Carlos A N D Castro (original) (raw)
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Papers by Carlos A N D Castro
Fluid Phase Equilibria, 2014
International Journal of Refrigeration, 2011
International Journal of Refrigeration, 2011
Industrial & Engineering Chemistry Research, 2018
International Journal of Thermophysics, 2016
TrAC Trends in Analytical Chemistry, 2001
Quality represents a cornerstone in the credibility of analytical laboratories. Their performance... more Quality represents a cornerstone in the credibility of analytical laboratories. Their performance must be systematically checked through participation in proficiency testing schemes, co-ordinated by independent providers. These establish the organisational arrangements and the interpretation of results for evaluating the technical competence of the laboratories. The EPTIS database (European Proficiency Testing Information System) aims to establish an important link between all
For a Better Quality of Life. 19th International Congress of Refrigeration., Aug 20, 1995
Journal of Physical and Chemical Reference Data, Jul 1, 1986
Journal of Nanofluids, Oct 1, 2017
Fluid Phase Equilibria, 1998
Fluid Phase Equilibria, Jun 1, 1997
The Journal of Chemical Thermodynamics, Nov 1, 2020
The Journal of Chemical Thermodynamics, Jul 1, 2019
Journal of Chemical & Engineering Data, Nov 30, 2015
The properties of mixtures of ionic liquids and water are very important for many applications. O... more The properties of mixtures of ionic liquids and water are very important for many applications. One key application is their use as absorbents in absorption refrigeration cycles, replacing water + LIBr and water + ammonia systems. As a possible mixture, the system [Bmpyr][dca] + H2O was studied, as the available data are scarce. Measurements of density, speed of sound, viscosity, and surface tension of [Bmpyr][dca] + H2O were made for seven molar compositions between 288.15 K and 333.15 K. The uncertainty of the density values is 0.07 kg·m–3, while that of the speed of sound was found to be 0.3 m·s–1. Viscosity measurements have an uncertainty of 1.4 %, while the surface tension values have an uncertainty lower than ±0.6 mN·m–1. All the measurement were measured at atmospheric pressure and are reported to 0.1 MPa ± 1 kPa. From density data, isobaric molar expansions were calculated and from combined density and speed of sound data, isentropic molar compressions were also obtained. Finally, excess molar vo...
Journal of Molecular Liquids, Sep 1, 2021
Abstract The viscosity of four in-house-made ionic liquids, 1-butyl-3-methyl-imidazolium bis(trif... more Abstract The viscosity of four in-house-made ionic liquids, 1-butyl-3-methyl-imidazolium bis(trifluoromethanesulfonylimide), ([C4mim][(CF3SO2)2N]), CAS RN 174899–83-3, 1-butyl-3-methyl-imidazolium dicyanamide, ([C4mim][N(CN)2]), CAS RN 448245–52-1, 1-ethyl-3-methyl-imidazolium ethylsulphate, ([C2mim][C2H5SO4]), CAS RN 342573–75-5 and methyltrialkyl(C8,C8,C10)ammonium dicyanamide [Aliquat][N(CN)2], CAS RN 63393–96-4, was measured in the temperature range 283.15 K − 373.15 K, at P = 0.1 MPa. Data obtained with an absolute relative uncertainty of Ur (η) = 0.02 was compared with available literature data for all ionic liquids, except for [Aliquat][N(CN)2], data herein presented for the first time. Both the Vogel-Tammann-Fulcher and IUPAC/IAPWS equations were applied to correlate the measured viscosity data as a function of temperature, the latter being more accurate. Values of η (298.15 K) are recommended for each ionic liquid studied. The viscosities of the different ionic liquids are discussed, considering their chemical structure differences.
Fluid Phase Equilibria, 2014
International Journal of Refrigeration, 2011
International Journal of Refrigeration, 2011
Industrial & Engineering Chemistry Research, 2018
International Journal of Thermophysics, 2016
TrAC Trends in Analytical Chemistry, 2001
Quality represents a cornerstone in the credibility of analytical laboratories. Their performance... more Quality represents a cornerstone in the credibility of analytical laboratories. Their performance must be systematically checked through participation in proficiency testing schemes, co-ordinated by independent providers. These establish the organisational arrangements and the interpretation of results for evaluating the technical competence of the laboratories. The EPTIS database (European Proficiency Testing Information System) aims to establish an important link between all
For a Better Quality of Life. 19th International Congress of Refrigeration., Aug 20, 1995
Journal of Physical and Chemical Reference Data, Jul 1, 1986
Journal of Nanofluids, Oct 1, 2017
Fluid Phase Equilibria, 1998
Fluid Phase Equilibria, Jun 1, 1997
The Journal of Chemical Thermodynamics, Nov 1, 2020
The Journal of Chemical Thermodynamics, Jul 1, 2019
Journal of Chemical & Engineering Data, Nov 30, 2015
The properties of mixtures of ionic liquids and water are very important for many applications. O... more The properties of mixtures of ionic liquids and water are very important for many applications. One key application is their use as absorbents in absorption refrigeration cycles, replacing water + LIBr and water + ammonia systems. As a possible mixture, the system [Bmpyr][dca] + H2O was studied, as the available data are scarce. Measurements of density, speed of sound, viscosity, and surface tension of [Bmpyr][dca] + H2O were made for seven molar compositions between 288.15 K and 333.15 K. The uncertainty of the density values is 0.07 kg·m–3, while that of the speed of sound was found to be 0.3 m·s–1. Viscosity measurements have an uncertainty of 1.4 %, while the surface tension values have an uncertainty lower than ±0.6 mN·m–1. All the measurement were measured at atmospheric pressure and are reported to 0.1 MPa ± 1 kPa. From density data, isobaric molar expansions were calculated and from combined density and speed of sound data, isentropic molar compressions were also obtained. Finally, excess molar vo...
Journal of Molecular Liquids, Sep 1, 2021
Abstract The viscosity of four in-house-made ionic liquids, 1-butyl-3-methyl-imidazolium bis(trif... more Abstract The viscosity of four in-house-made ionic liquids, 1-butyl-3-methyl-imidazolium bis(trifluoromethanesulfonylimide), ([C4mim][(CF3SO2)2N]), CAS RN 174899–83-3, 1-butyl-3-methyl-imidazolium dicyanamide, ([C4mim][N(CN)2]), CAS RN 448245–52-1, 1-ethyl-3-methyl-imidazolium ethylsulphate, ([C2mim][C2H5SO4]), CAS RN 342573–75-5 and methyltrialkyl(C8,C8,C10)ammonium dicyanamide [Aliquat][N(CN)2], CAS RN 63393–96-4, was measured in the temperature range 283.15 K − 373.15 K, at P = 0.1 MPa. Data obtained with an absolute relative uncertainty of Ur (η) = 0.02 was compared with available literature data for all ionic liquids, except for [Aliquat][N(CN)2], data herein presented for the first time. Both the Vogel-Tammann-Fulcher and IUPAC/IAPWS equations were applied to correlate the measured viscosity data as a function of temperature, the latter being more accurate. Values of η (298.15 K) are recommended for each ionic liquid studied. The viscosities of the different ionic liquids are discussed, considering their chemical structure differences.