resource extraction of natural resources. In this study, geopolymer composites based on class F fly ash with the addition of fine quartz sand and ground walnut shells used as a substitute for sand were examined. The study focused on investigating the effects of different weight percentages of ground walnut shells and quartz sand on the density and strength properties, including compressive and flexural strength, thermal conductivity, efflorescence formation, and water absorption of the fly ash-based geopolymer composites. The microstructure of the studied geopolymers was also analyzed using a scanning electron microscope (SEM). It was observed that the addition of ground walnut shells con...

ABSTACT: Functionally Graded Materials (FGMs) are materials that can be characterized by the vari... more ABSTACT: Functionally Graded Materials (FGMs) are materials that can be characterized by the variation in composition and structure gradually over volume along at least one specific direction. These variations can occur as a result of the chosen manufacturing process and they cause corresponding changes in the properties of the material. Functionally graded materials can be designed for specific function and applications. Nowadays, the possibilities of using FGM seem to be almost limitless. According to the literature these materials can be used in engineering, optical, power, and even in nuclear physics and medicine applications. The problem of thermal residual stresses creation in sintered FGM material during cooling from sintering temperature was presented in this paper. The influence of transition zone layers number on the distribution of residual stress was analysed. The thermo-mechanical analysis was performed using the finite element method (FEM). During performed analyses th...

The paper presents results obtained from the complex destructive laboratory investigations on rea... more The paper presents results obtained from the complex destructive laboratory investigations on real pressure vessels’ carbon steels after long-term operation in the refinery industry. Tested materials contained structural defects. Detailed metallographic tests and static tensile tests were realized firstly. Then, complex tensile tests with acoustic emission signals registration, and material microstructure changes observation by light microscopy were conducted. The correlations between acoustic emission signals parameters and material microstructure damage during the tensile tests were developed. At the next stage, the destructive pressure tests with acoustic emission recording of real cylindrical pressure vessel were realized. The vessel has been operated in the refinery industry for 45 years. A lot of corrosion damages were present on the inner surface of the vessel shell as a result of long-term operation. The material’s microstructure of some shall plates was coarse-grained, whic...

Materials, 2021

This study examines foamed geopolymer composites based on fly ash from the Skawina coal-fired pow... more This study examines foamed geopolymer composites based on fly ash from the Skawina coal-fired power plant in Poland. The paper presents the effect of adding 3% and 5% by weight of glass wool waste on selected properties of foamed geopolymers. The scope of the tests carried out included density measurements, compressive and bending strength tests, measurements of the heat conduction coefficient, and the results of measurements of changes in thermal radiation in samples subjected to a temperature of 800 °C. The obtained results indicate that glass wool waste can be successfully used to lower the density and heat conduction coefficient of foamed geopolymer composites with a fly ash matrix. In addition, the results of changes in thermal radiation in the samples subjected to the temperature of 800 °C showed a positive effect of the addition of glass wool waste. Moreover, the introduction of the addition of glass wool waste made it possible to increase the compressive strength of the exam...

Materials

The paper deals with the possibility of using Phase Change Materials (PCM) in concretes and geopo... more The paper deals with the possibility of using Phase Change Materials (PCM) in concretes and geopolymer composites. The article presents the most important properties of PCM materials, their types, and their characteristics. A review of the latest research results related to their use in geopolymer materials is presented. The benefits of using PCM in building materials include the improvement of thermal comfort inside the building, and also the fact that the additive in the form of PCM reduces thermal gradients and unifies the temperature inside the concrete mix, which can reduce the risk of cracking. The paper also presents a critical analysis related to the feasibility of mass scale implementations of such composites. It was found that the use of PCM in sustainable construction is necessary and inevitable, and will bring a number of benefits, but it still requires large financial resources and time for more comprehensive research. Despite the fact that PCM materials have been known...

IOP Conference Series: Materials Science and Engineering

Materials

This study investigated the influence of the steel and melamine fibers hybridization on the flexu... more This study investigated the influence of the steel and melamine fibers hybridization on the flexural and compressive strength of a fly ash-based geopolymer. The applied reinforcement reduced the geopolymer brittleness. Currently, there are several types of polymer fibers available on the market. However, the authors did not come across information on the use of melamine fibers in geopolymer composites. Two systems of reinforcement for the composites were investigated in this work. Reinforcement with a single type of fiber and a hybrid system, i.e., two types of fibers. Both systems strengthened the base material. The research results showed the addition of melamine fibers as well as steel fibers increased the compressive and flexural strength in comparison to the plain matrix. In the case of a hybrid system, the achieved results showed a synergistic effect of the introduced fibers, which provided better strength results in relation to composites reinforced with a single type of fibe...

Materials

This paper presents the results of research on geopolymer composites based on fly ash with the ad... more This paper presents the results of research on geopolymer composites based on fly ash with the addition of melamine fibers in amounts of 0.5%, 1% and 2% by weight and, for comparison, without the addition of fibers. The melamine fibers used in the tests retain their melamine resin properties by 100% and are characterized by excellent acoustic and thermal insulation as well as excellent filtration. In addition, these fibers are nonflammable, resistant to chemicals, resistant to UV radiation, characterized by high temperature resistance and, most importantly, do not show thermal-related shrinking, melting and dripping. This paper presents the results of density measurements, compressive and flexural strength as well as the results of the measurement of thermal radiation changes in samples subjected to a temperature of 600 °C. The results indicate that melamine fibers can be used as geopolymer reinforcement. The best result was achieved for 0.5% by weight amount of reinforcement, appro...

Journal of Composites Science

Transformation of waste into resources is an important part of the circular economy. Nowadays, th... more Transformation of waste into resources is an important part of the circular economy. Nowadays, the recovery of materials in the most effective way is crucial for sustainable development. Composite materials offer great opportunities for product development and high performance in use, but their position in a circular economy system remains challenging, especially in terms of material recovery. Currently, the methods applied for recycling composites are not always effective. The aim of the article is to analyse the most important methods of material recovery from multilateral composites. The manuscript presents three case studies related to the recycling of products manufactured from composites: used tyres, wind turbine blades, and solar panels. It shows the advantages and disadvantages of currently applied methods for multilateral composite utilisation and presents further trends in composite recycling. The results show that increasing volumes of end-of-life composites have led to i...

Materials

The subject of this work was the study of processes occurring during sintering of water atomized ... more The subject of this work was the study of processes occurring during sintering of water atomized AISI 316L austenitic stainless steel powder modified by the addition of graphite nanoparticles. The main purpose of the work was to determine the effect of modification of the AISI 316L stainless steel austenitic powder by the addition of graphite nanopowder on the sintering kinetics and oxide reduction mechanism. The phenomena occurring during the sintering process and oxide reduction mechanisms were subjected to detailed characterizations. Mixtures with two types of nanopowder with a high BET (measurement technique of the specific surface area of materials based on Brunauer–Emmett–Teller theory) specific surface area of 350 and 400 m2/g and for comparison with graphite micropowder with a poorly developed BET specific surface area of 15 m2/g were tested. The conducted thermal analysis showed that the samples made of austenitic stainless steel doped with 0.2% and 0.3% by weight graphite ...