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Papers by Colette Vignaud

Research paper thumbnail of Archeological applications of XAFS: prehistorical paintings and medieval glasses

Physica Scripta, 2005

... Dahn and co-workers in Berlin, Germany), the corrosion of Celtic weapons (Janssens&am... more ... Dahn and co-workers in Berlin, Germany), the corrosion of Celtic weapons (Janssens's group in Antwerp, Belgium), the determination of growth rate of desert varnish to help dating petroglyphs (Lytle's group at SSRL) or the sulfur speciation in old and modern woods (see ...

Research paper thumbnail of Le groupe des « bisons adossés » de Lascaux. Étude de la technique de l'artiste par analyse des pigments

Research paper thumbnail of Analysis of rock art painting and technology of Palaeolithic painters

Measurement Science and Technology, 2003

Research paper thumbnail of Heating effect on manganese oxihydroxides used as black Palaeolithic pigment

Research paper thumbnail of Le groupe des « bisons adossés » de Lascaux. Étude de la technique de l'artiste par analyse des pigments

L Anthropologie, Oct 1, 2006

Research paper thumbnail of Les matières colorantes en contexte solutréen : Combe Saunière (Dordogne), Fressignes (Indre) et Les Maîtreaux (Indre-et-Loire)

Research paper thumbnail of The crystallinity of ancient bone and dentine: New insights by transmission electron microscopy

Archaeometry, Jul 31, 2002

Research paper thumbnail of The history of a turquoise imitation - odontolite- a combined elemental, structural and spectroscopic study

Research paper thumbnail of Les matières colorantes en contexte solutréen : Combe Saunière (Dordogne), Fressignes (Indre) et Les Maîtreaux (Indre-et-Loire)

Résumé : L'abondance de matières colorantes sur certains sites d'habitat sans art pariéta... more Résumé : L'abondance de matières colorantes sur certains sites d'habitat sans art pariétal indique qu'il existait probablement des utilisations artisanales et domestiques de ces minéraux. L'utilisation de ces matériaux nécessitait l'élaboration de chaînes opératoires de production qu'il a été possible de reconstituer à travers l'étude des matières colorantes provenant des sites solutréens de Combe Saunière (Dordogne), Fressignes (Indre) et Les Maîtreaux (Indre-et-Loire). L'hématite, produisant une poudre rouge, et les oxydes de manganèse, produisant une poudre noire, sont les matières colorantes préférentiellement recherchées par les Solutréens. Il a été possible de mettre en évidence le chauffage des matières colorantes jaunes, qui a pour but la production d'hématite. À Combe Saunière et à Fressignes, le contexte ne permet pas de trancher en faveur d'un chauffage volontaire. En revanche, sur le site des Maîtreaux, une aire de 20 m 2 environ c...

Research paper thumbnail of BECK (L.), GENTY (D.), LAHLIL (S), LEBON (M.), TÉREYGEOL (F.), VIGNAUD (C.), REICHE (I.), LAMBERT (E.), VALLADAS (H.), KALTNECKER (E.), PLASSARD (F.), MENU (M.), PAILLET (P.), Non-destructive portable analytical techniques for carbon in situ screening before sampling for dating prehistoric rock p...

BECK (L.), GENTY (D.), LAHLIL (S), LEBON (M.), TÉREYGEOL (F.), VIGNAUD (C.), REICHE (I.), LAMBERT (E.), VALLADAS (H.), KALTNECKER (E.), PLASSARD (F.), MENU (M.), PAILLET (P.), Non-destructive portable analytical techniques for carbon in situ screening before sampling for dating prehistoric rock p...

Radiocarbon

Research paper thumbnail of Diffusion in Archaeological Bone

Defect and Diffusion Forum, 2001

ABSTRACT This paper presents a synthesis of the state of the knowledge concerning diffusion in ar... more ABSTRACT This paper presents a synthesis of the state of the knowledge concerning diffusion in archaeological bone. Bone remains are often the unique witnesses of ancient societies and so an irreplaceable source of information about ages, populations, ancient diets and palaeoclimates. As their degree of conservation is highly variable and dependent on the environment, the alteration processes, especially the modifications due to transport of chemical species, should be known in order to get reliable information on the past. Analysis of the literature and experimental results allows to describe the main features of the diagenetic evolution and to determine the important parameters for an adequate diffusion model We show that a more precise interpretation of the uptake of chemical species in archaeological bone will be possible when the complex organic and mineral microstructure of bone will be understood and if more diffusion coefficients of different chemical species in bone are determined.

Research paper thumbnail of Heat induced transformation of fossil mastodon ivory into turquoise ‘odontolite’. Structural and elemental characterisation

Solid State Sciences, 2000

... Heat induced transformation of fossil mastodon ivory into turquoise 'odontolite'. Str... more ... Heat induced transformation of fossil mastodon ivory into turquoise 'odontolite'. Structural and elemental characterisation. ... 2.2. Sample preparation for examination. 2.2.1. Heat treatment of ivory fragments. Modern and fossil ivory ...

Research paper thumbnail of A multi-analytical study of bone diagenesis: the Neolithic site of Bercy (Paris, France)

Measurement Science and Technology, 2003

Abstract Bone remains play an important role in archaeology as a source of information about the ... more Abstract Bone remains play an important role in archaeology as a source of information about the past. However, they alter over time. Alteration occurs at all scales from the macroscopic to nanoscopic level. The evaluation of information extracted on palaeodiets, ages and palaeoclimates from their chemical and isotopic composition requires the study of diagenetic modifications by means of different complementary analytical methods. Diagenetic parameters that quantify the post-mortem alteration of bone are bone histology ...

Research paper thumbnail of Analysis of rock art painting and technology of Palaeolithic painters

Measurement Science and Technology, 2003

Research paper thumbnail of Le groupe des « bisons adossés » de Lascaux. Étude de la technique de l'artiste par analyse des pigments

Research paper thumbnail of Fluorine Analysis in Biogenic and Geological Apatite by Analytical Transmission Electron Microscopy and Nuclear Reaction Analysis

Journal of Trace and Microprobe Techniques, 2002

... Menu, M., Calligaro, T., Salomon, J., Amsel, G. and Moulin, J. 1990. The Dedicated Accelerato... more ... Menu, M., Calligaro, T., Salomon, J., Amsel, G. and Moulin, J. 1990. The Dedicated Accelerator-Based IBA Facility AGLAE at the Louvre*. ... Structural and Elemental Characterisation. ... Apatite Crystal Morphologies in Archaeological Bone and Dentine Material Observed by TEM. ...

Research paper thumbnail of The crystallinity of ancient bone and dentine: new insights by transmission electron microscopy

Research paper thumbnail of Palaeolithic painting matter: natural or heat-treated pigment?

Applied Physics A: Materials Science & Processing, 2004

Research paper thumbnail of Analyse non destructive des pigments préhistoriques : du laboratoire à la grotte

Research paper thumbnail of Discovery of Unusual Minerals in Paleolithic Black Pigments from Lascaux (France) and Ekain (Spain)

Analyses of archaeological materials aim to rediscover the know-how of Prehistoric people by dete... more Analyses of archaeological materials aim to rediscover the know-how of Prehistoric people by determining the nature of the painting matter, its preparation mode, and the geographic origin of its raw materials. This study deals with identification of manganese oxides in black pigments by micro-XANES (X-ray absorption near-edge structure) based on previous TEM (transmission electron microscopy) studies. Complex mixtures of the manganese oxides studied are present in some of mankind's oldest known paintings, namely those from the caves of Lascaux (Dordogne, France) and Ekain (Basque country, Spain). Scarce manganese oxide minerals, including groutite, hausmannite, and manganite, were found for the first time in Paleolithic art at these archaeological sites. Because there are no known deposits of such minerals in these areas, more distant origins and trade routes are inferred. The closest known Mn-rich geological province for Lascaux is the central Pyrénées, which is ~ 250 km from the Dordogne area.

Research paper thumbnail of Archeological applications of XAFS: prehistorical paintings and medieval glasses

Physica Scripta, 2005

... Dahn and co-workers in Berlin, Germany), the corrosion of Celtic weapons (Janssens&am... more ... Dahn and co-workers in Berlin, Germany), the corrosion of Celtic weapons (Janssens's group in Antwerp, Belgium), the determination of growth rate of desert varnish to help dating petroglyphs (Lytle's group at SSRL) or the sulfur speciation in old and modern woods (see ...

Research paper thumbnail of Le groupe des « bisons adossés » de Lascaux. Étude de la technique de l'artiste par analyse des pigments

Research paper thumbnail of Analysis of rock art painting and technology of Palaeolithic painters

Measurement Science and Technology, 2003

Research paper thumbnail of Heating effect on manganese oxihydroxides used as black Palaeolithic pigment

Research paper thumbnail of Le groupe des « bisons adossés » de Lascaux. Étude de la technique de l'artiste par analyse des pigments

L Anthropologie, Oct 1, 2006

Research paper thumbnail of Les matières colorantes en contexte solutréen : Combe Saunière (Dordogne), Fressignes (Indre) et Les Maîtreaux (Indre-et-Loire)

Research paper thumbnail of The crystallinity of ancient bone and dentine: New insights by transmission electron microscopy

Archaeometry, Jul 31, 2002

Research paper thumbnail of The history of a turquoise imitation - odontolite- a combined elemental, structural and spectroscopic study

Research paper thumbnail of Les matières colorantes en contexte solutréen : Combe Saunière (Dordogne), Fressignes (Indre) et Les Maîtreaux (Indre-et-Loire)

Résumé : L'abondance de matières colorantes sur certains sites d'habitat sans art pariéta... more Résumé : L'abondance de matières colorantes sur certains sites d'habitat sans art pariétal indique qu'il existait probablement des utilisations artisanales et domestiques de ces minéraux. L'utilisation de ces matériaux nécessitait l'élaboration de chaînes opératoires de production qu'il a été possible de reconstituer à travers l'étude des matières colorantes provenant des sites solutréens de Combe Saunière (Dordogne), Fressignes (Indre) et Les Maîtreaux (Indre-et-Loire). L'hématite, produisant une poudre rouge, et les oxydes de manganèse, produisant une poudre noire, sont les matières colorantes préférentiellement recherchées par les Solutréens. Il a été possible de mettre en évidence le chauffage des matières colorantes jaunes, qui a pour but la production d'hématite. À Combe Saunière et à Fressignes, le contexte ne permet pas de trancher en faveur d'un chauffage volontaire. En revanche, sur le site des Maîtreaux, une aire de 20 m 2 environ c...

Research paper thumbnail of BECK (L.), GENTY (D.), LAHLIL (S), LEBON (M.), TÉREYGEOL (F.), VIGNAUD (C.), REICHE (I.), LAMBERT (E.), VALLADAS (H.), KALTNECKER (E.), PLASSARD (F.), MENU (M.), PAILLET (P.), Non-destructive portable analytical techniques for carbon in situ screening before sampling for dating prehistoric rock p...

BECK (L.), GENTY (D.), LAHLIL (S), LEBON (M.), TÉREYGEOL (F.), VIGNAUD (C.), REICHE (I.), LAMBERT (E.), VALLADAS (H.), KALTNECKER (E.), PLASSARD (F.), MENU (M.), PAILLET (P.), Non-destructive portable analytical techniques for carbon in situ screening before sampling for dating prehistoric rock p...

Radiocarbon

Research paper thumbnail of Diffusion in Archaeological Bone

Defect and Diffusion Forum, 2001

ABSTRACT This paper presents a synthesis of the state of the knowledge concerning diffusion in ar... more ABSTRACT This paper presents a synthesis of the state of the knowledge concerning diffusion in archaeological bone. Bone remains are often the unique witnesses of ancient societies and so an irreplaceable source of information about ages, populations, ancient diets and palaeoclimates. As their degree of conservation is highly variable and dependent on the environment, the alteration processes, especially the modifications due to transport of chemical species, should be known in order to get reliable information on the past. Analysis of the literature and experimental results allows to describe the main features of the diagenetic evolution and to determine the important parameters for an adequate diffusion model We show that a more precise interpretation of the uptake of chemical species in archaeological bone will be possible when the complex organic and mineral microstructure of bone will be understood and if more diffusion coefficients of different chemical species in bone are determined.

Research paper thumbnail of Heat induced transformation of fossil mastodon ivory into turquoise ‘odontolite’. Structural and elemental characterisation

Solid State Sciences, 2000

... Heat induced transformation of fossil mastodon ivory into turquoise 'odontolite'. Str... more ... Heat induced transformation of fossil mastodon ivory into turquoise 'odontolite'. Structural and elemental characterisation. ... 2.2. Sample preparation for examination. 2.2.1. Heat treatment of ivory fragments. Modern and fossil ivory ...

Research paper thumbnail of A multi-analytical study of bone diagenesis: the Neolithic site of Bercy (Paris, France)

Measurement Science and Technology, 2003

Abstract Bone remains play an important role in archaeology as a source of information about the ... more Abstract Bone remains play an important role in archaeology as a source of information about the past. However, they alter over time. Alteration occurs at all scales from the macroscopic to nanoscopic level. The evaluation of information extracted on palaeodiets, ages and palaeoclimates from their chemical and isotopic composition requires the study of diagenetic modifications by means of different complementary analytical methods. Diagenetic parameters that quantify the post-mortem alteration of bone are bone histology ...

Research paper thumbnail of Analysis of rock art painting and technology of Palaeolithic painters

Measurement Science and Technology, 2003

Research paper thumbnail of Le groupe des « bisons adossés » de Lascaux. Étude de la technique de l'artiste par analyse des pigments

Research paper thumbnail of Fluorine Analysis in Biogenic and Geological Apatite by Analytical Transmission Electron Microscopy and Nuclear Reaction Analysis

Journal of Trace and Microprobe Techniques, 2002

... Menu, M., Calligaro, T., Salomon, J., Amsel, G. and Moulin, J. 1990. The Dedicated Accelerato... more ... Menu, M., Calligaro, T., Salomon, J., Amsel, G. and Moulin, J. 1990. The Dedicated Accelerator-Based IBA Facility AGLAE at the Louvre*. ... Structural and Elemental Characterisation. ... Apatite Crystal Morphologies in Archaeological Bone and Dentine Material Observed by TEM. ...

Research paper thumbnail of The crystallinity of ancient bone and dentine: new insights by transmission electron microscopy

Research paper thumbnail of Palaeolithic painting matter: natural or heat-treated pigment?

Applied Physics A: Materials Science & Processing, 2004

Research paper thumbnail of Analyse non destructive des pigments préhistoriques : du laboratoire à la grotte

Research paper thumbnail of Discovery of Unusual Minerals in Paleolithic Black Pigments from Lascaux (France) and Ekain (Spain)

Analyses of archaeological materials aim to rediscover the know-how of Prehistoric people by dete... more Analyses of archaeological materials aim to rediscover the know-how of Prehistoric people by determining the nature of the painting matter, its preparation mode, and the geographic origin of its raw materials. This study deals with identification of manganese oxides in black pigments by micro-XANES (X-ray absorption near-edge structure) based on previous TEM (transmission electron microscopy) studies. Complex mixtures of the manganese oxides studied are present in some of mankind's oldest known paintings, namely those from the caves of Lascaux (Dordogne, France) and Ekain (Basque country, Spain). Scarce manganese oxide minerals, including groutite, hausmannite, and manganite, were found for the first time in Paleolithic art at these archaeological sites. Because there are no known deposits of such minerals in these areas, more distant origins and trade routes are inferred. The closest known Mn-rich geological province for Lascaux is the central Pyrénées, which is ~ 250 km from the Dordogne area.