Claudia Felser - Academia.edu (original) (raw)
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Papers by Claudia Felser
ABSTRACT In this work, results of hard X-ray photoelectron spectroscopy (HAXPES) of Heusler compo... more ABSTRACT In this work, results of hard X-ray photoelectron spectroscopy (HAXPES) of Heusler compounds and new materials for spintronics are presented. The class of Heusler materials includes some interesting half-metallic and ferromagnetic properties that were predicted by theory. HAXPES allows a direct comparison of the measured and the calculated electronic structure. Valence band spectroscopy of bulk materials by HAXPES is illustrated for the case of the half-metallic ferromagnet Co2MnGe. The feasibility of HAXPES to explore the valence band electronic structure in deeply buried metallic layers is demonstrated for buried Co2MnSi films. The films exhibit the same valence density of states as bulk samples and confirm the promise of an epitaxial, single-crystalline Co2-based Heusler compound film as a ferromagnetic electrode for spintronics devices. The study of complete CoFe(B)/MgO/CoFe(B) tunneling junctions demonstrates the capability of HAXPES to explore the electronic structure in deeply buried layers in a non-destructive way. The improvement of the TMR by annealing of the junction is explained by an improvement of the structure together with a change of the composition in the CoFeB layers.
ABSTRACT Spintronics is a multidisciplinary field and a new research area. New materials must be ... more ABSTRACT Spintronics is a multidisciplinary field and a new research area. New materials must be found for satisfying the different types of requirement. The search for stable half-metallic ferromagnets and ferromagnetic semiconductors with Curie temperatures higher than room temperature is still a challenge for solid state scientists. A general understanding of how structures are related to properties is a necessary prerequisite for material design. Computational simulations are an important tool for a rational design of new materials. The new developments in this new field are reported from the point of view of material scientists.
ABSTRACT We report on the experimental investigation of the influence of a seed layer on the magn... more ABSTRACT We report on the experimental investigation of the influence of a seed layer on the magnetic properties of the full-Heusler alloy Co2FeAl0.4Si0.6 (CFAS). The studied magnetic films are grown epitaxially on MgO (1 0 0) substrates with Cr and/or MgO seed layers. By employing magneto-optical Kerr effect magnetometry we show that magnetic anisotropy can be tuned by choosing the proper seed layer. The results on CFAS show an overall uniaxial anisotropy plus a biaxial contribution which depends on the seed layer. In addition, if grown on MgO, a sharp increase in the coercive field HC at a series of angles symmetric with respect to the easy axis is present. Scanning Kerr-microscope imaging is performed during the magnetization reversal process in order to reveal the type of magnetic domain formation taking place at these angles.
Following our recent discovery of slow spin relaxation in the unique [OCu(III)O](-) anion located... more Following our recent discovery of slow spin relaxation in the unique [OCu(III)O](-) anion located in the apatite-type pigment A10(PO4)6(CuxOH1-x-y)2, where A = Sr, we present the magnetic behavior of this anion for the cases of A = Ca and Ba, which provides evidence for a cation field impact on the properties of a single-ion magnet molecular anion.
ABSTRACT We analyze the superconductors TiNCl and ZrNCl from a local bonding perspective. Althoug... more ABSTRACT We analyze the superconductors TiNCl and ZrNCl from a local bonding perspective. Although TiNCl crystallizes in an orthorhombic structure and ZrNCl crystallizes in a hexagonal structure, both compounds show significant structural similarities, for example that both consist of layered metal-Nitrogen networks. The local bonding in those two structures is very similar, giving rise to a dispersive conduction band mostly consisting of metal-d -states. Upon doping both compounds show structural changes, which lead to short metal-metal distances, indicating a bonding interaction that might be important for the appearance of superconductivity in these systems. We furthermore draw analogies to other superconductors that are close to a charge density wave instability around a d 1 -configuration and offer a different perspective on this class of superconductors, which show non-BCS-like superconductivity.
ABSTRACT In this work, results of hard X-ray photoelectron spectroscopy (HAXPES) of Heusler compo... more ABSTRACT In this work, results of hard X-ray photoelectron spectroscopy (HAXPES) of Heusler compounds and new materials for spintronics are presented. The class of Heusler materials includes some interesting half-metallic and ferromagnetic properties that were predicted by theory. HAXPES allows a direct comparison of the measured and the calculated electronic structure. Valence band spectroscopy of bulk materials by HAXPES is illustrated for the case of the half-metallic ferromagnet Co2MnGe. The feasibility of HAXPES to explore the valence band electronic structure in deeply buried metallic layers is demonstrated for buried Co2MnSi films. The films exhibit the same valence density of states as bulk samples and confirm the promise of an epitaxial, single-crystalline Co2-based Heusler compound film as a ferromagnetic electrode for spintronics devices. The study of complete CoFe(B)/MgO/CoFe(B) tunneling junctions demonstrates the capability of HAXPES to explore the electronic structure in deeply buried layers in a non-destructive way. The improvement of the TMR by annealing of the junction is explained by an improvement of the structure together with a change of the composition in the CoFeB layers.
ABSTRACT Spintronics is a multidisciplinary field and a new research area. New materials must be ... more ABSTRACT Spintronics is a multidisciplinary field and a new research area. New materials must be found for satisfying the different types of requirement. The search for stable half-metallic ferromagnets and ferromagnetic semiconductors with Curie temperatures higher than room temperature is still a challenge for solid state scientists. A general understanding of how structures are related to properties is a necessary prerequisite for material design. Computational simulations are an important tool for a rational design of new materials. The new developments in this new field are reported from the point of view of material scientists.
ABSTRACT We report on the experimental investigation of the influence of a seed layer on the magn... more ABSTRACT We report on the experimental investigation of the influence of a seed layer on the magnetic properties of the full-Heusler alloy Co2FeAl0.4Si0.6 (CFAS). The studied magnetic films are grown epitaxially on MgO (1 0 0) substrates with Cr and/or MgO seed layers. By employing magneto-optical Kerr effect magnetometry we show that magnetic anisotropy can be tuned by choosing the proper seed layer. The results on CFAS show an overall uniaxial anisotropy plus a biaxial contribution which depends on the seed layer. In addition, if grown on MgO, a sharp increase in the coercive field HC at a series of angles symmetric with respect to the easy axis is present. Scanning Kerr-microscope imaging is performed during the magnetization reversal process in order to reveal the type of magnetic domain formation taking place at these angles.
Following our recent discovery of slow spin relaxation in the unique [OCu(III)O](-) anion located... more Following our recent discovery of slow spin relaxation in the unique [OCu(III)O](-) anion located in the apatite-type pigment A10(PO4)6(CuxOH1-x-y)2, where A = Sr, we present the magnetic behavior of this anion for the cases of A = Ca and Ba, which provides evidence for a cation field impact on the properties of a single-ion magnet molecular anion.
ABSTRACT We analyze the superconductors TiNCl and ZrNCl from a local bonding perspective. Althoug... more ABSTRACT We analyze the superconductors TiNCl and ZrNCl from a local bonding perspective. Although TiNCl crystallizes in an orthorhombic structure and ZrNCl crystallizes in a hexagonal structure, both compounds show significant structural similarities, for example that both consist of layered metal-Nitrogen networks. The local bonding in those two structures is very similar, giving rise to a dispersive conduction band mostly consisting of metal-d -states. Upon doping both compounds show structural changes, which lead to short metal-metal distances, indicating a bonding interaction that might be important for the appearance of superconductivity in these systems. We furthermore draw analogies to other superconductors that are close to a charge density wave instability around a d 1 -configuration and offer a different perspective on this class of superconductors, which show non-BCS-like superconductivity.