Chau Nguyen Kim - Academia.edu (original) (raw)

Chau Nguyen Kim

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Papers by Chau Nguyen Kim

Research paper thumbnail of Preparation of polypyrrole/sulfonated-poly(2,6-dimethyl-1,4-phenylene oxide) conducting composites and their electrical properties

Synthetic Metals, 2004

The conducting composites were prepared by chemical oxidative polymerization using pyrrole and po... more The conducting composites were prepared by chemical oxidative polymerization using pyrrole and poly(2,6-dimethyl-1,4-phenylene oxide) (PPO) or sulfonated-poly(2,6-dimethyl-1,4-phenylene oxide) (SPPO) in chloroform. The pyrrole was protonated and polymerized using iron(III) chloride (FeCl 3). The electrical conductivities of PPy/SPPO composites were increased up to 1 order with the amount of PPy compared to PPy/PPO composites. The introduction of sulfuric group to PPO results in the Coulombic interaction between each phase of composites. As a result, the electrical conductivities might be increased due to the effect of miscibility between each phase. The electrical conductivity of PPy/SPPO composite was increased up to 2.14 S/cm with amount of 25 wt.% PPy. The performance of charge-discharge of PPy/SPPO electrode was much higher than that of PPy/PVdF electrode because SPPO act as a dopant as well as a binder.

Research paper thumbnail of Preparation of polypyrrole/sulfonated-poly(2,6-dimethyl-1,4-phenylene oxide) conducting composites and their electrical properties

Synthetic Metals, 2004

The conducting composites were prepared by chemical oxidative polymerization using pyrrole and po... more The conducting composites were prepared by chemical oxidative polymerization using pyrrole and poly(2,6-dimethyl-1,4-phenylene oxide) (PPO) or sulfonated-poly(2,6-dimethyl-1,4-phenylene oxide) (SPPO) in chloroform. The pyrrole was protonated and polymerized using iron(III) chloride (FeCl 3). The electrical conductivities of PPy/SPPO composites were increased up to 1 order with the amount of PPy compared to PPy/PPO composites. The introduction of sulfuric group to PPO results in the Coulombic interaction between each phase of composites. As a result, the electrical conductivities might be increased due to the effect of miscibility between each phase. The electrical conductivity of PPy/SPPO composite was increased up to 2.14 S/cm with amount of 25 wt.% PPy. The performance of charge-discharge of PPy/SPPO electrode was much higher than that of PPy/PVdF electrode because SPPO act as a dopant as well as a binder.

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