Daniela Wilson - Academia.edu (original) (raw)

Papers by Daniela Wilson

Research paper thumbnail of Morphogenesis of starfish polymersomes

Nature Communications, Jun 17, 2023

Research paper thumbnail of Adaptive insertion of a hydrophobic anchor into a poly(ethylene glycol) host for programmable surface functionalization

Nature Chemistry, Nov 21, 2022

Research paper thumbnail of A supramolecular helix that disregards chirality

Nature Chemistry, Nov 16, 2015

Research paper thumbnail of ChemInform Abstract: Manipulation of Micro- and Nanostructure Motion with Magnetic Fields

Research paper thumbnail of Demonstrating the 8<sub>1</sub>-Helicity and Nanomechanical Function of Self-Organizable Dendronized Polymethacrylates and Polyacrylates

Macromolecules, Jul 11, 2017

A library of six dendronized polymers synthesized via single-electron transfer living radical pol... more A library of six dendronized polymers synthesized via single-electron transfer living radical polymerization (SET-LRP) of self-assembling dendrons with a methacrylate or acrylate apex is reported. Structural and retrostructural analysis by X-ray diffraction, molecular modeling, reconstructed electron density maps, and circular dichroism demonstrated that dendronized polymethacrylates and polyacrylates adopt a chiral, 81-helix induced by self-organization of the dendritic side groups. The helical handedness is selected by the stereocenter of the ethylene glycol linker between the dendron and polymer. Upon heating, oriented fibers of polymers with this linker undergo a phase transition between two columnar hexagonal phases, accompanied by unidirectional macroscopic thermal expansion. Replacement of the flexible linker with a shorter, rigid linker eliminates this expansion. Polyacrylates exhibit substantially quicker phase transition dynamics than polymethacrylates. The relationship between the primary struc...

Research paper thumbnail of Hierarchical Self-Organization of Chiral Columns from Chiral Supramolecular Spheres

Journal of the American Chemical Society, Sep 21, 2018

Research paper thumbnail of Supramolecular Spheres Self-Assembled from Conical Dendrons Are Chiral

Journal of the American Chemical Society, Apr 1, 2019

Research paper thumbnail of Entrapment of Metal Nanoparticles in Polymer Stomatocytes

Journal of the American Chemical Society, Jun 8, 2012

Research paper thumbnail of Leveraging synthetic particles for communication: from passive to active systems

Research paper thumbnail of Tailoring Polymersome Shape Using the Hofmeister Effect

Biomacromolecules, Sep 17, 2019

Research paper thumbnail of Screening Libraries of Amphiphilic Janus Dendrimers Based on Natural Phenolic Acids to Discover Monodisperse Unilamellar Dendrimersomes

Biomacromolecules, Oct 25, 2018

Research paper thumbnail of Stomatocyte in Stomatocyte: A New Shape of Polymersome Induced via Chemical-Addition Methodology

Nano Letters, Feb 7, 2018

Research paper thumbnail of Self‐Propelled PLGA Micromotor with Chemotactic Response to Inflammation

Advanced Healthcare Materials, Mar 6, 2020

Research paper thumbnail of Continuous fabrication of polymeric vesicles and nanotubes with fluidic channels

Research paper thumbnail of Selective photodimerization of acenaphthylene in polymersome nanoreactors

Chemical Communications, 2023

Research paper thumbnail of Supramolecular nanomotors with “pH taxis” for active drug delivery in the tumor microenvironment

Research paper thumbnail of Molecular Engineering of pH-Responsive Anchoring Systems onto Poly(ethylene glycol) Corona

Journal of the American Chemical Society, Apr 19, 2023

Research paper thumbnail of Membrane folding and shape transformation in biomimetic vesicles

Research paper thumbnail of Generating biomembrane-like local curvature in polymersomes via dynamic polymer insertion

Nature Communications, Apr 14, 2021

Research paper thumbnail of Photo-Cross-Linking Polymersome Nanoreactors with Size-Selective Permeability

Research paper thumbnail of Morphogenesis of starfish polymersomes

Nature Communications, Jun 17, 2023

Research paper thumbnail of Adaptive insertion of a hydrophobic anchor into a poly(ethylene glycol) host for programmable surface functionalization

Nature Chemistry, Nov 21, 2022

Research paper thumbnail of A supramolecular helix that disregards chirality

Nature Chemistry, Nov 16, 2015

Research paper thumbnail of ChemInform Abstract: Manipulation of Micro- and Nanostructure Motion with Magnetic Fields

Research paper thumbnail of Demonstrating the 8<sub>1</sub>-Helicity and Nanomechanical Function of Self-Organizable Dendronized Polymethacrylates and Polyacrylates

Macromolecules, Jul 11, 2017

A library of six dendronized polymers synthesized via single-electron transfer living radical pol... more A library of six dendronized polymers synthesized via single-electron transfer living radical polymerization (SET-LRP) of self-assembling dendrons with a methacrylate or acrylate apex is reported. Structural and retrostructural analysis by X-ray diffraction, molecular modeling, reconstructed electron density maps, and circular dichroism demonstrated that dendronized polymethacrylates and polyacrylates adopt a chiral, 81-helix induced by self-organization of the dendritic side groups. The helical handedness is selected by the stereocenter of the ethylene glycol linker between the dendron and polymer. Upon heating, oriented fibers of polymers with this linker undergo a phase transition between two columnar hexagonal phases, accompanied by unidirectional macroscopic thermal expansion. Replacement of the flexible linker with a shorter, rigid linker eliminates this expansion. Polyacrylates exhibit substantially quicker phase transition dynamics than polymethacrylates. The relationship between the primary struc...

Research paper thumbnail of Hierarchical Self-Organization of Chiral Columns from Chiral Supramolecular Spheres

Journal of the American Chemical Society, Sep 21, 2018

Research paper thumbnail of Supramolecular Spheres Self-Assembled from Conical Dendrons Are Chiral

Journal of the American Chemical Society, Apr 1, 2019

Research paper thumbnail of Entrapment of Metal Nanoparticles in Polymer Stomatocytes

Journal of the American Chemical Society, Jun 8, 2012

Research paper thumbnail of Leveraging synthetic particles for communication: from passive to active systems

Research paper thumbnail of Tailoring Polymersome Shape Using the Hofmeister Effect

Biomacromolecules, Sep 17, 2019

Research paper thumbnail of Screening Libraries of Amphiphilic Janus Dendrimers Based on Natural Phenolic Acids to Discover Monodisperse Unilamellar Dendrimersomes

Biomacromolecules, Oct 25, 2018

Research paper thumbnail of Stomatocyte in Stomatocyte: A New Shape of Polymersome Induced via Chemical-Addition Methodology

Nano Letters, Feb 7, 2018

Research paper thumbnail of Self‐Propelled PLGA Micromotor with Chemotactic Response to Inflammation

Advanced Healthcare Materials, Mar 6, 2020

Research paper thumbnail of Continuous fabrication of polymeric vesicles and nanotubes with fluidic channels

Research paper thumbnail of Selective photodimerization of acenaphthylene in polymersome nanoreactors

Chemical Communications, 2023

Research paper thumbnail of Supramolecular nanomotors with “pH taxis” for active drug delivery in the tumor microenvironment

Research paper thumbnail of Molecular Engineering of pH-Responsive Anchoring Systems onto Poly(ethylene glycol) Corona

Journal of the American Chemical Society, Apr 19, 2023

Research paper thumbnail of Membrane folding and shape transformation in biomimetic vesicles

Research paper thumbnail of Generating biomembrane-like local curvature in polymersomes via dynamic polymer insertion

Nature Communications, Apr 14, 2021

Research paper thumbnail of Photo-Cross-Linking Polymersome Nanoreactors with Size-Selective Permeability