Bruce Logan - Academia.edu (original) (raw)
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Papers by Bruce Logan
Applied and Environmental Microbiology, Dec 1, 2008
Environmental science, 2018
Applied and Environmental Microbiology, Dec 15, 2011
Proceedings of the National Academy of Sciences of the United States of America, Sep 19, 2011
Nature Reviews Microbiology, Mar 7, 2019
Chemical Engineering Journal, Nov 1, 2018
Energy and Environmental Science, 2017
Bioresource Technology, 2020
Journal of Power Sources, 2020
Chemical Engineering Journal, 2021
Electrochimica Acta, 2020
Journal of Power Sources, 2020
Environmental Science & Technology, 2019
Environmental Science & Technology, 2018
Environmental Science: Water Research & Technology, 2018
Long-term operation of wastewater-fed, microbial fuel cells (MFCs) with cathodes made of activate... more Long-term operation of wastewater-fed, microbial fuel cells (MFCs) with cathodes made of activated carbon and stainless steel (SS) current collectors can result in decreased performance due to cathode fouling.
Water research, Jan 10, 2018
To scale up microbial fuel cells (MFCs), larger cathodes need to be developed that can use air di... more To scale up microbial fuel cells (MFCs), larger cathodes need to be developed that can use air directly, rather than dissolved oxygen, and have good electrochemical performance. A new type of cathode design was examined here that uses a "window-pane" approach with fifteen smaller cathodes welded to a single conductive metal sheet to maintain good electrical conductivity across the cathode with an increase in total area. Abiotic electrochemical tests were conducted to evaluate the impact of the cathode size (exposed areas of 7 cm, 33 cm, and 6200 cm) on performance for all cathodes having the same active catalyst material. Increasing the size of the exposed area of the electrodes to the electrolyte from 7 cm to 33 cm (a single cathode panel) decreased the cathode potential by 5%, and a further increase in size to 6200 cm using the multi-panel cathode reduced the electrode potential by 55% (at 0.6 A m), in a 50 mM phosphate buffer solution (PBS). In 85 L MFC tests with the l...
Bioresource technology, 2017
Metal-organic framework (MOF) on activated carbon (AC) enhanced the performance of cathodes but l... more Metal-organic framework (MOF) on activated carbon (AC) enhanced the performance of cathodes but longevity needs to be considered in the presence of metal chelators or ligands, such as phosphate, present in wastewaters. MOF catalysts on AC initially produced 2.78±0.08Wm(-2), but power decreased by 26% after eight weeks in microbial fuel cells using a 50mM phosphate buffer (PBS) and acetate due to decreased cathode performance. However, power was still 41% larger than that of the control AC (no MOF). Power generation using domestic wastewater was initially 0.73±0.01Wm(-2), and decreased by 21% over time, with power 53% larger than previous reports, although changes in wastewater composition were a factor in performance. Adding phosphate salts to the wastewater did not affect the catalyst performance over time. While MOF catalysts are therefore initially adversely affected by chelators, performance remains enhanced compared to plain AC.
Report Nr.: Schriften …, 2010
Journal of Chemical Technology & Biotechnology, 2013
Non‐corrosive, carbon‐based materials are usually used as anodes in microbial fuel cells (MFCs). ... more Non‐corrosive, carbon‐based materials are usually used as anodes in microbial fuel cells (MFCs). In some cases, however, metals have been used that can corrode (e.g. copper) or that are corrosion resistant (e.g. stainless steel, SS). Corrosion could increase current through galvanic (abiotic) current production or by increasing exposed surface area, or decrease current due to generation of toxic products from corrosion. In order to directly examine the effects of using corrodible metal anodes, MFCs with Cu were compared with reactors using SS and carbon cloth anodes. MFCs with Cu anodes initially showed high current generation similar to abiotic controls, but subsequently they produced little power (2 mW m‐2). Higher power was produced with microbes using SS (12 mW m‐2) or carbon cloth (880 mW m‐2) anodes, with no power generated by abiotic controls. These results demonstrate that copper is an unsuitable anode material, due to corrosion and likely copper toxicity to microorganisms. ...
Applied and Environmental Microbiology, Dec 1, 2008
Environmental science, 2018
Applied and Environmental Microbiology, Dec 15, 2011
Proceedings of the National Academy of Sciences of the United States of America, Sep 19, 2011
Nature Reviews Microbiology, Mar 7, 2019
Chemical Engineering Journal, Nov 1, 2018
Energy and Environmental Science, 2017
Bioresource Technology, 2020
Journal of Power Sources, 2020
Chemical Engineering Journal, 2021
Electrochimica Acta, 2020
Journal of Power Sources, 2020
Environmental Science & Technology, 2019
Environmental Science & Technology, 2018
Environmental Science: Water Research & Technology, 2018
Long-term operation of wastewater-fed, microbial fuel cells (MFCs) with cathodes made of activate... more Long-term operation of wastewater-fed, microbial fuel cells (MFCs) with cathodes made of activated carbon and stainless steel (SS) current collectors can result in decreased performance due to cathode fouling.
Water research, Jan 10, 2018
To scale up microbial fuel cells (MFCs), larger cathodes need to be developed that can use air di... more To scale up microbial fuel cells (MFCs), larger cathodes need to be developed that can use air directly, rather than dissolved oxygen, and have good electrochemical performance. A new type of cathode design was examined here that uses a "window-pane" approach with fifteen smaller cathodes welded to a single conductive metal sheet to maintain good electrical conductivity across the cathode with an increase in total area. Abiotic electrochemical tests were conducted to evaluate the impact of the cathode size (exposed areas of 7 cm, 33 cm, and 6200 cm) on performance for all cathodes having the same active catalyst material. Increasing the size of the exposed area of the electrodes to the electrolyte from 7 cm to 33 cm (a single cathode panel) decreased the cathode potential by 5%, and a further increase in size to 6200 cm using the multi-panel cathode reduced the electrode potential by 55% (at 0.6 A m), in a 50 mM phosphate buffer solution (PBS). In 85 L MFC tests with the l...
Bioresource technology, 2017
Metal-organic framework (MOF) on activated carbon (AC) enhanced the performance of cathodes but l... more Metal-organic framework (MOF) on activated carbon (AC) enhanced the performance of cathodes but longevity needs to be considered in the presence of metal chelators or ligands, such as phosphate, present in wastewaters. MOF catalysts on AC initially produced 2.78±0.08Wm(-2), but power decreased by 26% after eight weeks in microbial fuel cells using a 50mM phosphate buffer (PBS) and acetate due to decreased cathode performance. However, power was still 41% larger than that of the control AC (no MOF). Power generation using domestic wastewater was initially 0.73±0.01Wm(-2), and decreased by 21% over time, with power 53% larger than previous reports, although changes in wastewater composition were a factor in performance. Adding phosphate salts to the wastewater did not affect the catalyst performance over time. While MOF catalysts are therefore initially adversely affected by chelators, performance remains enhanced compared to plain AC.
Report Nr.: Schriften …, 2010
Journal of Chemical Technology & Biotechnology, 2013
Non‐corrosive, carbon‐based materials are usually used as anodes in microbial fuel cells (MFCs). ... more Non‐corrosive, carbon‐based materials are usually used as anodes in microbial fuel cells (MFCs). In some cases, however, metals have been used that can corrode (e.g. copper) or that are corrosion resistant (e.g. stainless steel, SS). Corrosion could increase current through galvanic (abiotic) current production or by increasing exposed surface area, or decrease current due to generation of toxic products from corrosion. In order to directly examine the effects of using corrodible metal anodes, MFCs with Cu were compared with reactors using SS and carbon cloth anodes. MFCs with Cu anodes initially showed high current generation similar to abiotic controls, but subsequently they produced little power (2 mW m‐2). Higher power was produced with microbes using SS (12 mW m‐2) or carbon cloth (880 mW m‐2) anodes, with no power generated by abiotic controls. These results demonstrate that copper is an unsuitable anode material, due to corrosion and likely copper toxicity to microorganisms. ...