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Research paper thumbnail of Supercritical CO2 extraction of phenolic compounds from Baccharis dracunculifolia

Extracts from Baccharis dracunculifolia leaves were obtained using the following solvents: superc... more Extracts from Baccharis dracunculifolia leaves were obtained using the following solvents: supercritical carbon dioxide (SC-CO 2 ), ethanol and methanol. Supercritical extraction was carried out at temperatures of 40, 50 and 60 • C and pressures of 20, 30 and 40 MPa. Four phenolic compounds were analysed in the extracts by high-performance liquid chromatography: 3,5-diprenyl-4-hydroxycinnamic acid (DHCA or artepillin C); 3-prenyl-4-hydroxycinnamic acid (PHCA); 4-hydroxycinnamic acid (p-coumaric acid) and 4-methoxy-3,5,7-trihydroxyflavone (kaempferide). The global extraction yields (X 0 ) obtained by the conventional methods with ethanol and methanol were higher than those obtained by SC-CO 2 . However on analysing the components of interest extracted at 60 • C and 40 MPa, the extraction yields of kaempferide, DHCA and PHCA were 156%, 98% and 64% higher, respectively, than in the ethanolic extracts. Only the p-coumaric acid extraction yield was better when extracted using the conventional method.

Research paper thumbnail of Supercritical CO2 extraction of phenolic compounds from Baccharis dracunculifolia

The Journal of Supercritical Fluids, 2008

Extracts from Baccharis dracunculifolia leaves were obtained using the following solvents: superc... more Extracts from Baccharis dracunculifolia leaves were obtained using the following solvents: supercritical carbon dioxide (SC-CO 2 ), ethanol and methanol. Supercritical extraction was carried out at temperatures of 40, 50 and 60 • C and pressures of 20, 30 and 40 MPa. Four phenolic compounds were analysed in the extracts by high-performance liquid chromatography: 3,5-diprenyl-4-hydroxycinnamic acid (DHCA or artepillin C); 3-prenyl-4-hydroxycinnamic acid (PHCA); 4-hydroxycinnamic acid (p-coumaric acid) and 4-methoxy-3,5,7-trihydroxyflavone (kaempferide). The global extraction yields (X 0 ) obtained by the conventional methods with ethanol and methanol were higher than those obtained by SC-CO 2 . However on analysing the components of interest extracted at 60 • C and 40 MPa, the extraction yields of kaempferide, DHCA and PHCA were 156%, 98% and 64% higher, respectively, than in the ethanolic extracts. Only the p-coumaric acid extraction yield was better when extracted using the conventional method.

Research paper thumbnail of Supercritical CO2 extraction of omega-3 rich oil from Sacha inchi (Plukenetia volubilis L.) seeds

The Journal of Supercritical Fluids, 2009

Supercritical carbon dioxide (SC-CO 2 ) was employed to extract omega-3 rich oil from Sacha inchi... more Supercritical carbon dioxide (SC-CO 2 ) was employed to extract omega-3 rich oil from Sacha inchi (Plukenetia volubilis L.) seeds and partially defatted cake. For ground seeds, the supercritical extraction was carried out at temperatures of 40, 50 and 60 • C and pressures of 300 and 400 bar, and for the cold pressed partially defatted cake, the extraction was carried out with 300 bar at 40 • C and with 400 bar at 60 • C. The global extraction yields (X 0 ), oil solubility, fatty acid composition of the oil and tocopherol content were determined. The seed samples used in this work contained 54.3% oil, of which 50.5% was linoleinc acid (-3). The maximum extraction recovery for the seeds as 92% at 400 bar and 60 • C, but on one occasion a recovery of 99.1% oil was obtained when cold pressed extraction was employed, followed by supercritical extraction at 400 bar and 60 • C. A high tocopherol content of about 2-3 g/kg of oil was obtained.

Research paper thumbnail of Supercritical CO2 extraction of phenolic compounds from Baccharis dracunculifolia

Extracts from Baccharis dracunculifolia leaves were obtained using the following solvents: superc... more Extracts from Baccharis dracunculifolia leaves were obtained using the following solvents: supercritical carbon dioxide (SC-CO 2 ), ethanol and methanol. Supercritical extraction was carried out at temperatures of 40, 50 and 60 • C and pressures of 20, 30 and 40 MPa. Four phenolic compounds were analysed in the extracts by high-performance liquid chromatography: 3,5-diprenyl-4-hydroxycinnamic acid (DHCA or artepillin C); 3-prenyl-4-hydroxycinnamic acid (PHCA); 4-hydroxycinnamic acid (p-coumaric acid) and 4-methoxy-3,5,7-trihydroxyflavone (kaempferide). The global extraction yields (X 0 ) obtained by the conventional methods with ethanol and methanol were higher than those obtained by SC-CO 2 . However on analysing the components of interest extracted at 60 • C and 40 MPa, the extraction yields of kaempferide, DHCA and PHCA were 156%, 98% and 64% higher, respectively, than in the ethanolic extracts. Only the p-coumaric acid extraction yield was better when extracted using the conventional method.

Research paper thumbnail of Supercritical CO2 extraction of phenolic compounds from Baccharis dracunculifolia

The Journal of Supercritical Fluids, 2008

Extracts from Baccharis dracunculifolia leaves were obtained using the following solvents: superc... more Extracts from Baccharis dracunculifolia leaves were obtained using the following solvents: supercritical carbon dioxide (SC-CO 2 ), ethanol and methanol. Supercritical extraction was carried out at temperatures of 40, 50 and 60 • C and pressures of 20, 30 and 40 MPa. Four phenolic compounds were analysed in the extracts by high-performance liquid chromatography: 3,5-diprenyl-4-hydroxycinnamic acid (DHCA or artepillin C); 3-prenyl-4-hydroxycinnamic acid (PHCA); 4-hydroxycinnamic acid (p-coumaric acid) and 4-methoxy-3,5,7-trihydroxyflavone (kaempferide). The global extraction yields (X 0 ) obtained by the conventional methods with ethanol and methanol were higher than those obtained by SC-CO 2 . However on analysing the components of interest extracted at 60 • C and 40 MPa, the extraction yields of kaempferide, DHCA and PHCA were 156%, 98% and 64% higher, respectively, than in the ethanolic extracts. Only the p-coumaric acid extraction yield was better when extracted using the conventional method.

Research paper thumbnail of Supercritical CO2 extraction of omega-3 rich oil from Sacha inchi (Plukenetia volubilis L.) seeds

The Journal of Supercritical Fluids, 2009

Supercritical carbon dioxide (SC-CO 2 ) was employed to extract omega-3 rich oil from Sacha inchi... more Supercritical carbon dioxide (SC-CO 2 ) was employed to extract omega-3 rich oil from Sacha inchi (Plukenetia volubilis L.) seeds and partially defatted cake. For ground seeds, the supercritical extraction was carried out at temperatures of 40, 50 and 60 • C and pressures of 300 and 400 bar, and for the cold pressed partially defatted cake, the extraction was carried out with 300 bar at 40 • C and with 400 bar at 60 • C. The global extraction yields (X 0 ), oil solubility, fatty acid composition of the oil and tocopherol content were determined. The seed samples used in this work contained 54.3% oil, of which 50.5% was linoleinc acid (-3). The maximum extraction recovery for the seeds as 92% at 400 bar and 60 • C, but on one occasion a recovery of 99.1% oil was obtained when cold pressed extraction was employed, followed by supercritical extraction at 400 bar and 60 • C. A high tocopherol content of about 2-3 g/kg of oil was obtained.

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